全文获取类型
收费全文 | 249篇 |
免费 | 10篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 23篇 |
化学工业 | 59篇 |
金属工艺 | 4篇 |
机械仪表 | 4篇 |
建筑科学 | 6篇 |
能源动力 | 14篇 |
轻工业 | 32篇 |
水利工程 | 2篇 |
石油天然气 | 1篇 |
无线电 | 19篇 |
一般工业技术 | 33篇 |
冶金工业 | 26篇 |
自动化技术 | 37篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 10篇 |
2020年 | 2篇 |
2019年 | 1篇 |
2018年 | 12篇 |
2017年 | 4篇 |
2016年 | 9篇 |
2015年 | 9篇 |
2014年 | 15篇 |
2013年 | 14篇 |
2012年 | 20篇 |
2011年 | 23篇 |
2010年 | 12篇 |
2009年 | 19篇 |
2008年 | 9篇 |
2007年 | 7篇 |
2006年 | 11篇 |
2005年 | 5篇 |
2004年 | 7篇 |
2003年 | 6篇 |
2002年 | 5篇 |
2001年 | 6篇 |
2000年 | 4篇 |
1999年 | 2篇 |
1998年 | 6篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 1篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1992年 | 3篇 |
1990年 | 2篇 |
1989年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1983年 | 3篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有260条查询结果,搜索用时 15 毫秒
31.
Characterization of Cu Nanoparticles on TiO2 Photocatalysts Fabricated by Electroless Plating Method
Zheng Wang Kentaro Teramura Tetsuya Shishido Tsunehiro Tanaka 《Topics in Catalysis》2014,57(10-13):975-983
Cu-modified TiO2 photocatalysts (Cu/TiO2) were fabricated by electroless plating and wet impregnation methods. Photocatalytic activity for H2 production over Cu/TiO2 by electroless plating method was higher than that over Cu/TiO2 by impregnation method. Characterization of Cu nanoparticles by HRTEM, STEM-EDX, XRD and XAFS was studied. As compared to the wet impregnation method, the electroless plating method resulted in the formation of Cu nanoparticles with small size and uniform distribution on the TiO2 surface, which caused the enhancement of H2 production. XAFS measurement provided the evidences for the chemical state change of Cu species during the photocatalytic reaction. The process that Cu species varied from Cu2+ into Cu0 via Cu1+ as the intermediate under photoirradiation is very important for the H2 production, which indicates that the metallic Cu nanoparticles acted as the active sites and restrained the photogenerated charges recombination. 相似文献
32.
Aki Sorsa Ari Isokangas Suvi Santa-aho Minnamari Vippola Toivo Lepistö Kauko Leiviskä 《Journal of Nondestructive Evaluation》2014,33(1):43-50
Residual stresses are quantitatively predicted based on the Barkhausen noise measurement with a partial least squares regression model. The measurements are taken from two sets of case-hardened samples. The benefits of using certain feature elimination strategies prior model identification are also studied. The elimination methods applied are correlation-based elimination, uninformative variable elimination and successive projections algorithm. The results show that the best predictions are usually obtained when the successive projections algorithm is applied. The prediction accuracy of the best models found shows that partial least squares models can be successfully used for prediction of material properties based on the Barkhausen noise measurement. 相似文献
33.
34.
Three kinds of energy service system were examined as alternative energy systems in urban areas. A comparison of these energy systems was performed by finding Pareto optimum solutions for a multi-objective model. The model had two objective functions: CO2 emission and cost to consumer. Various energy pricings were provided in the model as variables. 相似文献
35.
Introduction of an integrated energy service system in an urban area is assumed. An energy supply plant is installed in the area to provide integrated energy service. It supplies electricity, gas, cooling, and heating to consumers. To consider CO/sub 2/ emission constraint in the area, analyses of energy pricing, economic impact on energy consumers, and operation of the system under the constraint of CO/sub 2/ emission were performed. CO/sub 2/ emission and economic impact on the consumers and the supplier of various energy pricing scenarios were calculated using linear programming models. The solution that satisfied the CO/sub 2/ emission restriction, and was economically optimal to the consumers was chosen from the results. The chosen solutions are Pareto optimum solutions of a multiobjective problem that concerns both CO/sub 2/ emission and cost to the consumers. 相似文献
36.
37.
Junya Ohyama Yutaka Hitomi Yasuhiro Higuchi Tsunehiro Tanaka 《Topics in Catalysis》2009,52(6-7):852-859
Tetradentate thioacetyl porphyrin ligand (1) was synthesized to protect gold nanoparticles. 1-protected gold nanoparticles were characterized by UV-vis spectroscopy and XPS. Analysis by XPS showed that all of four thioacetyl groups of 1 were dissociated and bound to the surface of gold nanoparticles in thiolate form. The size of 1-protected gold nanoparticles (GN:1) was controlled by thioacetyl group/HAuCl4 molar ratio and approached to 2 nm. Compared with a protecting ligand without porphyrin plane (2) or dodecanethiol, 1 can control the size of gold nanoparticles efficiently probably due to the tetradentate ligation effect. 相似文献
38.
Yasutaka Nagai Kazuhiko Dohmae Kentaro Teramura Tsunehiro Tanaka Gemma Guilera Kazuo Kato Masaharu Nomura Hirofumi Shinjoh Shinichi Matsumoto 《Catalysis Today》2009,145(3-4):279
Two main pivotal subjects of research in automotive catalysts were studied by modern X-ray absorption analysis techniques. One is oxygen storage/release behaviour, and the other is sintering inhibition of Pt particles. First, three types of CeO2–ZrO2 (Ce:Zr = 1:1 molar ratio) compounds with different oxygen storage/release capacities and different structural properties were prepared, and the valence change of Ce as a function of temperature during oxygen release/storage processes was investigated. The reduction of surface Ce mainly occurred in the range 100–170 °C, and the reduction of bulk Ce progressed at high temperatures of 170 °C and above. The Ce reduction behaviour depended not only on the homogeneity of the Ce and Zr for bulk reduction at high temperatures but also on the particle size of the CeO2–ZrO2 samples for surface reduction at low temperatures. Secondly, sintering inhibition of Pt in Pt/Al2O3, Pt/MgO and Pt/ceria-based catalysts after 800 °C ageing in air was studied. We found that the Pt–O–M (M = Mg, Ce) bond acted as an anchor and inhibited the sintering of Pt particles on MgO or ceria-based oxide. Especially, it was noteworthy that the Pt–O–Ce4+ bond on the ceria-based support breaks easily through the reduction of Ce (Ce4+ → Ce3+) during the usual stoichiometric and reducing conditions. 相似文献
39.
40.
Satoshi Hiroi Seongho Choi Shunsuke Nishino Okkyun Seo Yanna Chen Osami Sakata Tsunehiro Takeuchi 《Journal of Electronic Materials》2018,47(6):3113-3118
To gain deep insight into the mechanism of phonon scattering at grain boundaries, we investigated the boundary thermal resistance by using picosecond pulsed-laser time-domain thermoreflectance for epitaxially grown W/Fe2VAl/W films. By using radio-frequency magnetron sputtering, we prepared a series of the three-layer films whose Fe2VAl thickness ranged from 1 nm to 37 nm. The fine oscillation of reflectivity associated with the top W layer clearly appeared in synchrotron x-ray reflectivity measurements, indicating a less obvious mixture of elements at the boundary. The areal heat diffusion time, obtained from the time-domain thermoreflectance signal in the rear-heating front-detection configuration, reduced rapidly in samples whose Fe2VAl layer was thinner than 15 nm. The ~ 10% mismatch in lattice constant between Fe2VAl and W naturally produced the randomly distributed lattice stress near the boundary, causing an effective increase of boundary thermal resistance in the thick samples, but the stress became homogeneous in the thinner layers, which reduced the scattering probability of phonons. 相似文献