Behaviour of hexahydrobenzodipyrazolones towards chloroacetylation, aminoalkylation, Grignard reagent and their antimicrobial activity

Treatment of 2,3a,4,6,7a,8-hexahydrobenzo [1,2-c; 4,5-c] dipyrazole-3,7-dione (1) with chloroacetyl chloride gave the 2,6-bis (chloroacetyl) derivative (2), which on treatment with acetic anhydride pyridine afforded (3). Compound (2) when heated with pyridine afforded (1). Compound (1) underwent Mannich reaction with piperidine or morpholine and formaldehyde to give the 2,6-bis (piperidino or morpholinomethyl) derivatives (4a,b). Hydroxymethylation of (1) with formaldehyde gave the 2,6-bis (hydroxylmethyl) derivative (4), which on heating with piperidine afforded (4a), Reaction of 2,3a,4,6,7a,8-hexahydro- 2,6-bis (phenylsulphonyl) benzo [1,2-c; 4,5-?] dipyrazole-3,7-dione (7) with phenylmagnesium bromide gave dodecahydro-3,3,4a,7,7,8a-hexaphenyl-2,6- bis (phenylsulphonyl) benzo [1,2-c; 4,5-?] dipyrazole (8). Derivatives of hexahydrobenzodipyrazolone (9a-g) have been subjected to general screening for their antimicrobial activity.     

Study the Characteristic of Planer and Sandwich PSi Gas Sensor (Comparative Study)

In this work, two configurations (planner and sandwich) structures of (Al/n PSi/n-Si/Al) porous silicon (PSi) gas sensor have been fabricated and tested extensively for CO₂ gas molecules. Two laser wavelength infrared and violet of (810 nm) and (405 nm) was used in the laser assisting etching process on the n-type silicon substrate. The gas detection characteristic of planner and sandwich configuration were studied under different condition. The resistance measurement, for the planner and J-V characteristic for sandwich structures, which was analyzed based on the nano-sized silicon, porosity, layer thickness, and the effective dielectric constant of the PSi layer. The SEM image of the PSi layer showed the formation pore-like structure with cylindrical and rectangular pore shape with different dimensions for infrared illuminated PSi and crossed pores-like structure with randomly distributed for violet illuminated PSi. The sensing mechanism for sandwich structure configuration is governed by the porous silicon parameters, while for planer configuration the silicon channel among the pore has a significant role in sensing process.     

Prediction-based secured handover authentication for mobile cloud computing

Mobile cloud computing (MCC) is a new technology that brings cloud computing and mobile networks together. It enhances the quality of service delivered to mobile clients, network operators, and cloud providers. Security in MCC technology, particularly authentication during the handover process, is a big challenge. Current vertical handover authentication protocols encounter different problems such as undesirable delays in real-time applications, the man in the middle attack, and replay attack. In this paper, a new authentication protocol for heterogeneous IEEE 802.11/LTE-A mobile cloud networks are proposed. The proposed protocol is mainly based on the view of the 3GPP access network discovery and selection function, which uses the capacities given by the IEEE 802.11 and the 3GPP long term evolution-advanced (LTE-A) standards interconnection. A prediction scheme, with no additional load over the network, or the user is utilized to handle cloud computing issues arising during authentication in the handover process. The proposed handover authentication protocol outperformed existing protocols in terms of key confidentiality, powerful security, and efficiency which was used to reduce bandwidth consumption.

     

An Optimized Collaborative Scheduling Algorithm for Prioritized Tasks with Shared Resources in Mobile-Edge and Cloud Computing Systems

Mobile edge computing (MEC) is a promising technology that has the potential to meet the latency requirements of next-generation mobile networks. Since MEC servers have limited resources, an orchestrator utilizes a scheduling algorithm to decide where and when each task should execute so that the quality of service (QoS) of each task is achieved. The scheduling algorithm should use the least possible resources required to meet the service demands. In this paper, we develop a two-level cooperative scheduling algorithm with a centralized orchestrator layer. The first scheduling level is used to schedule tasks locally on MEC servers. In contrast, the second level resides at the orchestrator and assigns tasks to a neighboring base station or the cloud. The tasks serve in accordance with their priority, which is determined by the latency and required throughput. We also present a resource optimization algorithm for determining resource distribution in the system in order to ensure satisfactory service availability at the minimum cost. The resource optimization algorithm contains two variations that can be employed depending on the traffic model. One variant is used when the traffic is uniformly distributed, and the other is used when the traffic load is unbalanced among base stations. Numerical results show that the cooperative model of task scheduling outperforms the non-cooperative model. Furthermore, the results show that the suggested scheduling algorithm performs better than other well-known scheduling algorithms, such as shortest job first scheduling and earliest deadline first scheduling.

     

A broadband hybrid GaN cascode low noise amplifier for WiMax applications

This article reports a Microstrip design for low noise amplifier (LNA) using a packaged commercial GaN‐on‐SiC high electron mobility transistor (HEMT). A cascode configuration with an inter‐stage matching and an independent biasing technique was used. A lumped elements design was first developed, analyzed, and simulated in ADS. Then the design was implemented using microstrip technology and simulated using the momentum EM simulation in ADS. The LNA is easy to fabricate, has a low cost, and can be easily modified for other applications. The proposed GaN LNA showed a gain of 13.5 dB with a noise figure (NF) of 3 dB from 2.8 to 3.8 GHz.     

Outage probability analysis of multi-hop relayed wireless networks over $$\alpha -\mu $$ fading channels

In this paper, we study the end-to-end outage probability performance of Amplify and Forward (AF) and Decode and Forward (DF) multi-hop wireless communication systems operating over independent but not necessarily identical \(\alpha -\mu \) fading channels. To this end, we derive an expression for the moment generating function of the reciprocal of the end-to-end signal-to-noise ratio, and then use this expression to evaluate the end-to-end outage probability of the AF system by numerically inverting the Laplace transform. We also derive an expression for the end-to-end outage probability of the DF system.     

Extended Rama Distribution: Properties and Applications

In this paper, the Rama distribution (RD) is considered, and a new model called extended Rama distribution (ERD) is suggested. The new model involves the sum of two independent Rama distributed random variables. The probability density function (pdf) and cumulative distribution function (cdf) are obtained and analyzed. It is found that the new model is skewed to the right. Several mathematical and statistical properties are derived and proved. The properties studied include moments, coefficient of variation, coefficient of skewness, coefficient of kurtosis and moment generating function. Some simulations are undertaken to illustrate the behavior of these properties. In addition, the reliability analysis of the distribution is investigated through the hazard rate function, reversed hazard rate function and odds function. The parameter of the distribution is estimated based on the maximum likelihood method. The distributions of order statistics for ERD are also presented. The performance of the suggested model is compared with several other lifetime distributions based on some goodness of fit tests on a real dataset. It turns out that the suggested model is more flexible than its competitors considered in this study, for modeling real lifetime data.     

Performance of dual-hop wireless communication systems over the α–μ fading channels

In this paper, we consider a dual-hop wireless communication system with non-regenerative relay node and we study its performance over the α–μ fading channels. Specifically, we derive a closed-form expression for the moment generating function (MGF) of the harmonic mean of end-to-end signal-to-noise ratio (SNR) assuming the α–μ fading models. We also derive closed-form expressions for the end-to-end outage probability and average bit error rate of coherent modulation techniques. The obtained expressions can be reduced to study the performance of dual-hop communication systems over other fading channel models by using the proper values for the α and μ parameters. Numerical results are provided and conclusion remarks are drawn.     

“Dialdehyde Cellulose” Nanofibers by Electrospinning as Polyvinyl Alcohol Blends: Manufacture and Product Characterization

A nanofiber was obtained by electrospinning of “dialdehyde cellulose” (periodate-oxidized cellulose, DAC) and polyvinyl alcohol (PVA), using only water as the solvent. Celluloses of four different origins were fully oxidized with sodium periodate to water-soluble DAC. Aqueous solution of DAC showed inadequate spinnability regardless of the polymer concentration and the electrospinning conditions used. Addition of PVA improved the solution's viscoelasticity and, consequently, the solution's spinnability. We examined the effects of DAC/PVA composition and electrospinning parameters on fiber morphology. Highly homogeneous nanofibers were prepared from 1:1 up to 2:1 (weight) DAC/PVA blends while samples of lower viscosity or higher relative DAC contents resulted in continuous, beaded fiber networks. Characterization of the electrospun fabrics revealed a highly crosslinked DAC structure reinforced with PVA, strongly interacting through hemiacetal bonds and hydrogen bonding. Fluorescence labeling confirmed the presence of reactive aldehyde functionalities in the electrospun web. The versatile properties of DAC as reactive material can now be imparted on electrospun fiber and nanofiber material – which was not possible so far –further widening the application scope of this interesting cellulose derivative.