Thermoelectric and Magnetic Properties of Pt-Substituted $${BaFe_{4-{x}}Pt_{{x}}Sb_{12}}$$ Compounds

\({BaFe_{4-{x}}Pt_{{x}}Sb_{12}}\) (x = 0, 0.1, 0.2) compounds were prepared by melting and annealing, followed by a spark plasma sintering method. Low-temperature thermoelectric and magnetic properties were investigated based on Seebeck coefficient, electrical and thermal conductivity and magnetization measurements. The structural properties of \({BaFe_{4-{x}}Pt_{{x}}Sb_{12}}\) (x = 0, 0.1, 0.2) compounds were ascertained by powder x-ray diffraction analysis, confirming that all samples have a main phase of a skutterudite structure with the space group Im\({\mathrm {\bar{3}}}\). The lattice parameters obtained, 9.202(5), 9.199(5) and 9.202(1) Å for x = 0, 0.1 and 0.2, respectively, were found consistent with literature. The Seebeck coefficient sign shows that holes are dominant carriers in all compounds. The local maximum Seebeck coefficient was observed around 50 K which may be a trace of paramagnon-drag effect of charge carriers. Thermal conductivity and electrical resistivity measurements were carried out between 4.2 and 300 K. Temperature dependence of electrical resistivity reflects that all samples show semi-metallic behavior in our temperature range of 4.2–300 K. Samples for x = 0.1 and x = 0.2 show Kondo-like behavior. In magnetization measurement, we observe that there are two successive magnetic transitions in Pt-substituted compounds; however, there is only one (transition from a paramagnetic state to long-range magnetic ordering) in Pt-free compounds. In Pt-substituted compounds, the first transition appears at \( T _{ {\rm c}}\) = 48 K. In addition, the second transition is observed at \( T _{ {\rm irr}}\) = 30 K where an intermediate state is observed before the magnetic ordering transforms to an irreversible ferromagnetic state. We concluded that Pt substitution on the Fe side effectual on the thermoelectric and magnetic properties of \({BaFe_{4-{x}}Pt_{{x}}Sb_{12}}\) (x = 0, 0.1, 0.2) compounds.     

A Distributed and Elastic Application Processing Model for Mobile Cloud Computing

The latest developments in mobile computing technology have increased the computing capabilities of smart mobile devices (SMDs). However, SMDs are still constrained by low bandwidth, processing potential, storage capacity, and battery lifetime. To overcome these problems, the rich resources and powerful computational cloud is tapped for enabling intensive applications on SMDs. In Mobile Cloud Computing (MCC), application processing services of computational clouds are leveraged for alleviating resource limitations in SMDs. The particular deficiency of distributed architecture and runtime partitioning of the elastic mobile application are the challenging aspects of current offloading models. To address these issues of traditional models for computational offloading in MCC, this paper proposes a novel distributed and elastic applications processing (DEAP) model for intensive applications in MCC. We present an analytical model to evaluate the proposed DEAP model, and test a prototype application in the real MCC environment to demonstrate the usefulness of DEAP model. Computational offloading using the DEAP model minimizes resources utilization on SMD in the distributed processing of intensive mobile applications. Evaluation indicates a reduction of 74.6% in the overhead of runtime application partitioning and a 66.6% reduction in the CPU utilization for the execution of the application on SMD.

     

Effects of urban coarse particles inhalation on oxidative and inflammatory parameters in the mouse lung and colon

Background

Air pollution is a recognized aggravating factor for pulmonary diseases and has notably deleterious effects on asthma, bronchitis and pneumonia. Recent studies suggest that air pollution may also cause adverse effects in the gastrointestinal tract. Accumulating experimental evidence shows that immune responses in the pulmonary and intestinal mucosae are closely interrelated, and that gut-lung crosstalk controls pathophysiological processes such as responses to cigarette smoke and influenza virus infection. Our first aim was to collect urban coarse particulate matter (PM) and to characterize them for elemental content, gastric bioaccessibility, and oxidative potential; our second aim was to determine the short-term effects of urban coarse PM inhalation on pulmonary and colonic mucosae in mice, and to test the hypothesis that the well-known antioxidant N-acetyl-L-cysteine (NAC) reverses the effects of PM inhalation.

Results

The collected PM had classical features of urban particles and possessed oxidative potential partly attributable to their metal fraction. Bioaccessibility study confirmed the high solubility of some metals at the gastric level. Male mice were exposed to urban coarse PM in a ventilated inhalation chamber for 15 days at a concentration relevant to episodic elevation peak of air pollution. Coarse PM inhalation induced systemic oxidative stress, recruited immune cells to the lung, and increased cytokine levels in the lung and colon. Concomitant oral administration of NAC reversed all the observed effects relative to the inhalation of coarse PM.

Conclusions

Coarse PM-induced low-grade inflammation in the lung and colon is mediated by oxidative stress and deserves more investigation as potentiating factor for inflammatory diseases.

     

Effects of Neutron Flux on the Temperature Dependency of Permittivity of 3C-SiC Nanoparticles

In the present work, the real and imaginary parts of permittivity of cubic modification silicon carbide (3C-SiC) nanoparticles are investigated before and after neutron irradiation. The real and imaginary parts of permittivity for the samples were studied in 0.1 Hz–2.5 MHz frequency and 100 K–400 K temperature ranges. The samples were continuously irradiated by neutron flux (2x10 ¹³ n ?cm ^?2 s ^?1) up to 20 hours. The real and imaginary parts of permittivity were comparatively studied before and after irradiation. Neutron irradiation effects were studied with comparative analysis of non-irradiated samples. The increase in polarization was observed as a result of the increase in the impact period of neutron flux. All the mechanisms of the observed effects are given in the work.     

A multivariate study: variation in uptake of trace and toxic elements by various varieties of Sorghum bicolor L

The aim of present study was to evaluate the variation in uptake of elements (As, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb and Zn) by different varieties of Sorghum bicolor L., plants grown in soil amended with untreated industrial waste water sewage sludge (SUIS), on same experimental plots. The power of chemometrics was also used in exploring the potential natural and/or anthropogenic sources responsible for elemental contents in different varieties of sorghum. Hierarchical cluster analysis was used to explore the different variety of sorghum grouping according to corresponding their SUIS samples as additional information to the output obtained by principal component analysis. Significant genotypic variation was detected in the fourteen elements concentrations in sorghum grains, indicating the possibility to reduce the concentration of toxic elements in grains through breeding approach. It was observed that high tolerance limit of toxic elements was observed in sorghum variety PARC-SV-1.     

Hazardous impact of toxic metals on tobacco leaves grown in contaminated soil by ultrasonic assisted pseudo-digestion: multivariate study

Tobacco leaves (Nicotiana tabacum L.), agricultural soil and pollute irrigated lake water samples were collected during 2005–2006 and analyzed for Cd and Ni by electrothermal atomic absorption spectrometry (ETAAS). A simple and efficient procedure was investigated for the complete decomposition of tobacco leaves using ultrasonic assisted acid pseudo-digestion method (UPDM). A Plackett–Burman experimental design was used as a multivariate strategy for the evaluation of seven factors/variables at once, while central composite were used to found optimum values of significant variables. The accuracy of the proposed methods was assessed by analyzing certified reference (CRM); Virginia tobacco leaves (CTA-VTL-2). The results being compared with those obtained by conventional wet acid digestion method. The result obtained by optimized method showed good agreement with the certified values and sufficiently high recovery 97.8 and 98.7% for Cd and Ni, respectively. Under optimal conditions, the detection limits (3σ) were evaluated to be 0.019 μg g⁻¹ for Cd and 0.37 μg g⁻¹ for Ni. The proposed method was successfully applied to the determination of Cd and Ni in raw, processed tobacco and different branded cigarettes samples.     

An Effective Power-Aware At-Speed Test Methodology for IP Qualification and Characterization

Advanced nanometer technologies have led to a drastic increase in operational frequencies resulting in the performance of circuits becoming increasingly vulnerable to timing variations. The increasing process spread in advanced nanometer nodes poses considerable challenges in predicting post-fabrication silicon performance from timing models. Thus, there is a great need to qualify basic building structures on silicon in terms of critical parameters before they could be integrated within a complex System-on-Chip (SoC). The work of this paper presents a configurable circuit and an associated power-aware at-speed test methodology for the purpose of qualifying basic standard cells and complex IP structures to detect the presence of timing faults. Our design has been embedded within test-chips used for the development of the 28 nm Fully Depleted Silicon On Insulator (FD-SOI) technology node. The relevant silicon results and analysis validate the proposed power-aware test methodology for qualification and characterization of IPs and provide deeper insights for process improvements.     

STRESS ANALYSIS OF ALUMINA COATINGS ON SILICON CARBIDE BASED REFRACTORIES DURING THERMAL CYCLING

It is possible to enhance the high tempera-ture oxidation resistance and thus prolong the life time of non-oxide refractories by the application of oxide coating. In this -work, silicon nitride bonded silicon carbide refractories were coated with alumina using the plasma spraying technique. X-ray diffraction shouted r-Al2O3 to be the dominent phase in the as-sprayed alumina coatings. The stresses developed in the coating layer during post-spray heat-treatment have been analysed. It was found that the coating-was under a compressive stress below,but when heated above 1100C , the r-Al2O3 phase transformed into a-Al2O3 and this led to the formation of a destructive tensile stress(up to 1700 MPa) which caused cracks to form in and along the iveak bond between the alumina coating and SiC grains. The coatings then delaminated and of fered little protection to the refractory substrate from oxidation. Future research will be directed on the avoidance oj metastable phase formation in the plasma sprayed coating a     

A newly synthesized single crystal zinc complex as molecular electrocatalyst for efficient hydrogen generation from neutral aqueous solutions

A new chlorobis(2-aminomethylbenzimidazole)zinc(II) perchlorate complex [Zn(AMB)₂Cl](ClO₄) 1 has been synthesized and characterized. Spectral and X-ray structural features led to the conclusion that the zinc(II) complex has a square-pyramidal environment around zinc(II) center with coordination chromophore ZnN₄Cl. Different amounts of complex 1 were supported on glassy carbon (GC) electrode yielding three GC-supported complex 1 electrodes with different loading densities (0.2, 0.4, and 0.8 mg cm^?2). These electrodes were tested as molecular electrocatalysts for the hydrogen evolution reaction (HER) in phosphate buffer aqueous solutions (pH 7), employing linear sweep voltammetry (LSV) and electrochemical impedance spectroscopy (EIS). Results showed that GC-complex 1 catalysts are highly active for the HER, and this catalytic activity enhances with the loading density. The one with the highest loading density (0.8 mg cm^?2) exhibited high HER catalytic activity with low onset potential of ?140 mV vs. RHE and a high exchange current density of 0.22 mA cm^?2. It required an overpotential of 240 mV to achieve a current density of 10 mA cm^?2. It also recorded a turnover frequency (TOF) of 1722 mol of hydrogen per mole of catalyst per hour at overpotential 500 mV, which is comparable with the most active molecular electrocatalysts reported in the literature for H₂ generation from aqueous neutral solutions. A catalytic cycle is proposed for the generation of hydrogen by complex 1 and the mechanism of the HER is discussed based on the measured Tafel slope (140 mV dec^?1).