Leapfrog cracking and nanoamorphization of ZnO nanowires during in situ electrochemical lithiation

The lithiation reaction of single ZnO nanowire (NW) electrode in a Li-ion nanobattery configuration was observed by in situ transmission electron microscopy. Upon first charge, the single-crystalline NW was transformed into a nanoglass with multiple glassy nanodomains (Gleiter, H. MRS Bulletin2009, 34, 456) by an intriguing reaction mechanism. First, partial lithiation of crystalline NW induced multiple nanocracks ～70 nm ahead of the main lithiation front, which traversed the NW cross-section and divided the NW into multiple segments. This was followed by rapid surface diffusion of Li(+) and solid-state amorphization along the open crack surfaces. Finally the crack surfaces merged, leaving behind a glass-glass interface (GGI). Such reaction front instability also repeated in the interior of each divided segment, further subdividing the NW into different nanoglass domains (nanoamorphization). Instead of the profuse dislocation plasticity seen in SnO(2) NWs (Science2010, 330, 1515), no dislocation was seen and the aforementioned nanocracking was the main precursor to the electrochemically driven solid-state amorphization in ZnO. Ab initio tensile decohesion calculations verified dramatic lithium embrittlement effect in ZnO, but not in SnO(2). This is attributed to the aliovalency of Sn cation (Sn(IV), Sn(II)) in contrast to the electronically more rigid Zn(II) cation.     

Detection of Thermal Radiation,Sensing of Heat Flux,and Recovery of Waste Heat by the Transverse Thermoelectric Effect

The transverse thermoelectric effect is unique in that an output voltage can be extracted in the direction perpendicular to the input temperature gradient. This paper describes how this transverse feature can be exploited to realize simple and promising configurations of thermoelectric devices. For detection of thermal radiation, two-dimensional imaging has been demonstrated by a fabricated sensor array of tilt-oriented Ca _x CoO₂ epitaxial thin film. We have also developed a serpentine heat flux sensor made of multilayered Bi/Cu, and Bi_0.5Sb_1.5Te₃/Ni tubular thermoelectric devices for power generation. The fabrication processes and test results are presented.     

Spectroscopic Characterization of Nanohybrids Consisting of Single-walled Carbon Nanotubes and Fullerodendron

Hydrogen gas, which can be used in fuel cells to generate electricity, is considered the ultimate clean energy source. Recently, it was reported that a photo-induced electron transfer system consisting of single-walled carbon nanotubes (SWCNTs) and fullerodendrons shows photo-catalytic activity with a very high quantum yield for splitting water under visible light irradiation. However, the mechanism of high efficiency hydrogen generation is not yet clearly understood. We report here the spectroscopic characterizations of the SWCNT-fullerodendron composites. The results indicate two important fundamental properties of the composite system. First, fullerodendrons preferentially interact with the semiconducting SWCNTs instead of with their metallic counterparts. Second, the photo-induced electron transfer process from the C₆₀ moiety of fullerodendrons to SWCNTs occurs more efficiently with an increasing tube diameter.     

Mechanical and thermal properties of potassium salts of poly(ethylene‐co‐ethylacrylate): Polyolefin ionomers in the absence of acid groups

The thermal and mechanical properties of ionomers prepared by partial saponification of poly(ethylene‐co‐ethylacrylate) (EEA) with potassium were investigated by using differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA). The Vicat softening temperature (VST) and bending modulus were also evaluated. Molecular design of the present EEA‐based ionomers eliminates acid groups, which affect ionic aggregates for conventional ionomers. The DSC results showed that the melting enthalpy and main crystallization temperature decreased as the ion content increased, whereas on the other hand, the crystal melting temperature at about 360 K did not depend on the ion content, and a secondary exothermal peak was observed in the cooling process. The variance of the VST increased as the crystallinity decreased. The temperature‐dependent curves of DMA data of the EEA‐based potassium ionomers with a higher ion content showed elastic plateau even at temperatures above their crystal melting points. Our results indicate the existence of strong cross‐linking mediated by ion aggregates. The quadratic increase of stiffness as a function of ion content, increasing VST with decreasing crystallinity, and elastic plateau of temperature‐dependent moduli above crystal melting temperature are significant characteristics of the EEA‐based potassium ionomers, which contain ionic aggregations without acid group presence. POLYM. ENG. SCI., 55:1843–1848, 2015. © 2014 Society of Plastics Engineers     

Investigation of false triggering mechanism

This paper discusses a problem that a half‐bridge circuit can generate, namely a false trigger by high‐speed switching transition. In general, a false trigger occurs by charging a gate–source capacitance because of high‐speed voltage transition and influx of current via a reverse transfer capacitance. Therefore, it is thought that the ratio of the input capacitance and the reverse transfer capacitance is important to check whether a false trigger occurs. However, we find another reason and propose a novel assumption. A novel false triggering mechanism appears by considering the source‐side parasitic inductance. © 2013 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc.     

Heat transfer characteristics of the latent heat thermal energy storage capsule

The characteristic variation of the rate of heat transfer to and from a latent heat thermal energy storage capsule was investigated analytically and experimentally. Basic experiments were carried out to simulate a solar energy storage capsule, using a horizontal cylindrical capsule (300 mm length, 40 mm o.d.) filled with naphthalene as the phase change material. The variation of heat flux during the processes of heat storage and removal was measured by a heat flow meter wrapped around the capsule, as the capsule was subjected to stepwise variations of the surface temperature. Finite difference calculations based on heat conduction were also carried out to compare with the experimental results. For the heat removal process, the experimental results and the calculated heat flux agreed well with each other. They showed different characteristic trends for the heat storage process, due to the effects of natural convection.     

Over 27% efficiency GaAs/InGaAs mechanically stacked solar cell

We have applied an InGaAs solar cell (band GAP = 0.75 eV) to the bottom cell of the super-high-efficiency tandem solar cell aiming an over 35% conversion efficiency. The InGaAs cell which is lattice-matched to the InP substrate showed the efficiency of 5.5% under the GaAs substrate with low carrier concentration. Combining with the GaAs cell by means of a mechanically stacking technique, we obtained an efficiency of 28.8% at air mass (AM) 1.5, 1-sun. This result suggests the possibility of the cells with the efficiency of over 35% with combining a GalnP/GaAs monolithic tandem cell and the InGaAs cell (or InGaAsP cell).     

Regional determinants of total factor productivity in Japan: stochastic frontier analysis

As Japan’s birthrate declines and its society ages, governmental policies need to improve the productivity of regional economies in order to sustain regional growth. This study examines social overhead capital and population agglomeration as drivers of total factor productivity (TFP) growth in Japan. The use of stochastic frontier analysis demonstrates that social overhead capital contributes to TFP growth and, especially, influences productive efficiency. Furthermore, the findings reveal that population agglomeration underpins TFP growth in regional economies. Empirical results also indicate that productive efficiency is high in regions where manufacturing is concentrated and that productive efficiency improves when internationally competitive manufacturers concentrate in regional economies. This study endorses the development of social overhead capital to spur Japan’s regional TFP growth. As such, it indicates that providing social infrastructure and enhancing regional productivity are important strategies for the government to consider in its efforts to achieve sustainable regional growth.     

User-assisted in-network caching in information-centric networking

In information-centric networking, in-network caching has the potential to improve network efficiency and content distribution performance by satisfying user requests with cached content rather than downloading the requested content from remote sources. In this respect, users who request, download, and keep the content may be able to contribute to in-network caching by sharing their downloaded content with other users in the same network domain (i.e., user-assisted in-network caching). In this paper, we examine various aspects of user-assisted in-network caching in the hopes of efficiently utilizing user resources to achieve in-network caching. Through simulations, we first show that user-assisted in-network caching has attractive features, such as self-scalable caching, a near-optimal cache hit ratio (that can be achieved when the content is fully cached by the in-network caching) based on stable caching, and performance improvements over in-network caching. We then examine the caching strategy of user-assisted in-network caching. We examine three caching strategies based on a centralized server that maintains all content availability information and informs each user of what to cache. We also examine three caching strategies based on each user’s content availability information. We first show that the caching strategy affects the distribution of upload overhead across users and the number of cache hits in each segment. One interesting observation is that, even with a small storage space (i.e., 0.1% of the content size per user), the centralized and distributed approaches improve the cache hit ratio by 50% and 45%, respectively. With an overall view of caching information, the centralized approach can achieve a higher cache hit ratio than the distributed approach. Based on this observation, we discuss a distributed approach with a larger view of caching information than the distributed approach and, through simulations, confirm that a larger view leads to a higher cache hit ratio. Another interesting observation is that the random distributed strategy yields comparable performance to more complex strategies.