Mineralization of a sorbed polycyclic aromatic hydrocarbon in two soils using catalyzed hydrogen peroxide

Hydrogen peroxide (H2O2) catalyzed by soluble iron or naturally occurring soil minerals, (i.e., modified Fenton's reagent) was investigated as a basis for mineralizing sorbed and NAPL-phase benzo[a]pyrene (BaP), a hydrophobic and toxic polycyclic aromatic hydrocarbon, in two soils of different complexity. 14C-Benzo[a]pyrene was added to silica sand and a silt loam soil, and mineralization was investigated using three-level central composite rotatable experimental designs. The effects of H2O2 concentration, slurry volume, and iron(II) amendment were investigated in the silica sand systems. In a Palouse loess silt loam soil, the variables included H2O2 concentration, slurry volume, and pH, with H2O2 catalyzed by naturally occurring iron oxyhydroxides. Regression equations generated from the data were used to develop three-dimensional response surfaces describing BaP mineralization. Based on the recovery of 14C-CO2, 70% BaP mineralization was achieved in the sand within 24 h using 15 M H2O2 and an iron(II) concentration of 6.6 mM with a slurry volume of 0.3 x the field capacity of the sand. For the silt loam soil, 85% mineralization of BaP was observed using 15 M H2O2, no iron amendment, and a slurry volume of 20 x the soil field capacity. The balance of the radiolabeled carbon remained as unreacted BaP in the soil fraction. Gas-purge measurements over 5 d confirmed negligible desorption under nontreatment conditions. However, oxidation reactions were complete within 24 h and promoted up to 85% BaP mineralization, documenting that the natural rate of desorption/dissolution did not control the rate of oxidation and mineralization of the BaP. The results show that catalyzed H2O2 has the ability to rapidly mineralize sorbed/NAPL-phase BaP and that partitioning, which is often the rate-limiting factor in soil remediation, does not appear to limit the rate of vigorous Fenton-like treatment.     

Guest Editor's Introduction

Journal of Signal Processing Systems -     

Effects of Consolidation History on Critical State of Sand

A series of drained biaxial compression tests were conducted on two sands to determine the effects of consolidation history on their critical states. Specimens of each sand were consolidated along at least two separate paths in void ratio-effective stress space, creating several unique consolidation histories. Because the sands were dilative, strains localized during shearing and the evolution to critical state occurred only within the shear band. Digital images were obtained through a plexiglass sidewall throughout each test. Digital image correlation techniques were used to quantify the displacements within the band, and a linear regression technique was used to formulate a displacement function from which strains were computed. The critical state was achieved within the shear band in each test, but the critical state line was found to depend on the initial state and subsequent consolidation history of the sand specimens.     

Pressure retarded osmosis: From the vision of Sidney Loeb to the first prototype installation — Review

The energy released from the mixing of freshwater with saltwater is a source of renewable energy that can be harvested using pressure retarded osmosis (PRO). In PRO, water from a low salinity solution permeates through a membrane into a pressurized, high salinity solution; power is obtained by depressurizing the permeate through a hydroturbine. The combination of increased interest in renewable and sustainable sources of power production and recent progress in membrane science has led to a spike in PRO interest in the last decade. This interest culminated in the first prototype installation of PRO which opened in Norway in late 2009. Although many investigators would suggest there is still lack of theoretical and experimental investigations to ensure the success of scaled-up PRO, the Norway installation has evoked several specialized and main-stream press news articles. Whether the installation and the press it has received will also boost competitive commercialization of membranes and modules for PRO applications remains to be seen. This state-of-the-art review paper tells the unusual journey of PRO, from the pioneering days in the middle of the 20th century to the first experimental installation.     

Dispersion and Deposition of Spherical Particles from Point Sources in a Turbulent Channel Flow

The dispersion and deposition of particles from a point source in a turbulent channel flow are studied. An empirical mean velocity profile and the experimental data for turbulent intensities are used in the analysis. The instantaneous turbulence fluctuation is simulated as a continuous Gaussian random field, and an ensemble of particle trajectories is generated and statistically analyzed. A series of digital simulations for dispersion and deposition of aerosol particles of various sizes from point sources at different positions from the wall is performed. Effects of Brownian diffusion on particle dispersion are studied. The effects of variation in particle density and particle-surface interaction are also discussed.     

Experimental Investigation of the Thermal Performance of Graphite Foam for Evaporator Enhancement in Both Pool Boiling and an FC-72 Thermosyphon

High-conductivity graphite foam is investigated for use as a surface enhancement for improved thermal performance in both pool boiling and an FC-72 thermosyphon. The influences of heat load and fluid level on the overall system thermal performance including surface superheat, effective heat transfer coefficient, and thermal resistance are examined. The thermal resistance of the foam heat sink is found to be extremely low at a minimum of 0.024 K/W, well below that of many other methods. The featured low thermal resistance is the primary benefit of this system. The thermal resistance is found to rise with increasing heat flux, but still remains advantageously low and exhibits excellent potential for high heat flux dissipation with low surface superheat, making it suitable for thermal management of advanced electronics.     

Exercise as stigma management for individuals with onset-controllable and onset-uncontrollable spinal cord injury.

Studies have suggested that individuals with physical disabilities are often stigmatized and are perceived to possess less favorable physical and psychological characteristics than individuals without disability. Purpose: To investigate whether able-bodied adults' perceptions of people with different causes of spinal cord injury (SCI) are influenced by physical activity status information. Method and Participants: Each participant (N = 198) read all five vignettes describing individuals with SCI who had varying levels of physical activity participation and cause of injury information (e.g., onset-uncontrollable [hit by impaired driver] and onset-controllable [caused by impaired driving]). After reading each vignette, participants completed a 12-item Warmth and Competence Questionnaire to evaluate each target. One-way repeated measures multivariate analyses of variance were conducted to examine the within-subjects differences. Results: Physically active individuals with onset-uncontrollable SCI were rated most favorably on warmth and competence. Physically active individuals with onset-controllable SCI also were rated more favorably on warmth and competence than physically inactive targets with onset-controllable SCI. Conclusion: A physically active lifestyle may be beneficial in managing the stigma experienced by individuals with both onset-controllable and onset-uncontrollable SCI. (PsycINFO Database Record (c) 2010 APA, all rights reserved)