Thermal decomposition of cellulose/synthetic polymer blends containing grafted products. V. Cellulose/polystyrene blends

Homogeneous grafting of styrene onto cellulose was carried out in a dimethylacetamide/lithium chloride solvent system. The grafted products were added to cellulose/polystyrene (PS) blends as compatibilizers. The thermal decomposition behavior of the blends was investigated by thermogravimetry. The thermal stability of the blends decreased with an increase in grafted product content. The crystallinity of the blends decreased with grafted product content. The microphase‐separated structures of the blends became finer with grafted product content. The glass transition temperatures for cellulose and PS in the blends were lowered with grafted product content. Differences in thermal decomposition behavior of the blends were correlated with compatibility. Thermogravimetry was effective for compatibility estimation in cellulose/PS blends containing grafted products. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Morphology of CuO through precipitation process under 2.45 GHz microwave irradiation

The morphology of CuO powders formed by a homogeneous precipitation process from aqueous copper precursor complex was investigated. The effect of 2.45 GHz microwave irradiation appeared in the characteristic morphology of the CuO microcrystal with comparison of an ordinal synthesis process. The crystallographic orientation of CuO microcrystals in the particle was examined by HRTEM. Using microwave irradiation, it was demonstrated that the morphology of the particles was kept through the decomposition of the precursor. Also the rapid transformation of a precursor to CuO in aqueous solution under microwave irradiation condition was discussed.     

Design and manufacturing of JT-60SA vacuum vessel

JT-60 is planned to be upgraded to JT-60SA tokamak machine with fully superconducting coils, which is a project of the JA-EU satellite tokamak program under both Broader Approach program and Japanese domestic program. The JT-60SA vacuum vessel (VV) has a D-shape poloidal cross section and a toroidal configuration with 10° facet segmented in toroidal direction. The material of the VV is 316L stainless steel with low cobalt content of <0.05 wt%. A double wall structure is adopted for the VV to ensure high rigidity and high toroidal one-turn resistance simultaneously.Fundamental welding R&D and a trial manufacturing of the 20° upper half of the VV have been performed to study the manufacturing procedure. After the confirmation of the quality of the mock-up, manufacturing of the actual VV started in November 2009.     

Rheological studies of nickel oxide and quartz/hematite mixture systems

This study aimed to investigate the rheology of two-mineral mixture systems as a function of pH and solid concentration. Single minerals (nickel oxide, quartz and hematite) and two-mineral systems (nickel oxide–quartz and nickel oxide–hematite) were studied. Rheology tests were conducted to investigate the effect of pH and solid concentration on shear yield stress of suspensions while zeta potential measurements of suspensions were used to explain the rheology results. Rheology results indicated that single mineral experiments showed that 5 and 10 vol.% of quartz and hematite had no shear yield stress whereas the one of nickel oxide was positive value. Shear yield stress of nickel oxide–quartz mixture and nickel oxide–hematite mixtures increased as increasing pH and solid concentration, and the value was higher than the one obtained with only nickel oxide. These results obtained with two-mineral mixture systems were explained by electrokinetic properties of the minerals, i.e. zeta potential of the minerals.     

Simplified method for determining cadmium concentrations in rice foliage and soil by using a biosensor kit with immunochromatography

BACKGROUND: The behavior of cadmium in ecosystems needs to be monitored because of the human toxicity of this heavy metal. The need recently arose for a simple and quick on‐site test for trace levels of Cd in food and environmental samples. In response, an immunochromatographic assay kit for detecting Cd was manufactured by Kansai Electric Power Co. of Japan. This kit uses the antigen–antibody complex reaction between the Cd–EDTA complex and an anti‐Cd–EDTA antibody and shows the results in terms of the degree of color developed on a test paper. We previously reported the successful use of this kit to determine Cd concentrations in brown rice. Here, we applied the kit to the determination of Cd concentrations in rice foliage and soil. RESULTS: Cadmium in rice foliage was not extracted successfully by the method used for brown rice. However, it was successfully extracted by 0.1 mol L^?1 HCl solution at a rice foliage:HCl ratio of 1:20, and coexisting metals were removed sufficiently by the column treatment. The Cd concentrations determined by immunochromatographic assay were well correlated with the values obtained by acid decomposition and inductively coupled plasma mass spectrometry. The 0.1 mol L^?1 HCl‐extractable Cd concentration in soil was also determined successfully with the kit. CONCLUSION: Approximate Cd concentrations in rice plants and 0.1 mol L^?1 HCl‐extractable Cd concentrations in soil can be monitored easily and quickly by this method at locations where facilities for acid digestion and precision analysis are not available. Copyright © 2009 Society of Chemical Industry     

Power characteristics of unsteadily forward–reverse rotating impellers in an unbaffled aerated agitated vessel

Power characteristics of an unbaffled aerated agitated vessel with unsteadily forward‐reverse rotating impellers, ie a new type of gas–liquid agitator named ‘AJITER’, treating viscous Newtonian liquids were studied experimentally. Measurements were first made on the agitation torque, ie the torque on the drive shaft on which forward–reverse rotating impellers with four delta‐type blades were attached, and the data obtained were analyzed by fitting them to an equation consisting of two terms with respect to the resistance of the fluid, one due to viscous drag and the other due to added moment of inertia. The effects of operating conditions and physical properties of liquids on the drag and added moment of inertia coefficients were then evaluated, and empirical relationships which estimate values of these coefficients, useful to predict the unsteady behavior and magnitude of agitation torque, were presented. Furthermore, equations were developed for estimating the average and maximum power consumptions as a function of the drag and added moment of inertia coefficients. Prediction of respective power levels in AJITER by these equations was also discussed. © 2001 Society of Chemical Industry     

Preparation of surfactant-free vinyl polymers by conventional emulsion polymerization using hydrolysable emulsifiers

Emulsion polymerizations of several vinyl monomers, styrene, methyl methacrylate, butyl methacrylate, butyl acrylate, and vinyl acetate, in water using alkali–hydrolysable cationic surfactants with a betaine ester group (1-alkoxycarbonylmethyl)trimethylammonium chlorides, as emulsifiers were carried out and properties of the resulting latices and the polymers recovered by hydrolysis and salting out were investigated. There were little influences of the surfactants and monomers used here on the polymerizations, forming stable and monodisperse latices with a mean diameter of ca. 70 nm and giving a high molecular weight of polymers at high yields. All polymers were precipitated and recovered by adding a small amount of sodium hydroxide into the latex solutions contained little amount of ionic species. Solvent-cast films of the polymers were found to have surfaces as hydrophobic as those for the corresponding pure polymers prepared by bulk polymerization.     

循环荷载下圆柱和I型钢筋混凝土剪力墙的能量消耗与损伤分析

采用非线性有限元方法,对循环荷载下圆柱和Ⅰ型钢筋混凝土剪力墙进行试验,通过能量消耗分析评估其损伤。首先,通过对荷载-位移关系、裂缝情况的研究以及经过分析所得的总应变能与试验加载能量的比较,验证分析方法的有效性。其次,对能量消耗分布以及钢筋和混凝土的配置进行研究。研究表明:能量消耗是评估剪力墙损伤的有效方法。     

Fundamental Behavior of Direct-Coupled Submicrosecond Pulse Energization in Electrostatic Precipitators

The fundamental characteristics of the direct-coupled pulse energization in electrostatic precipitators (EP's) are investigated in a test rig comprised of a coal pulverizing facility, a furnace, a gas cooling system, and an EP. The EP consisted of a corona electrode with barbed wires and a collection electrode with 300-mm duct spacing. This simulates the type of EP normally used in a coal-fired power station. The pulse-energized collection field shows a very high collection performance of more than 99 percent collection efficiency and the performance enhancement compared to the conventional dc energization, causing very severe back corona, becomes as large as H = 2.50.H is the enhancement factor in terms of the Deutsch migration velocity in the case of the very high resistivity dust of rd = 2 x 1013 ?cm at the gas temperature of Tg = 150°C. Even at the lower level of the dust resistivity at Tg = 110°C, where no back corona occurs in the dc-energized collection field, the performance enhancement is as large as H = 1.21. The mechanism of such great performance enhancement is likely to be the result of the very uniform and very intense formation of corona plasmas on the wires as a result of the very fast rise in the pulse voltage applied and a special sawtooth waveform of the operating voltage between the corona and collection electrodes.