pH sensitive phosphate crosslinked films of starch-carboxymethyl cellulose

This work aims to develop hydrogel films of starch and carboxymethyl cellulose (CMC) crosslinked with sodium trimetaphosphate (STMP) and to characterize some of their properties. Starch and STMP (S/T), starch and CMC (S/C), and mixed (S/T/C) films were prepared by casting. The degree of substitution, morphology, swelling degree, FTIR, mechanical properties, and sorption isotherms were studied. Reticulated samples (S/T and S/T/C) showed the same degree of substitution (0.050 ± 0.001). All films presented homogeneous morphology, but the mixed film showed greater roughness. Crosslinking increased the swelling capacity of the mixed hydrogel at pH 7, although it remained decreased concerning the S/T hydrogel. However, this property was sensitive to pH variations. The mixed film (S/T/C) showed greater mechanical resistance. The casting process was efficient to produce hydrogel films of starch/CMC crosslinked with STMP and the general results demonstrated the advantages of the mixed hydrogel.     

Ni/Al Intermetallics Plasma Transferred Arc Processing

TAILORING COMPONENT SUFACES for elevatedtemperature operations has been a goal of researchersduring the last century.Process and material selectionare the key factors for this development.In particularlythe latter can be described to have started with thedevelopment of stainless steels.Ni and Co based alloys,the superalloys,attended the increasing technologicaldemands for higher service temperatures(1).Morerecently the higher operating temperatures ofequipments,such as gas turbines,r…     

The Influence of High Temperature Exposure on the Wear Performance of a Ni Based Alloy PTA Coating

Degradation phenomena like wear and corrosion, may have their effects accelerated as components operate at high temperature. The aim of this work is to make an indirect evaluation of the influence of high temperature exposure on wear behavior of Ni coatings. A Ni-Cr-Mo-W alloy, was deposited with Plasma Transferred Arc (PTA) process. An indirect approach based on the Ahrrenius relationship was used to evaluated long time exposures at high temperatures. To simulate longer exposures at lower temperatures, coatings were exposed to higher temperatures for the same time interval. So coatings were soaked in an air furnace at 650℃, 1000℃ and 1200℃. Metal/metal wear behavior was evaluated by pin-on-disc tests. Pins were removed from the coatings by eletrodischarge machining and rubbed against a VC31 quenched and tempered tool steel. Two sets of wear tests were run at 2m/s, for different loads (0.5, 1.0, 2.0 and 3.0Kg) and for different sliding distances (120, 720, 1080, 1440 and 1800m).Coatings characterization was done by scanning electronic microscopy and Vickers microhardness. Results showed as temperature is increased, coatings wear performance is altered,and this is associated with microstructural changes.     

Probabilistic consensus clustering using evidence accumulation

Machine Learning - Clustering ensemble methods produce a consensus partition of a set of data points by combining the results of a collection of base clustering algorithms. In the evidence...     

Modeling culture in intelligent virtual agents

This work addresses the challenge of creating virtual agents that are able to portray culturally appropriate behavior when interacting with other agents or humans. Because culture influences how people perceive their social reality it is important to have agent models that explicitly consider social elements, such as existing relational factors. We addressed this necessity by integrating culture into a novel model for simulating human social behavior. With this model, we operationalized a particular dimension of culture—individualism versus collectivism—within the context of an interactive narrative scenario that is part of an agent-based tool for intercultural training. Using this scenario we conducted a cross-cultural study in which participants from a collectivistic country (Portugal) were compared with participants from an individualistic country (the Netherlands) in the way they perceived and interacted with agents whose behavior was either individualistic or collectivistic, according to the configuration of the proposed model. In the obtained results, Portuguese subjects rated the collectivistic agents more positively than the Dutch but both countries had a similarly positive opinion about the individualistic agents. This experiment sheds new light on how people from different countries differ when assessing the social appropriateness of virtual agents, while also raising new research questions on this matter.     

Characterizing peers communities and dynamics in a P2P live streaming system

Despite the large number of works devoted to understand P2P live streaming applications, most of them put forth so far rely on characterizing the static view of these systems. In this work, we characterize the SopCast, one of the most important P2P live streaming applications. We focus on its dynamics behavior as well as on the community formation phenomena. Our results show that SopCast presents a low overlay topology diameter and low end-to-end shortest path. In fact, diameter is smaller than 6 hops in almost 90 % of the observation time. More than 96 % of peers’ end-to-end connections present only 3 hops. These values combined may lead to low latencies and a fast streaming diffusion. Second, we show that communities in SopCast are well defined by the streaming data exchange process. Moreover, the SopCast protocol does not group peers according to their Autonomous System. In fact, the probability that a community contains 50 % of its members belonging to the same AS (when we observe the largest AS of our experiments) is lower then 10 %. Peers exchange more data with partners belonging to the same community instead of peers inside the same AS. For the largest AS we have, less than 18 % of peer traffic has been exchanged with another AS partners. Finally, our analysis provides important information to support the future design of more efficient P2P live streaming systems and new protocols that exploit communities’ relationships.     

Assessment of the Impact of Stormwater Characteristics on Clogging in Stormwater Filters

Hydraulic conductivity of granular filter media and its evolution over time is a key design parameter for stormwater filtration and infiltration systems that are now widely used in management of polluted urban runoff. In fact, clogging of filter media is recognised as the main limiting factor of these stormwater treatment systems. This paper focuses on the effect of stormwater characteristics on the clogging of stormwater filters. Effect of five different operational regimes has been tested in this study of sediment concentration; pollutant concentrations; stormwater sediment size; loading rate and stormwater loading/dosing regime and compared with the Base case. For each operational condition, five column replicates were tested. Results suggest that sediment concentration in stormwater is a significant parameter affecting hydraulic and treatment performance, eventually affecting longevity of these stormwater treatment systems. Further, the size of sediments (and their relation to the size of filter media grains) in stormwater was found to be an important parameter to be considered in design of coarse filters with high infiltration rates that are used for stormwater treatment. As expected, the addition of metals and nutrients had limited or no contribution to changes in hydraulic or sediment removal performance of the studied stormwater filters. Whilst loading rate was found to be an important parameter affecting the hydraulic and treatment performance of these systems, any variation in the stormwater loading regime had a limited effect on their performance. This study therefore develops an understanding of the effect of catchment characteristics on design of filters and hence their longevity and maintenance needs.     

Lyapunov Design of Multivariable MRAC via Generalized Passivation

A Lyapunov design of multiple input, multiple output (MIMO) model‐reference adaptive control (MRAC) systems is proposed using new generalized passivity concepts based on WSPR and WASPR properties. The new design avoids control overparameterization and leads to the simplest unnormalized gradient algorithm by means of a passivating multiplier. To this end, a necessary and sufficient condition on the high frequency gain matrix to achieve the WASPR property is established. This condition is referred to as Positive Diagonal Jordan (PDJ) form. Based on the robustness WSPR and WASPR properties, a systematic determination of a robust passivating matrix multiplier is then presented. The advantages of the new design are illustrated by numerical simulation including a robotics adaptive visual servoing problem and a 4‐input‐4‐output dynamic system. © 2014 Chinese Automatic Control Society and Wiley Publishing Asia Pty Ltd