The electrochemical behaviour of nitrogen-containing austenitic stainless steel in methanolic solution

The corrosion behaviour of nitrogen-containing austenitic stainless steel in methanol containing different concentrations of H₂SO₄, HCl, LiCl and H₂SO₄ + HCl has been investigated using a potentiostatic polarization method. The cathodic reaction in the H₂SO₄, HCl and H₂SO₄ + HCl solutions was proton reduction whereas in the neutral LiCl solution, oxygen reduction was the predominant cathodic reaction. Active, passive and transpassive behaviours were observed only for higher concentrations of H₂SO₄ (0.01–2.0 M) due to the inherent water content. A cathodic loop, characterized by measured negative current in the anodic region, was also observed in solutions, in which the concentration of H₂SO₄ was 1.0 M or higher. The relative stability of the passive films decreased as the H₂SO₄ concentration increased, and thus the steel suffered from mild pitting corrosion. In the chloride environment, the rate of corrosion increased as the Cl⁻ ion concentration increased. The presence of acid along with Cl⁻ ions enhanced corrosion, and the corrosion rate increased significantly. The steel suffered from mild intergranular corrosion in acidic chloride solutions of methanol. In the H₂SO₄ + HCl solutions, passive films were only formed when the H₂SO₄ to HCl concentration ratio was greater than ∼10:1.     

The sliding-window packet switch: a new class of packet switch architecture with plural memory modules and decentralized control

Shared-memory based packet switches are known to provide the best possible throughput performance for bursty data traffic in high-speed packet networks and internets compared with other buffering strategies under conditions of identical memory resources deployed in the switch. However, scaling of shared-memory packet switches to a larger size has been restricted mainly due to the physical limitations imposed by the memory-access speed and the centralized control for switching functions in shared-memory switches. A new scalable architecture for a shared-memory packet switch, called the sliding-window (SW) switch, is proposed to overcome these limitations. The SW switch introduces a new class of switching architecture, where physically separate multiple memory modules are logically shared among all the ports of the switch, and the control is decentralized. The SW switch alleviates the bottleneck caused by the centralized control of switching functions in large shared-memory switches. Decentralized switching functions enable the SW switch to operate in a pipeline fashion to enhance scalability and switching capacity compared with that of previously known classes of shared-memory switch architecture.     

Synthesis and properties of star-like wholly aromatic polyester fibers

Novel star-like wholly aromatic copolyesters having four arms based on a tetraamine star core, p- and m- hydroxybenzoic acids and 6-hydroxy-2-naphthoic acid have been successfully synthesized and spun into fibers for the investigation of the effect of the star-like structure on improving compressive properties of the fiber. The reactivity of the star core was demonstrated using a model compound with FTIR, ¹H and ¹³C NMR spectroscopy. The ¹³C NMR spectrum of the star-like terpolymer having a molar ratio of 10:1 of the monomers to star core showed a characteristic peak at around δ62 ppm which corresponds to a tetra-substituted carbon and thereby demonstrates that the star core was really incorporated into the polymer. The star-like copolyester exhibited a clear stir opalescence and liquid crystalline morphology in the temperature range of 150-280 °C. However, no transition was observed in the DSC thermogram except a clear T_g at 110 °C. The star-like terpolymer fiber, prepared from a polymer with a molar ratio of 500:1 for the monomers to imide core, was spun in the liquid crystalline state at 180 °C. Fiber structure and properties have been studied.     

Copper(II) removal from aqueous solutions by fly ash

The removal of Cu(II) by adsorption on fly ash has been found to be concentration, pH and temperature dependent. The kinetics of adsorption indicates the process to be diffusion controlled. The Langmuir constants have been calculated at different temperatures, and the adsorption has been found to be endothermic (ΔH = 15.652 kcal mol^?1). The maximum removal is observed at pH 8.0, and variation in adsorption with pH has been explained on the basis of surface ionisation and complexation.     

On certain classes of exact solutions of Einstein equations for rotating fields in conventional and nonconventional form

Using the symmetry reduction approach we have herein examined, under continuous groups of transformations, the invariance of Einstein exterior equations for stationary axisymmetric and rotating case, in conventional and nonconventional forms, that is a coupled system of nonlinear partial differential equations of second order. More specifically, the said technique yields the invariant transformation that reduces the given system of partial differential equations to a system of nonlinear ordinary differential equations (nlodes) which, in the case of conventional form, is reduced to a single nlode of second order. The first integral of the resulting nlode has been obtained via invariant-variational principle and Noether’s theorem and involves an integration constant. Depending upon the choice of the arbitrary constant two different forms of the exact solutions are indicated. The generalized forms of Weyl and Schwarzschild solutions for the case of no spin have also been deduced as particular cases. Investigation of nonconventional form of Einstein exterior equations has not only led to the recovery of solutions obtained through conventional form but it also yields physically important asymptotically flat solutions. In a particular case, a single third order nlode has been derived which evidently opens up the possibility of finding many further interesting solutions of the exterior field equations.     

Theoretical investigation of penetration characteristics in gas metal-arc welding using finite element method

In the modeling of the gas metal-arc (GMA) welding process, heat inputs to the workpiece by the arc and the metal transfers have been considered separately. The heat energy delivered due to the metal transfer has been approximated in the form of a cylindrical volumetric heat source, whose dimensions of the radius and the height are dependent on the molten metal droplet characteristics. The pinch instability theory (PIT) and the static force balance theory (SFBT) of drop detachment have independently been used to obtain the expressions for various characteristics of the drop,i.e., the drop radius, the drop velocity, and the drop frequency at various welding parameters. The occurrence or the nonoccurrence of finger penetration, routinely found in the GMA welding at high welding currents, has been satisfactorily explained by the cylindrical heat source model. The effect of various welding parameters,e.g., the welding current, the wire radiusetc., on the weld bead penetration characteristics has been investigated. In this modeling effort, the heat conduction equation has been solved in three dimensions.     

An analysis of the electrical conductivity in BaSO4-added Ag2SO4 solid electrolyte system

The compositions (1 −x)Ag₂SO₄−(x)BaSO₄, wherex=0·01 to 0·6, were prepared by slow cooling of the melt. The extent of the solid solubility of Ba²⁺ in Ag₂SO₄ was determined by X-ray powder diffraction and scanning electron microscopy. The bulk conductivity of each sample was obtained using a detailed impedance analysis. The partial substitution of Ba²⁺ results in the enhancement of conductivity in compliance with the classical aliovalent doping theory. A simplistic model based on lattice distortion (expansion) due to partial substitution of Ag⁺ by the bigger Ba²⁺ has been considered to explain enhanced conductivity. Beyond solid-solubility limit (5·27 mole%) the BaSO₄-dispersed Ag₂SO₄ conductivity follows the usual trend seen in binary systems. An increase in conductivity in this case is discussed in the light of interfacial reactions and surface defect chemistry. The maximum conductivity in 20 mole% BaSO₄ dispersed Ag₂SO₄ is due to percolation threshold.     

Off-line quality control for V-process castings

In the present work Taguchi's approach has been applied to the V-process castings of Al-11 per cent Si alloy to acertain the most influential control factors which will provide better and consistent surface finish to the castings regardless of the noise factors present. The control factors of the V-process that may affect the quality of the castings are the molding sand, vibration frequency, vibrating time, degree of vacuum imposed, and pouring temperature. In order to understand how these factors affect the surface roughness of the V-process castings, response surface methodology has been applied, and to obtain the optimal setting of the control factors Taguchi's method has been used. It is found that the pouring temperature has a significant effect on the surface roughness of Al-11 per cent Si alloy castings made by a V-process. Thus the pouring temperature must be kept at the lower level. All other factors are insignificant. Therefore, any setting of the insignificant factors/variables that give the minimum cost can be used.     

Response spectrum analysis of piping systems with elastic-plastic gap supports

A new seismic support device and its application in piping systems is described. The device, E-BAR (patented), can be cost effectively used for snubber replacement programs, mitigation of hydraulic transients, pipe whip and as a thermal stop. The device has pre-set gaps to allow free thermal movement. During a seismic or other dynamic load event, if the pipe movement exceeds the gap dimension, the device acts as an elastic or elastic-plastic restraint. The device also has a unique design feature for not exceeding the restraint force beyond a specified limit design value. To analyze piping systems with gap supports having elastic-plastic characteristics, modal analysis procedures for both response spectrum and time history methods are developed. The comparison of responses obtained from the procedures with nonlinear time history analysis and test results available in the literature shows excellent correlation. A pilot program conducted for snubber replacement with E-BARs demonstrates that the limit force feature of E-BAR makes them very attractive for snubber replacement. This is because a particular E-BAR with a specified limit design force can be selected, such that, the E-BAR replacing the snubber does not require any modifications be made to the existing support steel and hardware.