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51.
Jian Duan Wangyan Wu Adelaide M. Nolan Tengrui Wang Jiayun Wen Chenchen Hu Yifei Mo Wei Luo Yunhui Huang 《Advanced materials (Deerfield Beach, Fla.)》2019,31(10)
All‐solid‐state batteries (ASSBs) with ceramic‐based solid‐state electrolytes (SSEs) enable high safety that is inaccessible with conventional lithium‐ion batteries. Lithium metal, the ultimate anode with the highest specific capacity, also becomes available with nonflammable SSEs in ASSBs, which offers promising energy density. The rapid development of ASSBs, however, is significantly hampered by the large interfacial resistance as a matched lithium/ceramic interface that is not easy to pursue. Here, a lithium–graphite (Li–C) composite anode is fabricated, which shows a dramatic modification in wettability with garnet SSE. An intimate Li–C/garnet interface is obtained by casting Li–C composite onto garnet‐type SSE, delivering an interfacial resistance as low as 11 Ω cm2. As a comparison, pure Li/garnet interface gives a large resistance of 381 Ω cm2. Such improvement can be ascribed to the experiment‐measured increased viscosity of Li–C composite and simulation‐verified limited interfacial reaction. The Li–C/garnet/Li–C symmetric cell exhibits stable plating/striping performance with small voltage hysteresis and endures a critical current density up to 1.0 mA cm?2. The full cell paired with LiFePO4 shows stable cycle performance, comparable to the cell with liquid electrolyte. The present work demonstrates a promising strategy to develop ceramic‐compatible lithium metal‐based anodes and hence low‐impedance ASSBs. 相似文献
52.
The HMI1 gene encodes a DNA helicase that localizes to the mitochondria and is required for maintenance of the mitochondrial DNA (mtDNA) genome of Saccharomyces cerevisiae. Identified based on its homology with E. coli uvrD, the HMI1 gene product, Hmi1p, has been presumed to be involved in the replication of the 80 kb linear S. cerevisiae mtDNA genome. Here we report the purification of Hmi1p to apparent homogeneity and provide a characterization of the helicase reaction and the ATPase reaction with regard to NTP preference, divalent cation preference and the stimulatory effects of different nucleic acids on Hmi1p-catalysed ATPase activity. Genetic complementation assays indicate that mitochondrial localization of Hmi1p is essential for its role in mtDNA metabolism. The helicase activity, however, is not essential. Point mutants that lack ATPase/helicase activity partially complement a strain lacking Hmi1p. We suggest several possible roles for Hmi1p in mtDNA metabolism. 相似文献
53.
Adelaide Cerveira Amaro de Sousa E. J. Solteiro Pires José Baptista 《International Transactions in Operational Research》2024,31(1):88-114
Wind power is becoming an important source of electrical energy production. In an onshore wind farm (WF), the electrical energy is collected at a substation from different wind turbines through electrical cables deployed over ground ditches. This work considers the WF layout design assuming that the substation location and all wind turbine locations are given, and a set of electrical cable types is available. The WF layout problem, taking into account its lifetime and technical constraints, involves selecting the cables to interconnect all wind turbines to the substation and the supporting ditches to minimize the initial investment cost plus the cost of the electrical energy that is lost on the cables over the lifetime of the WF. It is assumed that each ditch can deploy multiple cables, turning this problem into a more complex variant of previously addressed WF layout problems. This variant turns the problem best fitting to the real case and leads to substantial gains in the total cost of the solutions. The problem is defined as an integer linear programming model, which is then strengthened with different sets of valid inequalities. The models are tested with four WFs with up to 115 wind turbines. The computational experiments show that the optimal solutions can be computed with the proposed models for almost all cases. The largest WF was not solved to optimality, but the final relative gaps are small. 相似文献