Development of a toroidal-shaped differential mobility analyzer for effective measurements of airborne particles: Experiment and modeling

Abstract

A toroidal-shaped differential mobility analyzer (DMA), called toroidal Hanyang-DMA (toroidal Hy-DMA), was developed for particle characterization. The height, width, and weight of the newly developed toroidal Hy-DMA are 8?cm, 14?cm, and 1.2?kg, respectively, indicating that it is much more compact and lighter than the TSI long-DMA; nevertheless, the classifiable particle size range is up to 400?nm. Therefore, the toroidal Hy-DMA can be useful for many applications in a limited space owing to its small size. The performance of the Hy-DMA was evaluated using tandem differential mobility analyzer (TDMA) experiments with two identical Hy-DMAs and numerical simulations using a single-particle tracking analysis in a Lagrangian framework. To simulate particle behaviors, a flow-rate-weighted particle injection method, which is more realistic, was employed, and the proposed particle tracking method can be widely applied to any non-plug flow conditions. The obtained experimental data and numerical results of central particle sizes are consistent with each other. Empirical and numerical transfer functions of the toroidal Hy-DMA were obtained and compared with those of other types of well-known DMAs. It is concluded that the toroidal Hy-DMA has an empirical transmission probability ranging from 0.5 to 0.9 and a sizing resolution ranging from 5.5 to 9.0, which indicates acceptable performance in classifying monodisperse particles within the test size range of 20 to 400?nm.

Copyright © 2019 American Association for Aerosol Research     

Determination of Inversion Temperature of Sb2O3-Doped BaTiO3 Positive Temperature Coefficient of Resistivity (PTCR) Ceramics by the Finite Difference Method

The effect of the cooling rate on the PTCR (positive temperature coefficient of resistivity) characteristics of 0.1 mol% Sb₂O₃-doped BaTiO₃ ceramics has been investigated. Resistances both below and above the Curie temperature were increased by slow cooling, which indicated that the resistive layer width at the grain boundary increased as the cooling rate decreased. Concentration profiles of the Ba vacancies as a function of distance from the grain boundary have been simulated by the finite difference method. The inversion temperature of the 0.1 mol% Sb₂O₃-doped BaTiO₃ system was determined to be 1160°C from the measured electrical properties and computed concentration profiles.     

Effect of substrate on the phase transformation of TiO2 in pearlescent pigment

The TiO₂/substrate pearlescent pigments were prepared by the hydrolysis of TiOCl₂ on the substrate followed by a calcinations process. The natural mica (muscovite), synthetic mica (fluorophlogopite) and -alumina flake were selected as the substrates for pearlescent pigments. The effect of substrate on the anatase to rutile (A–R) phase transformation of TiO₂ was studied. The A–R phase transformation of TiO₂ during the preparation of pearlescent pigments and their proportion in the TiO₂ layer have been analyzed by XRD measurements. The phase compositions of TiO₂ layer in each pearlescent pigment are quite different depending on the substrates. The TiO₂ layer deposited on -alumina has higher rutile fraction than those on the natural and synthetic mica. The XPS analysis showed that the cations originally present in the substrates diffused into the TiO₂ layer. The TiO₂ layer deposited on -alumina contains Al, while those on the natural and synthetic mica substrates contain Si and K in addition to Al. The metal cations diffusing from the substrate into TiO₂ layer might retard the A–R phase transformation of TiO₂. The suppressing effect on the A–R transformation of TiO₂ by mixed cations seems to be much stronger than that of single cation, resulting in relatively higher rutile fraction in the case of TiO₂ layer deposited on -alumina.     

Lipid production in Porphyridium cruentum grown under different culture conditions

Autotrophic growth of Porphyridium cruentum under 18:12 h and 12:12 h light:dark cycles showed the maximum cell concentration of 2.1 g-dry wt./L, whereas the specific growth rate, 0.042 (1/h), at 18:6 h is faster than that of 12:12 h, 0.031 (1/h), respectively. The highest lipid accumulation level, 19.3 (%, w/w), was achieved at 12:12 h cycle. Under dark cultivation condition with 10 g/L of glucose, the lipid accumulation in the cell was 10.9 (%, w/w), whereas the heterotrophic growth with glycerol as the carbon resource showed low level of cell concentration and lipid production, compared to that of glucose. The glucose was decided to be a suitable carbon resource for the heterotrophic growth of P. cruentum. The lipids from P. cruentum seemed be feasible for biodiesel production, because over 30% of the lipid was C₁₆–C_18:1. The cultivation time and temperature were important factors to increase the maximum cell concentration. Extending the cultivation time helps maintain the maximum cell concentration, and higher lipid accumulation was achieved at 25 °C, compared to 35 °C. The fed-batch cultures showed that, under the light condition, the specific production rate was slightly decreased to 0.4% lipid/g-dry wt./day at the later stage, whereas, under the dark condition, the specific production rate was maintained to be a maximum value of 1.1% lipid/g-dry wt./day, even in the later stage of cultivation. The results indicate that the heterotrophic or 12:12 h cyclic mixotrophic growth of P. cruentum could be used for the production of biodiesel in long-term fed-batch cultivation of P. cruentum.     

Experimental research on thermal comfort in the university classroom of regular semesters in Korea

This research has investigated physical variables affecting indoor thermal comfort and subjective responses of thermal comfort of students in a university in Korea in which the weather is oceanic temperate climate, and has been performed to contribute to the research fields of Sustainable Thermal Standard and Adaptive Thermal Comfort (ATC). This research is based on the ISO 7730-2005 standard and the ATC theories and 4 main variables of PMV such as dry bulb temperature (Ta), relative humidity (RH), black bulb temperature (Tg), and air velocity (Va) are measured once a week during two regular semesters. A clothing insulation, a thermal sensation vote (TSV), an acceptability of thermal environment, and a preference for cooling and heating are investigated at the same time using a questionnaire. This study was carried out for 26 weeks during the spring season, from March to June 2009, and the autumn season, from September to December 2009. The main achievements of this study are as follows. Monthly Mean Outdoor Temperature (MMOT) and Operative Temperature (OT) in the classroom during research periods are 7.4∼23.3°C and 17.5∼29.0°C, respectively. The acceptability ratio of thermal environment shows over 80% when the range of OT in the classroom is 17∼25°C, and the range can be applicable to operative index of heating and cooling of classroom. The mean TSV of respondents is almost “neutral (0)” when the PMV in the classroom moves to “neutral (0)” and “slightly cool (−1)”, and the TSV is almost “+1.5” when the PMV moves to “slightly warm (+1)”. The acceptability ratio of thermal environment is slightly different from ASHRAE Standard 55-2004. So it is necessary to more investigate standard range of acceptability of thermal environment in oceanic temperate climate region using much more databases.     

Photocatalytic activity of metal ion (Fe or W) doped titania

Iron or tungsten-doped nano TiO₂ were successfully synthesized from TiCl₄. All of the samples showed anatase phase of TiO₂. For the iron-doped TiO₂, Iron ion was well dispersed in the TiO₂ lattice. However, tungsten-doped TiO₂ formed 12-tungstate with anatase TiO₂. As the concentration of tungsten increased, 12-tungstate disappeared. The photocatalytic oxidation of acetaldehyde was evaluated to examine the photocatalytic characteristics of metal-doped TiO₂. Because of the surface containing metal oxide or metal precursors at high concentration metal ion, increasing the concentration of W or Fe ion decreased the reactivity. The reaction rate was drastically increased after 300 °C heat treatment. Furthermore, the photocatalytic activity of iron- or tungsten-doped TiO₂ was higher than that of synthesized pure TiO₂ and commercial TiO₂.     

Synthesis of Low-Dielectric Silica Aerogel Films by Ambient Drying

A new ambient drying process that is simple, effective, and reproducible has been developed to synthesize low- k SiO₂ aerogel thin films for intermetal dielectric (IMD) materials. The SiO₂ aerogel films having a thickness of 9500 Å, a high porosity of 79.5%, and a low dielectric constant of 2.0 were obtained by a new ambient drying process using n -heptane as a drying solvent.     

Reverse‐Conducting IGBT Using MEMS Technology on the Wafer Back Side

In this paper, we present a 600‐V reverse conducting insulated gate bipolar transistor (RC‐IGBT) for soft and hard switching applications, such as general purpose inverters. The newly developed RC‐IGBT uses the deep reactive‐ion etching trench technology without the thin wafer process technology. Therefore, a freewheeling diode (FWD) is monolithically integrated in an IGBT chip. The proposed RC‐IGBT operates as an IGBT in forward conducting mode and as an FWD in reverse conducting mode. Also, to avoid the destructive failure of the gate oxide under the surge current and abnormal conditions, a protective Zener diode is successfully integrated in the gate electrode without compromising the operation performance of the IGBT.     

Rule-based personalized comparison shopping including delivery cost

Comparison shopping allows customers to reduce time and effort when searching for product information and prices. However, traditional comparison sites mainly compare product prices without using precise information on delivery cost. To overcome this limitation, we adopted a rule-based comparison shopping framework using the eXtensible Rule Markup Language (XRML) architecture, which computes the exact personalized delivery cost at comparison sites. The prototype ConsiderD, which was developed for this purpose, computes the exact delivery costs considering the shipping rules, destination, delivery speed, and shipping rates. The XRML architecture effectively maintains the consistency of formal rules with the original Web pages. To demonstrate the performance of rule-based comparisons, we conducted an experiment on the purchase of books based on real-world data from five leading online bookstores. This experiment shows that rule-based comparison can significantly outperform data-based comparison in terms of the total cost of product and delivery. We also found that the comparison of delivery cost is very important because the variance of delivery cost can be as big as the variance of book prices itself.