Open‐Shell Donor–Acceptor Conjugated Polymers with High Electrical Conductivity

Conductive polymers largely derive their electronic functionality from chemical doping, processes by which redox and charge‐transfer reactions form mobile carriers. While decades of research have demonstrated fundamentally new technologies that merge the unique functionality of these materials with the chemical versatility of macromolecules, doping and the resultant material properties are not ideal for many applications. Here, it is demonstrated that open‐shell conjugated polymers comprised of alternating cyclopentadithiophene and thiadiazoloquinoxaline units can achieve high electrical conductivities in their native “undoped” form. Spectroscopic, electrochemical, electron paramagnetic resonance, and magnetic susceptibility measurements demonstrate that this donor–acceptor architecture promotes very narrow bandgaps, strong electronic correlations, high‐spin ground states, and long‐range π‐delocalization. A comparative study of structural variants and processing methodologies demonstrates that the conductivity can be tuned up to 8.18 S cm^?1. This exceeds other neutral narrow bandgap conjugated polymers, many doped polymers, radical conductors, and is comparable to commercial grades of poly(styrene‐sulfonate)‐doped poly(3,4‐ethylenedioxythiophene). X‐ray and morphological studies trace the high conductivity to rigid backbone conformations emanating from strong π‐interactions and long‐range ordered structures formed through self‐organization that lead to a network of delocalized open‐shell sites in electronic communication. The results offer a new platform for the transport of charge in molecular systems.     

A combined field approach to scattering from infinite ellipticalcylinders using the method of ordered multiple interactions

The method of ordered multiple interactions (MOMI) is an iterative procedure which has been demonstrated to provide a rapidly convergent series for the problem of wave scattering from perfectly conducting surfaces rough in a single dimension. In this paper, we consider the extension of this technique to the problem of scattering from infinite elliptical cylinders. For an incident plane wave having its electric field polarized along the axis of the cylinder a combined field formulation of the scattering problem is found to provide a rapidly convergent MOMI series. The determination of an optimal combined field representation for the scattering problem in this case is also discussed. An extension of the MOMI method is necessary to properly treat the remaining polarization     

Multi-Fidelity High-Throughput Optimization of Electrical Conductivity in P3HT-CNT Composites

Combining high-throughput experiments with machine learning accelerates materials and process optimization toward user-specified target properties. In this study, a rapid machine learning-driven automated flow mixing setup with a high-throughput drop-casting system is introduced for thin film preparation, followed by fast characterization of proxy optical and target electrical properties that completes one cycle of learning with 160 unique samples in a single day, a > 10 ×  improvement relative to quantified, manual-controlled baseline. Regio-regular poly-3-hexylthiophene is combined with various types of carbon nanotubes, to identify the optimum composition and synthesis conditions to realize electrical conductivities as high as state-of-the-art 1000 S cm⁻¹. The results are subsequently verified and explained using offline high-fidelity experiments. Graph-based model selection strategies with classical regression that optimize among multi-fidelity noisy input-output measurements are introduced. These strategies present a robust machine-learning driven high-throughput experimental scheme that can be effectively applied to understand, optimize, and design new materials and composites.     

Generalized S transform

The generalized S transform (GST), a family of reversible integer-to-integer transforms inspired by the S transform, is proposed. This family of transforms is then studied in detail by considering topics such as GST parameter calculation, the effects of using different rounding operators in the GST, and the relationship between the GST and the lifting scheme. Some examples of specific transforms in the GST family are also given. In particular, a new transform in this family is introduced, and its practical utility is demonstrated.     

Improved Optoelectronic Properties of Rapid Thermally Annealed Dilute Nitride GaInNAs Photodetectors

We investigate the optical and electrical characteristics of GaInNAs/GaAs long-wavelength photodiodes grown under varying conditions by molecular beam epitaxy and subjected to postgrowth rapid thermal annealing (RTA) at a series of temperatures. It is found that the device performance of the nonoptimally grown GaInNAs p ⁺–i–n ⁺ structures, with nominal compositions of 10% In and 3.8% N, can be improved significantly by the RTA treatment to match that of optimally grown structures. The optimally annealed devices exhibit overall improvement in optical and electrical characteristics, including increased photoluminescence brightness, reduced density of deep-level traps, reduced series resistance resulting from the GaAs/GaInNAs heterointerface, lower dark current, and significantly lower background doping density, all of which can be attributed to the reduced structural disorder in the GaInNAs alloy.     

Conjugate-order systems for signal processing: stability, causality, boundedness, compactness

The fundamental system theory is presented for a class of real systems whose derivative order is complex. It is demonstrated that these so-called conjugate-order systems have a scale-invariance property in both the time and frequency domains, which makes them useful for describing certain phenomena in continuous media. The conditions for which these systems are guaranteed to be causal and stable are reviewed. The compactness properties of their Hankel operators, which allow them to admit finite-order approximations, are also discussed. A procedure is developed for choosing appropriate transfer-function parameter values to design a stable conjugate-order system whose frequency response meets given bandwidth, resonance, and ripple specifications.     

AN-1071应用指南——D类功放基础（一）

如果我们在选择器件时很谨慎，并且考虑到精细的设计布线，因为杂散参数有很大的影响，那么目前高效D类功放可以提供和传统的AB类功放类似的性能。半导体技术不断创新使得效率提高，功率密度增加和较好的音响效果，增加了D类功放的运用。     

Narrative analysis of sexual etiquette in teenage magazines

Expanding on existing research on women's magazines, this essay examines the sexual etiquette developed in advice columns in magazines popular among teenage women. Over a span of 20 years, the advice has changed very little. Serving the rhetorical function of field guides and training manuals, teen magazines limit women's sociality and sexuality within narrowly defined heterosexual norms and practices. The rhetoric of sexual etiquette encourages young women to be sex objects and teachers of interpersonal communication rather than lovers, friends, and partners. Young women are being taught to subordinate self for others and to be contained.     

多波长泵浦宽带拉曼放大器功率增益研究

受激拉曼散射（SRS）的Stokes波谱线型比较复杂,本文分别用Gauss线型和Lorentz线型,研究多波长泵浦宽带Raman放大器的增益特性,提出宽带增益平坦的多波长泵浦方案,研究表明增益平坦程序与泵清波频率间隔密切相关。对G．652、G．653、G．655光纤和新型大有效面积非零色散平坦光纤的Raman放大增益分别进行了研究,结果表明Raman增益与光纤种类和光纤传输性有关,特别是随光纤有效纤芯面积的增大而明显减小。