Synthesis and characterization of 1,3,2-diazaboroine derivatives for organic thin-film transistor applications

2,2′-(1,4-Phenylene)bis(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaboroine) [PND] and 2,2′-(4,4′-biphenylene)bis(2,3-dihydro-1H-naphtho[1,8-de]-1,3,2-diazaboroine) [BND] were synthesized and characterized by using differential scanning calorimetry (DSC) measurements, single crystal X-ray structure analysis, UV–vis absorption and electrochemical measurements, thin-film X-ray diffraction (XRD) and AFM studies. Organic field-effect transistors (OFETs) were fabricated by vacuum deposition with a bottom contact geometry using Au electrodes. Annealing treatment optimizes the organic active layer and increases the charge carrier mobility. Field-effect mobilities of 7.2 × 10^?3 for PND and 4.1 × 10^?4 cm² V^?1 s^?1 for BND were found.     

Ozonation of Spent Reactive Dye-Baths: Effect of HCO3?/CO32? Alkalinity

The effect of carbonate and bicarbonate alkalinity (soda ash buffer as 5,180 mg/L HCO3? alkalinity at pH 7 and as 5,100 mg/L CO32? alkalinity at pH 12) on the ozonation of reactive vinylsulphone dyestuffs in a simulated spent dye-bath has been studied at varying pHs. Adsorbable organic halogen (AOX) formation due to the high chloride content of the effluent and detoxification, which was evaluated in terms of the relative toxicity index Itox determined from the ED50 values for the marine photobacteria Vibrio fischeri, were also evaluated. Highest total organic carbon (56%), chemical oxygen demand (44%), and UV254 (77%) removals were achieved at pH 7 in the presence of HCO3? alkalinity. The fastest decolorization was observed for the case pH 2, the first order decolorization rate constant found as k620 = 0.16?min?1, closely followed by the pH 12 case with soda ash (k620 = 0.12?min?1) case. No positive correlation was evident between AOX, whose maximum value (=1.3 mg/L) appeared after 40 min ozonation at pH 7 and decreased to 0.54 mg/L after 120 min treatment, and Itox, which decreased to 0.16 at t = 50?min and increased rapidly thereafter. The Itox values were more related to color abatement kinetics. The maximum relative toxicity index of Itox = 0.83 occurred after 120 min. It was also established that the presence of alkalinity in the spent reactive dye-bath had no negative impact on the oxidation rates. In contrast, its absence seriously inhibited treatment efficiency. It is speculated that, with added soda ash, the carbonate radicals HCO3? and CO3??, which are more stable and selective than OH?, were produced and promoted the oxidation process.     

Elastic-plastic thermal stress analysis of an aluminum composite disc under parabolic thermal load distribution

An elastic-plastic thermal stress analysis was carried out on an orthotropic aluminum metal matrix composite disc with a hole by using an analytical solution. The thermal load distribution was chosen to vary parabolically from inner surface to outer surface. An aluminum composite disc reinforced curvilinearly by steel fibers was produced under hydraulic press. The mechanical properties of the composite disc were obtained from experiments by using strain gauges. A computer program was developed to calculate the thermal stresses under a parabolic temperature from inner surface to outer surface. The material was assumed to be non-linear hardening. The elastic-plastic solution was performed for the plastic region expanded around the inner surface by an analytical method. The magnitude of the tangential stress component for elastic and elastic-plastic was higher than the magnitude of the radial stress component. Besides, the tangential stress component was compressive on the inner surface and tensile on the outer surface. The magnitude of the tangential residual stress component was the highest on the inner surface of the composite disc. The plastic region began at the inner surface of disc. This paper was recommended for publication in revised form by Associate Editor Joo Ho Choi Gürkan Altan is a Research Assistant of Mechanical Engineering at the University of Pamukkale, Denizli, Turkey. Gürkan Altan received the B.E. degree (1999) in mechanical engineering from Dokuz Eylül University, Izmir, and the M.S. degree (2004) in mechanical engineering from Pamukkale University, Denizli. Gürkan Altan is interested in production and applications of composite materials. Currently he is involved in the development and application of joints of composite structures.     

Electrorheological properties of kaolinite,polyindole, and polyindole/kaolinite composite suspensions

In this study, polyindole (PIN) and polyindole/kaolinite (PIN/KAO) composite were synthesized by free radical polymerization using FeCl₃ as an initiator. Average particle sizes (d₅₀) of PIN and PIN/KAO composite were determined by dynamic light scattering (DLS) as 7.2 and 6.2 μm, respectively. The samples were characterized by FTIR, elemental analysis, DSC/TGA and SEM measurements. Suspensions of KAO, PIN, and PIN/KAO composite were prepared in silicone oil (SO) and the sedimentation stabilities were determined. Electrorheological (ER) properties of these suspensions were studied as a function of dispersed phase concentration, shear rate, shear stress, and temperature; and yield stresses and excess shear stresses determined. Further, dielectric properties of KAO, PIN, and PIN/KAO composite were investigated. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Effects of growth rate and temperature gradient on the microstructure parameters in the directionally solidified succinonitrile–7.5 wt.% carbon tetrabromide alloy

Succinonitrile (SCN)–7.5 wt.% carbon tetrabromide (CTB) alloy was unidirectionally solidified with a constant growth rate (V = 33 μm/s) at five different temperature gradients (G = 4.1–7.6 K/mm) and with a constant temperature gradient (G = 7.6 K/mm) at five different growth rates (V = 7.2–116.7 μm/s). The primary dendrite arm spacings, secondary dendrite arm spacings, dendrite tip radius and mushy zone depths were measured. Theoretical models for the microstructure parameters have been compared with the experimental observations, and a comparison of our results with the current theoretical models and previous experimental results have also been made.     

Equalization for discrete multitone transceivers to maximize bitrate

In a discrete multitone receiver, a time-domain equalizer (TEQ) reduces the intersymbol interference (ISI) by shortening the effective duration of the channel impulse response. Current TEQ design methods such as the minimum mean-squared error (MMSE), maximum shortening SNR (MSSNR), and maximum geometric SNR (MGSNR) do not directly maximize bit rate. We develop two TEQ design methods to maximize the bit rate. First, we partition an equalized multicarrier channel into its equivalent signal, noise, and ISI paths to develop a new subchannel SNR definition. Then, we derive a nonlinear function of TEQ taps that measures the bit rate, which the proposed maximum bit rate (MBR) method optimizes. We also propose a minimum-ISI method that generalizes the MSSNR method by weighting the ISI in the frequency domain to obtain higher performance. The minimum-ISI method is amenable to real-time implementation on a fixed-point digital signal processor. Based on simulations using eight different carrier-serving-area loop channels, (1) the proposed methods yield higher bit rates than MMSE, MGSNR, and MSSNR methods; (2) the proposed methods give three-tap TEQs with higher bit rates than 17-tap MMSE, MGSNR, and MSSNR TEQs; (3) the proposed MBR method achieves the channel capacity (as computed by the matched filter bound using the proposed subchannel SNR model) with a five-tap TEQ; and (4) the proposed minimum-ISI method achieves the bit rate of the optimal MBR method     

A bis-selenophene substituted alkoxy benzene derivative as a highly stable novel electrochromic polymer

Up to date there are few studies reporting the use of selenophene derivatives as electrochromic polymers. This report highlights the synthesis of a selenophene containing multi-ring aromatic polymer which possesses reasonable optical contrasts at both visible and near-IR regions. Electrochemical synthesis of a conducting polymer from a multi-ring aromatic monomer, 2-(2,5-bis(hexyloxy)-4-(selenophen-2-yl)phenyl)selenophene (BSB(OC₆H₁₃)₂), was achieved at a lower potential than its corresponding parent, selenophene. The strong absorption band for the undoped polymer was 474 nm and the onset energy for the π–π^* transition (Eg) was 1.9 eV (645 nm).A novel dual-polymer electrochromic device was constructed in sandwich configuration where poly(BSB(OC₆H₁₃)₂) was used as the anodically coloring material. It is the first electrochromic device where a selenophene-containing polymer was used as an active layer. The device switches between a rose-colored state and a blue-colored state with a fast response time (less than 1 s).     

Numerical prediction of three-dimensional fiber orientation in Hele-Shaw flows

A numerical technique is developed to determine the three-dimensional fiber orientation in complex flows. The fiber orientation state is specified in terms of orientation tensors, which are used in several constitutive models. This method is applied to quasi-steady state Hele-Shaw flows in order to predict the flow-induced fiber orientation during injection molding at zero volume fraction limit. At the inlet, a number of fibers are introduced at a specified rate into the flow and each fiber location is traced during the mold filling. Along these determined paths, the independent components of fourth order orientation tensors are solved, describing the orientation state. The numerical grid generation technique, which is suitable for complex mold shapes, is employed for the flow solution. Orientation ellipsoids are calculated from the second order tensors and are used to present the fiber orientation results. The numerical solutions are obtained for channel and converging flows. Planar, longitudinal, and transverse orientation results are generated from the orthogonal projections of the orientation ellipsoids.     

Relevance of peat-draining rivers for the riverine input of dissolved iron into the ocean

Peat bogs have the ability to produce strong chelate ligands (humic and fulvic acids) which enhance the weathering rates of iron-silicate minerals and greatly increase the solubility of the essential trace metal iron in river water. Fluvial networks link peat bogs with the ocean, and thus terrestrial-derived fulvic-iron complexes fuel the ocean's biological productivity and biological carbon pump, but understanding this role is constrained by inconsistent observations regarding the behaviour of riverine iron in the estuarine mixing zone, where precipitation reactions remove iron from the water column. We applied a characterization of the colloidal iron carriers in peatland-draining rivers in North Scotland, using field-flow fractionation (FFF), in combination with end-member mixing experiments of river water sampled near the river mouth and coastal seawater using a ⁵⁹Fe radiotracer method. According to our results, the investigated river contributed “truly dissolved” Fe concentrations of about 3300 nmol L^− 1 to the ocean which is nearly two orders of magnitude higher than the dissolved iron contribution of the “average world” river (∼ 40 nmol L^− 1). Thus we conclude that peatland-draining rivers are important sources of dissolved iron to the ocean margins. We propose highly electrostatic and sterical stabilized iron-organic matter complexes in the size range of < 2 kDa to be responsible for iron transport across the estuarine mixing zone.