Grain-shape parameters for high-temperature creep resistance in powder metallurgy tungsten fine wires

Three grain-shape parameters, f ₁, f ₂, and f ₃, are defined to clarify the morphological effect of grains on the high-temperature creep resistance under the condition that no grain boundary cavitation occurs. The parameter f ₁ is characteristic of complicated grain shapes, suggesting that it can be a measure of the interlocking grain structure. The parameter f ₂ is an important parameter when torsional stresses are imposed on coiled wires, and f ₃ is characteristic of the short-range roughness of grain boundaries only when f ₁ is not greatly changed. The minimum creep rate decreases as the grain aspect ratio, R, increases for R <30, and the creep rate increases as R increases for R >30. The parameter f ₁, as well as Raj and Ashby’s model, gives a satisfactory explanation for the former behavior. On the other hand, it is proven that their model must be modified using f ₃ to explain the latter behavior because of the highly elongated grain configuration that is associated with R >30.     

R‐learning with multiple state‐action value tables

We propose a method to improve the performance of R‐learning, a reinforcement learning algorithm, by using multiple state‐action value tables. Unlike Q‐ or Sarsa learning, R‐learning learns a policy to maximize undiscounted rewards. Multiple state‐action value tables cause substantial explorations as needed and make R‐learning work well. Efficiency of the proposed method is verified through experiments in a simulated environment. © 2007 Wiley Periodicals, Inc. Electr Eng Jpn, 159(3): 34– 47, 2007; Published online in Wiley InterScience ( www.interscience. wiley.com ). DOI 10.1002/eej.20473     

Tribo-electrification of particles under sudden change of fluid flow in the junction between branch pipe and straight pipe

An experimental investigation of the tribo-electrification of glass beads fed by an ejector has been conducted by measuring both the current generated at the pipe wall and the specific-charge measured by a Faraday cage under sudden change of fluid flow in the junction between a stainless-steel branch pipe and a stainless-steel straight pipe. In measuring a current per unit mass, for D_p,50 ? 206 μm at the branch pipe section the current has a positive value as expected by the contact potential difference between glass beads and stainless-steel. On the other hand, for D_p,50 ? 105 μm at the branch and straight pipe section, the current has a negative value couldn’t be explained solely by the contact potential difference. In measuring a specific-charge by the Faraday cage, the specific-charge has a negative highest value at the ejector. The negative specific-charge decreases along the particle flow direction. Therefore, an “unusual” charge-transfer, which couldn’t be explained solely by the contact potential difference, was confirmed also by the Faraday cage. Although the charge-transfer between the beads and the inclined stainless plate with high impact speed has been examined, the sign of the current is positive for all data. It was found that the “unusual” charge-transfer in this study couldn’t be caused by the high speed impaction. An negative current in air by using a stainless steel needle detected at the ejector for D_p,50 = 51 μm while an positive current in air detected at the branch and straight pipe. The reason is suggested that the ion balance in the air does not keep between the ejector and the branch pipe due to both the adsorption of some negative ions on the pipe wall and the decrement of negative charge of particles. Therefore the “unusual” charge-transfer consists of not only the ionization caused by the self-discharge but also an adsorption of ions on the inner wall of the pipe.     

Synthesis, characterization, and high gas permeability of poly(diarylacetylene)s having fluorenyl groups

Diarylacetylenes having fluorenyl groups and other substituents (trimethylsilyl, t-butyl, bromine, fluorine) (1a-1) were polymerized with TaCl₅-n-Bu₄Sn. Monomers 1a-l produced high molecular weight polymers 2a-l (M_w 5.1 × 10⁵-1.3 × 10⁶) in 12-59% yields. All of the polymers were soluble in common organic solvents, and gave tough free-standing membranes by the solution casting method. The onset temperatures of weight loss of polymers 2a-l in air were over 400 °C, indicating considerably high thermal stability. All the polymer membranes showed high gas permeability; e.g., the oxygen permeability coefficient (PO₂) of 2a was as large as 4800 barrers. Membrane 2d possessing two fluorine atoms at meta and para positions of the phenyl ring showed the highest oxygen permeability (PO₂ = 6600 barrers) among the present polymers.     

Radical-initiator-Induced solid-state polymerization of butadiyne nanocrystals in water and their dispersion stabilization

Butadiyne nanocrystals in water are usually polymerized by UV or gamma-ray irradiation to give polydiacetylene (PDA) nanocrystals. In this study, we confirmed that solid-state polymerization of 1,6-di(N-carbazolyl)-2,4-hexadiyne (DCHD) and 5,7-dodecadiyn-1,12-diyl bis[N-(butoxycarbonyl-methyl)carbamate] (4BCMU) could be stimulated by water-soluble radical initiators. The radical initiators used were potassium peroxodisulfate, three kinds of azo-type compounds and a redox initiator. In all cases, the solid-state polymerization was confirmed by color change into blue indicating that PDA modified by the radical residues at the end was formed. However, nanocrystal cohesion occurred especially when the concentration of the initiators was high or the dispersion was kept for a long time. In order to improve the dispersion stability, two kinds of surfactants, i.e., sodium dodecyl sulfate (SDS) or dodecyltrimethylammonium chloride (DTMAC), were added to the DCHD nanocrystal aqueous dispersion. As a result, when anionic SDS was added, the solid-state polymerization of nanocrystals proceeded without coagulation and quantitative conversion was confirmed for all initiators. Cationic DTMAC has no effect on dispersion stabilization. PDA nanocrystal surfaces in water are negatively charged in nature and electric interaction of nanocrystals with the cations results in decrease of surface charge and aggregation of nanocrystals.     

Preparation of various DLC films by T-shaped filtered arc deposition and the effect of heat treatment on film properties

Different types of diamond-like carbon (DLC) films (ta-C, a-C, ta-C:H and a-C:H) were prepared on super hard alloy (WC-Co) substrate using a T-shape filtered arc deposition (T-FAD) system. At first, the film properties, such as structure, hydrogen content, density, hardness, elastic modulus, were measured. Ta-C prepared with a DC bias of −100 V showed the highest density (3.1 g/cm³) and hardness (70-80 GPa), and the lowest hydrogen content (less than 0.1 at. %). It was found that the hardness of the DLC film is proportional to approximately the third power of film density. The DLC films were then heated for 60 min in an electric furnace at 550 °C in N₂. Only the ta-C film hardly change its structure, although other films were graphitized. The 200-nm thick ta-C film was then heated for 60 min through the temperature range from 400 to 800 °C in N₂ with 2 vol.% of O₂ and the film structure found to be stable up to 700 °C. The substrate was oxidized at 800 °C, indicating the ta-C film had a thermal barrier function up to that temperature.     

Peculiar sandwich-like π–π interaction regulating the nonplanarity of the model heme crystals

X-ray crystallographic analysis of bis(pyridine N-oxide) complexes of iron(III) porphyrinates has revealed that the two pyridine rings of the axial ligands correctly sandwich the porphyrin ring to induce the deformation of commonly observed S₄ saddled porphyrin ring.