Finite element solution for gas–solid reactions: Application to the moving boundary problems

Gas–solid reactions are very important in the chemical and metallurgical process industries. Several models described these reactions such as volume reaction model, grain model, and nucleation model. These models give two coupled partial differential equations (CPDEs). In this work an integral transformation and subsequent finite element method is used for solving the coupled partial differential equations of these reactions. In each mesh the Rayleigh–Ritz method is applied. Finally the results of this work are compared with the existing numerical solutions and experimental data successfully.     

Reliability and risk treatment centered maintenance

We propose a new methodology for application of well-known tools — RCM, RBI and SIFpro — with the aim to treat risks by means of suitable maintenance. The basis of the new methodology is the complex application of all three methods at the same time and not separately as is typical today. The proposed methodology suggests having just one managing team for reliability and risk treatment centred maintenance (RRTCM), employing existing RCM, RBI, and SIFpro tools concurrently. This approach allows for significant reduction of engineering activities’ duration. In the proposed methodology these activities are staged into five phases and structured to eliminate all duplication resulting from separate application of the three tools. The newly proposed methodology saves 45% to 50% of the engineering workload and adequate significant financial savings.     

Sorption and Drying Characteristics of Xylite

The wood from which xylite is formed in a long-term process undergoes numous changes while still retaining the character of a hygroscopic porous material. To plan the optimal drying schedule of xylite, the permeability coefficient, diffusion coefficient, and surface emission coefficient were determined. The porosity of xylite is low due to the demolished capillary structure; concurrently with the blocked pits, the permeability of xylite is very low, with a permeability coefficient not higher than 2.12 × 10^?10 m²/Pa s. The capillary flow of free water is insignificant, allowing the diffusion transport of water to prevail. The diffusion coefficient is considerably influenced by the xylite's density. We confirm a significant increase in the bound water diffusion coefficient as the temperature increased (from 5.5 × 10^?12 m²/s at 20°C to 46.3 × 10^?12 m²/s at 40°C), and we predict that the activation energy will increase as the moisture content of xylite decreases (approx. 0.63 to 1.05%/% MC changes). As a consequence of the low surface resistance, the surface emission coefficient barely influences the moisture transport below the fiber saturation point.With an appropriate drying schedule, quality dried xylite can be used for various products as an equivalent substitute for dark-colored, high-density woods like ebony.     

Identifying the unknowns by aligning fragmentation trees

Mass spectrometry allows sensitive, automated, and high-throughput analysis of small molecules. In principle, tandem mass spectrometry allows us to identify "unknown" small molecules not in any database, but the automated interpretation of such data is in its infancy. Fragmentation trees have recently been introduced for the automated analysis of the fragmentation patterns of small molecules. We present a method for the automated comparison of such fragmentation patterns, based on aligning the compounds' fragmentation trees. We cluster compounds based solely on their fragmentation patterns and show a good agreement with known compound classes. Fragmentation pattern similarities are strongly correlated with the chemical similarity of molecules. We present a tool for searching a database for compounds with fragmentation pattern similar to an unknown sample compound. We apply this tool to metabolites from Icelandic poppy. Our method allows fully automated computational identification of small molecules that cannot be found in any database.     

The best screw shape for fine zinc oxide particles feeding

One of the most important requirements of particles feeding is a very homogeneous mass flow of fine particles. Screw feeders are among equipment used to feed particles in many industries. In this study, the performance of four single screw feeders with different pitch and blade shape screws has been studied experimentally for steady and stable feeding of fine zinc oxide particles at flow rates corresponding to laboratory scale range (under 10 g/min). The following results were obtained from this investigation: (I) the sticking problem of fine particles in angular pitch screw was solved by changing the pitch shape to circular; (II) the distribution of the fluctuations and their intensity in mass flow rates also lessen by using the circular pitch and a thin blade screw in place of the circular pitch and a thick blade screw. Also for both feeders, the feeding was often interrupted in low flow rates, but it will be disappeared by increasing the flow rate. Furthermore, the results of experiments show that the performance of the circular pitch and a thin blade screw feeder was better than other screw feeders and able to both swirl and mix the particles with different characteristics and reduce the mean aggregate size of the particle size distribution (PSD) when transmitting the zinc oxide particles.     

Influence of carboxymethylation on the surface physical–chemical properties of glucuronoxylan and arabinoxylan films

Xylans were carboxymethylated in order to increase their anionic nature and thus tune their surface free energy (SFE) and hydrophilicity, which are of crucial importance in the majority of special applications. Fourier transform infrared spectroscopy and polyelectrolyte titration results confirmed the successful carboxymethylation of the xylan samples. The main aim of this study was to investigate the influences of carboxymethylation of glucuronoxylan and arabinoxylans on the surface physical and chemical properties of the films made from them. Films were prepared by the casting method, and their surface morphologies were analyzed by atomic force microscopy. The surface chemical compositions of the films were investigated using X‐ray photoelectron spectroscopy, and their influences on SFE, i.e., Lifshitz–van der Waals and electron donor and acceptor contributions, were determined using goniometry. The introduction of ～2 mmol/g of carboxyl groups into the glucuronoxylan or arabinoxylan molecular structures had a significant influence on the chemical and physical surface properties of the prepared films. Higher amounts of the carboxyl group present on the films' surfaces and higher surface roughness contributed to a significant increase (by 270%) in the electron donor component of SFE and to 40% improvements in the hydrophilicities of the films' surfaces. POLYM. ENG. SCI., 55:2706–2713, 2015. © 2015 Society of Plastics Engineers     

Letter to the Editor

This paper examines how an object called a decision support system (DSS) is a system from the point of view of GST (general systems theory) and how GST is related with the development of DSS in a positive way. Since a DSS is a complicated system, it cannot be described by one model. We will proceed the consideration in the following different levels: functional level, structural level, process level and physical level. We will show that on each level GST provides a useful framework to deal with a DSS and the general formulation by GST directs what is to be done in the development of DSS. On the progress of the development we have found GST can help us with conceptualizing a DSS which is most important in finding a correct research direction. The presented models are the basic framework of our current system, a product of GST.