Technical risk involved in long-term operation of steam turbines

The scope of the paper is the assessment of the technical risk involved in long-term operation of power units. Detailed analyses have been conducted for steam turbine components. The sources and consequences of risk have been identified and the probability of turbine components failure calculated. The quantitative assessment of the risk has been made and possibilities of its reduction discussed.     

Influence of the amount of ferromagnetic addition on the rheological properties of spinning solutions,the structure,the strength,and thermal properties of polyacrylonitrile fibres

The rheological properties of spinning solutions of polyacrylonitrile in dimethyl formamide (DMF) containing various amounts of a ferromagnetic nanoaddition were investigated. The porous structure, the strength and thermal properties of fibers obtained from these solutions were assessed, as well as the uniformity of the nanoaddition distribution on the fiber surface was estimated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Potentiometric studies of oxidation–reduction reactions with redox copolymers

Polymeric oxidants in the bead form that were macroporous styrene/divinylbenzene copolymers containing N‐chlorosulfonamide functional groups (in sodium or hydrogen form) or N‐bromosulfonamide groups (in sodium form) were synthesized and investigated to determine their oxidizing powers. The redox potentials of the N‐chlorosulfonamide/sulfonamide and N‐bromosulfonamide/sulfonamide systems were determined by potentiometric studies at different pH values with aqueous solutions of Na₂SO₃, KCN, and KSCN as reducers. The formal redox potentials of the N‐chlorosulfonamide copolymers were 0.79, 0.44, and ?0.12 V at pH's of 1.8, 8.45, and 13.6, respectively. The formal redox potential of the N‐bromosulfonamide copolymer was about 100 mV higher in comparable conditions and in solutions over pH = 5 (e.g., 0.56 V at pH = 8.56). The comparatively higher oxidizing power of the N‐bromosulfonamide copolymer was particularly evident in a strong alkaline medium (in which the N‐chlorosulfonamide copolymer was not reactive). In contrast, the N‐chlorosulfonamide copolymer showed strong oxidative properties in acidic media (in which the N‐bromosulfonamide copolymer decomposed itself). © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008     

Mode of deformation and the rate of energy storage during uniaxial tensile deformation of austenitic steel

The mechanism of slip and its consequence in the process of energy storage during uniaxial tension of austenitic steel was studied. The interpretation of the energy storage process in terms of the slip development and microscopic shear band formation is presented.     

Effect of annealing on the structure and electrical properties of sulfur-doped amorphous c-BN layers

Undoped and sulfur doped amorphous cubic boron nitride (a-cBN) layers were deposited on to silicon substrates by reactive pulse plasma (RPP) method. Subsequently they were annealed at 475, 500 and 700 K for 1 h in pure nitrogen atmosphere. In this study structural and electronic properties of unannealed and annealed layers were investigated. The results show that a consequence of annealing is formation of microstructural stable nanocrystalline cubic boron nitride film as well as substitutional location of introducedin situ donor impurities. This resulted in creation of a-cBN(n-type)-Si(p-type) heterojunction.     

Note on covering monotone orthogonal polygons with star-shaped polygons

In 1986, Keil provided an O(n²) time algorithm for the problem of covering monotone orthogonal polygons with the minimum number of r-star-shaped orthogonal polygons. This was later improved to O(n) time and space by Gewali et al. in [L. Gewali, M. Keil, S.C. Ntafos, On covering orthogonal polygons with star-shaped polygons, Information Sciences 65 (1992) 45-63]. In this paper we simplify the latter algorithm—we show that with a little modification, the first step Sweep1 of the discussed algorithm—which computes the top ceilings of horizontal grid segments—can be omitted.In addition, for the minimum orthogonal guard problem in the considered class of polygons, our approach provides a linear time algorithm which uses O(k) additional space, where k is the size of the optimal solution—the algorithm in [L. Gewali, M. Keil, S.C. Ntafos, On covering orthogonal polygons with star-shaped polygons, Information Sciences 65 (1992) 45-63] uses both O(n) time and O(n) additional space.     

Cathodic reduction of acids in dimethylformamide on platinum

A linear correlation was shown to exist between the acidity and the cyclic voltammetric half-potential of the reduction of acids in DMF for carboxylic and N-acids in the pK_a range of 6-16. Chlorophenols are reduced at slightly lower potentials giving a separate parallel line. Applying the obtained equation and employing the same method to literature data in DMSO, the pK_a values for conjugate aids of DMF and DMSO can be calculated, showing DMSO·H⁺ to be more acidic (pK_a = 2.9) than DMF·H⁺ (pK_a = 5.7). The analysis of cyclovoltammetric data demonstrated that a CE mechanism operates in the reduction of strong acids, including the conjugate acid of DMF. Weaker acids are reduced by direct discharge or a mixed mechanism.     

Embedding linear orders in grids

A grid (or a mesh) is a two-dimensional permutation: an m× n-grid of size mn is an m× n-matrix where the entries run through the elements {1,2, …, mn}. We prove that if δ₁ and δ₂ are any two linear orders on {1,2, …, N}, then they can be simultaneously embedded (in a well defined sense) into a unique grid having the smallest size.     

Recursion from iteration

In a simply-typed, call-by-value (CBV) language with first-class continuations, the usual CBV fixpoint operator can be defined in terms of a simple, infinitely-looping iteration primitive. We first consider a natural but flawed definition, based on exceptions and “iterative deepening” of finite unfoldings, and point out some of its shortcomings. Then we present the proper construction using full first-class continuations, with both an informal derivation and a proof that the behavior of the defined operator faithfully mimics a “built-in” recursion primitive. In fact, given an additional uniformity assumption, the construction is a two-sided inverse of the usual definition of iteration from recursion. Continuing, we show that the CBV looping primitive is in fact the direct-style equivalent of a continuation-passing-style fixpoint, and that this correspondence extends all the way to traditional definitions of these operators in terms of reflexive types.     

Ein Beitrag zur Bestimmung der mittleren Zeitkonstante von Diffusionsprozessen

In the paper the general Galerkin method has been applied for the determination of the equivalent time constant of diffusion processes. After establishing the step function response the general formulas have been obtained, which allow for the consideration of boundary conditions of various kinds. The method has been illustrated with some numerical examples.