Control policies for an industrial acetylene hydrogenation reactor

This paper addresses the problem of finding optimal operational policies for an acetylene reactor for day to day operation. A lumped parameter model based on four main reactions is developed and used to examine the effects of the reactor manipulated variables on key reaction parameters. An optimal and a sub-optimal operational policy which minimize the ethylene loss over time are formulated and the solution techniques are presented. The results indicate that the reactor model is in good agreement with industrial plant data. The performance of the optimal control policy is very similar to the performance of the sub-optimal control policy. However, the sub-optimal formulation, while retaining the dominant features of the optimal response, reduces the computational requirements. Finally, some issues concerning the real-time implementation of an advanced acetylene reactor control scheme are presented. These include the estimation of the optimum regeneration cycle, a recursive model update algorithm, the process optimizer and their overall coordination. A preliminary analysis of the benefits associated with the advanced control scheme suggests a considerable reduction in the yearly ethylene loss.     

Characterization of polymer‐layered silicate (clay) nanocomposites by transmission electron microscopy and X‐ray diffraction: A comparative study

Several polymer‐layered silicate (clay) nanocomposites (PLSNs) were analyzed by transmission electron microscopy (TEM) and wide‐angle X‐ray diffraction (XRD) in an effort to characterize the nanoscale dispersion of the layered silicate. The PLSNs investigated included thermoset (cyanate esters) and thermoplastic polymers (polystyrene, nylon 6, and polypropylene‐g‐maleic anhydride). The results of this study reveal that the overall nanoscale dispersion of the clay in the polymer is best described by TEM, especially when mixed morphologies are present. XRD is useful for the measurement of d‐spacings in intercalated systems but cannot always observe low clay loadings (<5%) or be used as a method to identify an exfoliated nanocomposite where no XRD peaks are present (constituting a negative result). Most importantly, the study showed that XRD is not a stand‐alone technique, and it should be used in conjunction with TEM. Our studies suggest that new definitions, or a clarification of existing definitions, are needed to properly describe the diversity of PLSN nanostructures seen in various materials. Published 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 1329–1338, 2003     

Engineering of functional supramacromolecular complexes of proteins (enzymes) using reversed micelles as matrix microreactors

The size of the inner water cavity of reversed micelles formedin a triple system ‘water-surfactant-organic solvent’can be widely varied by changing the degree of surfactant hydration.This gives grounds to use reversed micelles as matrix microreactorsfor the design of supramolecular complexes of proteins. Usingultracentrifugation analysis, it has been demonstrated thatthe oligomeric composition of various enzymes (ketoglutaratedehydrogenase, alkaline phosphatase, lactic dehydrogenase, glyceraldehyde-3-phosphatedehydrogenase) solubilized in reversed micelles of Aerosol OT[sodium bis(2-ethylehexyl)sulfosuccinate] in octane changesupon variation of the degree of hydration. An oligomeric complexforms under conditions when the radius of the micelle innercavity is big enough to incorporate this complex as a whole.At lower degrees of hydration the micelles ‘uncouple’such complexes to their components. The catalytic propertiesof various oligomeric complexes have been studied. Possibilitiesof using reversed micelles for the separation of subunits ofoligomeric enzymes under non-denaturating conditions have beendemonstrated. In particular, the isolated subunits of alkalinephosphatase, lactic dehydrogenase and glyceralde-hyde-3-phosphatedehydrogenase have been found to be active in Aerosol OT reversedmicelles. The dependences of the catalytic activity of oligomericenzymes represent saw-like curves. The maxima of the catalyticactivity observed at these curves relate to the functioningof various oligomeric forms of an enzyme. The radii of the micelleinner cavity under conditions when these maxima are observedcorrelate with the linear dimensions of the enzyme oligomericforms. Correlation of the position of a maximum with the shapeof an oligomeric complex is discussed.     

The relationship between strength and the composition and fineness of cement

Data from new experiments and from work published during the past 40 years are subjected to regression analysis to determine the relationship between strength and the composition and fineness of cement. The original authors differed in their opinions on the relative importance of C₃S and C₃A. The controversy is examined against a background of experience with a group of materials that are representative of Portland cement in general, and in terms of an analysis based on a model in which, during the first weeks of hardening, the strength developed by C₃S depends on the proportion of C₃A in the cement.     

Knowledge and Belief: Some Clarifications

The notions of knowledge and belief play an important role in philosophy. Unfortunately, the literature is not very consistent about defining these notions. Is belief more fundamental than knowledge or is it the other way around? Many accounts rely on the widely accepted strategy of appealing to the intuition of the reader. Such an argumentative methodology is fundamentally flawed because it lets the problems of common sense reasoning in through the front door. Instead, I suggest that philosophical arguments should be based on formal-computational models to (a) reduce the ambiguities and uncertainties that come with intuitive arguments and reasoning, and (b) capture the dynamic nature of many philosophical concepts. I present a model of knowledge and belief that lends itself to being implemented on computers. Its purpose is to resolve terminological confusion in favor of a more transparent account. The position I defend is an antirealist naturalized one: knowledge is best conceived as arising from experience, and is fundamental to belief.     

Tethered space orientation via adaptive sliding mode

Here, we study the problem of a rotating tethered satellite system (TSS) orientation. The rotation TSS is used for propellantless delivery of the payload from low earth orbits to geostationary orbits or other transfer orbits. Driving the angular positions to correct desired orientation in rendezvous and tossing moments, in fact, is important operation in many real sceneries. We suggest the mathematical model describing the dynamics of TSS and catch mechanism/payload rendezvous with external disturbance terms. Here is shown that using sliding mode control (SMC), we are able to control successfully the position of TSS. The conventional and adaptive versions of SMC are considered. We show that SMC with the gain matrix adaptation based on the equivalent control method can significantly reduce the undesirable chattering effect provoking possible damages of TSS. Copyright © 2015 John Wiley & Sons, Ltd.     

Urban Social Media Demographics: An Exploration of Twitter Use in Major American Cities

This article explores intersections between place, race/ethnicity, and gender amongst American Twitter users and makes an argument that studying the intensity of tweets provides insights into how and why particular groups tweet. Given recent events in American political life such as the shooting in Ferguson, Missouri and the reactions by young, urban African Americans on Twitter, understanding the role of race, place, gender, and age is important. We observed the time between tweets of urban American Twitter users and explored whether the medium may be providing traditionally marginalized groups, such as young Black men, with potential avenues for mobilizing communication and access to resources.     

Evaluation of Sensors and Mapping Approaches for Disasters in Tunnels

Ground or aerial robots equipped with advanced sensing technologies, such as three‐dimensional laser scanners and advanced mapping algorithms, are deemed useful as a supporting technology for first responders. A great deal of excellent research in the field exists, but practical applications at real disaster sites are scarce. Many projects concentrate on equipping robots with advanced capabilities, such as autonomous exploration or object manipulation. In spite of this, realistic application areas for such robots are limited to teleoperated reconnaissance or search. In this paper, we investigate how well state‐of‐the‐art and off‐the‐shelf components and algorithms are suited for reconnaissance in current disaster‐relief scenarios. The basic idea is to make use of some of the most common sensors and deploy some widely used algorithms in a disaster situation, and to evaluate how well the components work for these scenarios. We acquired the sensor data from two field experiments, one from a disaster‐relief operation in a motorway tunnel, and one from a mapping experiment in a partly closed down motorway tunnel. Based on these data, which we make publicly available, we evaluate state‐of‐the‐art and off‐the‐shelf mapping approaches. In our analysis, we integrate opinions and replies from first responders as well as from some algorithm developers on the usefulness of the data and the limitations of the deployed approaches, respectively. We discuss the lessons we learned during the two missions. These lessons are interesting for the community working in similar areas of urban search and rescue, particularly reconnaissance and search.