Numerical assessment of the Double-Cantilever Beam and Tapered Double-Cantilever Beam tests for the GIC determination of adhesive layers

ABSTRACT

Fracture mechanics-based techniques have become very popular in the failure prediction of adhesive joints. The most commonly used is cohesive zone modeling (CZM). For both conventional fracture mechanics and CZM, the most important parameters are the tensile and shear critical strain energy release rates (G_IC and G_IIC, respectively). The most common tests to estimate G_IC are the Double-Cantilever Beam (DCB) and the Tapered Double-Cantilever Beam (TDCB) tests. The main objective of this work is to compare the DCB and TDCB tests to obtain the G_IC of adhesive joints. Three adhesives with varying ductilities were used to verify their influence on the precision of the typical methods of data reduction. For both tests, methods that do not need the measurement of crack length (a) were tested. A CZM analysis was considered to reproduce the experimental load–displacement (P-δ) curves and obtain the tensile CZM laws of each tested adhesive, to test the suitability of the data reduction methods, and to study the effect of the CZM parameters on the outcome of the simulations. The CZM models accurately reproduced the experimental tests and confirmed that the data reduction methods for the TDCB test tend to underestimate G_IC for ductile adhesives.     

Polyvinyl alcohol associated with carbon nanotube scaffolds for osteogenic differentiation of rat bone mesenchymal stem cells

Polyvinyl alcohol (PVAl) hydrogel, alone and reinforced with two types of carbon nanoparticles, was studied in cultured cells to assess its potential use in treating osteochondral defects. The carbon nanoparticles were produced by hot-filament chemical vapour deposition. The carbon material was characterised with a Renishaw Invia Raman microscope system and the morphological particles were characterised with field emission scanning electron microscopy and high-resolution transmission electron microscopy. Cytotoxicity was evaluated by measuring the Vero fibroblast-type cells’ metabolic activity and studying their morphology. The osteogenic differentiation of mesenchymal stem cells obtained from rat bone marrow was evaluated by alkaline phosphatase (ALP) and alizarin red S (ARS) staining. Cell viability and morphology were assessed with thiazolyl blue tetrazolium bromide and scanning electron microscopy, respectively. The materials did not interfere with the viability, metabolic activity, morphology and spreading of either of the cell types analysed. Nodules of mineralised organic matrix were identified with ARS and ALP, confirming osteogenic differentiation. These results indicated higher concentration of ALP and mineralised matrix for PVAl with carbon nanoparticles. The results of this study indicate the potential use of carbon nanoparticles with PVAl hydrogels as orthopaedic biomaterials to treat osteochondral defects, but further in vivo investigations are still necessary.     

Unsupervised neural models for country and political risk analysis

This interdisciplinary research project focuses on relevant applications of Knowledge Discovery and Artificial Neural Networks in order to identify and analyze levels of country, business and political risk. Its main goal is to help business decision-makers understand the dynamics within the emerging market countries in which they operate. Most of the neural models applied in this study are defined within the framework of unsupervised learning. They are based on Exploratory Projection Pursuit, Topology Preserving Maps and Curvilinear Component Analysis. Two interesting real data sets are analyzed to empirically probe the robustness of these models. The first case study describes information from a significant sample of Spanish multinational enterprises (MNEs). It analyses data pertaining to such aspects as decisions over the location of subsidiary enterprises in various regions across the world, the importance accorded to such decisions and the driving forces behind them. Through a projection-based analysis, this study reveals a range of different reasons underlying the internationalization strategies of Spanish MNEs and the different goals they pursue. It may be concluded that projection connectionist techniques are of immense assistance in the process of identifying the internationalization strategies of Spanish MNEs, their underlying motives and the goals they pursue. The second case study covers several risk categories that include task policy, security, and political stability among others, and it tracks the scores of different countries all over the world. Interesting conclusions are drawn from the application of several business intelligence solutions based on neural projection models, which support data analysis in the context of country and political risk analysis.     

A real time FFT-based impedance meter with bias compensation

A real time FFT-based impedance meter is here presented. It is realized simply by a standard PC in addition to a low cost two channels hardware device, and is based on a cost-effective algorithm to meaningfully reduce the known problem of the bias introduced by the relative phase and amplitude error between channels. The impedance meter exploits the implementation of an ad hoc cost-effective algorithm and a synchronous sampling allows eliminating the leakage error. The aliasing and the spectral interference are eliminated by means of an anti-aliasing filter and the use of very low distortion sinusoidal signals. Automatic measurements can be managed too, capturing different measures at different test frequencies and displaying them graphically on the PC screen. To validate the measured results comparative test were performed with respect to certified and calibrated commercially available multimeters known with good accuracies.Finally, this novel impedance meter integrates a home-made software, previously reported [1] capable to implement real time virtual instruments.     

Transformation Methods for the Numerical Integration of Three-Dimensional Singular Functions

The implementations of the eXtended Finite Element Method and the Boundary Element Method need to face the challenge of integrating singular functions. Since standard quadrature techniques usually produce inaccurate results, a number of specific algorithms have been developed to address this problem. We present a general framework for the systematic formulation of the three-dimensional case. The classical cubic transformation is also considered, including an analytical optimization of its parameters for improved practical efficiency.     

Solid‐phase extraction of phenolic compounds with poly[metalloprotoporphyrin IX]

A highly insoluble metalloporphyrin polymeric material was used as sorbent for the solid‐phase extraction of phenolic compounds. Substantial quantities of phenols (40 to 60 mg/g polymer) were absorbed from aqueous solution comparing satisfactorily with other extraction methods. The polymeric phase presented similar K_SPE values for the hydrophobic compounds tested such as p‐chlorophenol, BPA, p‐nitrophenol, and a significant lower value for the more hydrophilic p‐aminophenol and cresol. Several metallic complexes of protoporphyrin IX (Co²⁺, Cu²⁺, Ni²⁺, Zn²⁺, and Fe³⁺) have been tested. The analytes were extracted with high recoveries at acid and neutral pH values, whereas at pH 10 low recoveries were obtained. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3038–3043, 2001     

Stability conditions in piecewise smooth dynamical systems at a two-fold singularity

Some qualitative and geometric aspects of 3-dimensional non-smooth vector fields theory are discussed. Our main aim is to study the dynamics near typical singularities of piecewise smooth dynamical systems, the so-called two-fold singularities. More specifically, we are interested in discussing stability problems of such systems around these singularities.     

Evaluation of a hydrothermal process for pretreatment of wheat straw—effect of particle size and process conditions

BACKGROUND: Hydrothermal processes are an eco‐friendly processes that provide an interesting alternative for chemical utilization of lignocellulosic materials, in which water and crop residues are the only reagents. In this work the effect of process conditions (size distribution of the wheat straw, temperature and time) was evaluated against production of fermentable products. RESULTS: The use of milled wheat straw fractions as a raw material containing blends of different particle size distribution showed that the latter had an influence on the final sugars in the hydrolysate. Improved values of glucose (21.1%) and xylose yields (49.32%) present in the hydrolysate were obtained with treatment severity factors of 2.77 and 3.36, respectively. Mathematical models were developed aimed at establishing the effect of process conditions on monosaccharide concentration and its degradation in the liquor. CONCLUSION: This work shows that the use of wheat straw blends with various particle sizes has a significant effect on the extraction of fermentable products. The effect of treatment severity, which takes into account both processing time and temperature was also evaluated. These results are of importance for process design. Copyright © 2010 Society of Chemical Industry     

Degradation of Phenolic Compounds in Aqueous Sucrose Solutions by Ozonation

The sugar industry is concerned with color formation due to the oxidation of phenolic compounds in the presence of carbohydrates. In this study, we investigated the ozonation of a mixture of five phenolic compounds in water and aqueous sucrose solution: p-coumaric (p-COU), caffeic (CAF), syringic (SYR), and chlorogenic (CHO) acids, as well as the flavonoid quercetin (QUE). The experiments were carried out in a 3-L glass reactor with magnetic stirring and a diffuser plate at the bottom to feed the ozone-oxygen gas mixture. Initial solution concentrations of 5 mg L?1 of each acid, 15 mg L?1 of quercetin, and 40 g L?1 of sucrose were used. The degradation of phenolic compounds followed apparent first-order kinetics, with rate constants and percent removals decreasing in the presence of sucrose. In water, average consumed ozone dosages of 10.4 and 18.7 mg L?1 were necessary for 50% and 90% removals, respectively, for CHO, CAF, and p-COU; for QUE they were slightly higher (13.9 and 20.5 mg L?1, respectively). At a consumed dosage of 20.8 mg O3 L?1, more than 99% removal was obtained for CHO, CAF, and p-COU, while 96.2% was achieved for SYR. In contrast, QUE revealed to be more recalcitrant during ozonation in the absence of sucrose, with only 70% removal at the highest consumed O3 dosage. The consumed ozone dosages for 50% and 90% removals were higher for CHO, CAF, and p-COU in aqueous sucrose solution, which may impact ozone consumption during real sugarcane juice treatment. Sucrose and t-butanol were the main influential parameters that significantly affected the total amount of phenolic compounds degraded.