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141.
The present study investigates the interaction of NO2 gas and μ-carbido-bridged iron phthalocyanine (PcFeCFePc) films obtained by Langmuir–Blodgett (LB) and spin-coating (SC) techniques. The phthalocyanine bridged dimer under study belongs to the polynuclear unsubstituted phthalocyanines class and presents poor solubility: in contrast the corresponding N-base bis-adducts are soluble enough in organic solvents to be deposited by Langmuir–Blodgett and spin-coating techniques. The reaction with NO2 is monitored by visible spectra variation that shows identical behaviour for both kinds of films, indicating that the chemical reaction between the gas and the films is independent of the deposition method. The electrical conductivity change as a function of time with NO2 is instead dissimilar: for spin-coated films it shows a behaviour already observed for sandwich-type phthalocyanine whereas for LB films it resembles that of monomeric phthalocyanine. Such a response implies that the charges (holes) generated in the oxidation/reduction process are carried differently through the material, and we attempt to explain this behaviour taking into account the two different structural and morphological features induced by the two techniques. 相似文献
142.
143.
Correcting for the influence of frozen lakes in satellite microwave radiometer observations through application of a microwave emission model 总被引:1,自引:0,他引:1
Juha Lemmetyinen Anna Kontu Juho Vehviläinen Jouni Pulliainen 《Remote sensing of environment》2011,115(12):3695-3706
The spatial resolution of passive microwave observations from space is of the order of tens of kilometers with currently available instruments, such as the Special Sensor Microwave/Imager (SSM/I) and Advanced Microwave Scanning Radiometer (AMSR-E). The large field of view of these instruments dictates that the observed brightness temperature can originate from heterogeneous land cover, with different vegetation and surface properties.In this study, we assess the influence of freshwater lakes on the observed brightness temperature of AMSR-E in winter conditions. The study focuses on the geographic region of Finland, where lakes account for 10% of the total terrestrial area. We present a method to mitigate for the influence of lakes through forward modeling of snow covered lakes, as a part of a microwave emission simulation scheme of space-borne observations. We apply a forward model to predict brightness temperatures of snow covered sceneries over several winter seasons, using available data on snow cover, vegetation and lake ice cover to set the forward model input parameters. Comparison of model estimates with space-borne observations shows that the modeling accuracy improves in the majority of examined cases when lakes are accounted for, with respect to the case where lakes are not included in the simulation. Moreover, we present a method for applying the correction to the retrieval of Snow Water Equivalent (SWE) in lake-rich areas, using a numerical inversion method of the forward model. In a comparison to available independent validation data on SWE, also the retrieval accuracy is seen to improve when applying the influence of snow covered lakes in the emission model. 相似文献
144.
Luca AcetoTaolue Chen Anna IngolfsdottirBas Luttik Jaco van de Pol 《Theoretical computer science》2011,412(28):3035-3044
This paper contributes to the study of the equational theory of the priority operator of Baeten, Bergstra and Klop in the setting of the process algebra BCCSP. It is shown that, in the presence of at least two actions, the collection of process equations over BCCSP with the priority operator that are valid modulo bisimilarity, irrespective of the chosen priority order over actions, is not finitely based. This holds true even if one restricts oneself to the collection of valid process equations that do not contain occurrences of process variables. 相似文献
145.
The problem of query optimization in object-oriented databases is addressed. We follow the Stack-Based Approach to query languages, which employs the naming-scoping-binding paradigm of programming languages rather than traditional database concepts such as relational/object algebras or calculi. The classical environment stack is a semantic basis for definitions of object query operators, such as selection, projection/navigation, dependent join, and quantifiers. We describe a general object data model and define a formalized OQL-like query language SBQL. Optimization by rewriting concerns queries containing so-called independent subqueries. It consists in detecting them and then factoring outside loops implied by query operators. The idea is based on the formal static analysis of scoping rules and binding names occurring in a query. It is more general than the classical pushing selections/projections before joins. 相似文献
146.
Termeer M Oliván Bescós J Breeuwer M Vilanova A Gerritsen F Gröller ME Nagel E 《IEEE transactions on visualization and computer graphics》2008,14(6):1595-1602
Visually assessing the effect of the coronary artery anatomy on the perfusion of the heart muscle in patients with coronary artery disease remains a challenging task. We explore the feasibility of visualizing this effect on perfusion using a numerical approach. We perform a computational simulation of the way blood is perfused throughout the myocardium purely based on information from a three-dimensional anatomical tomographic scan. The results are subsequently visualized using both three-dimensional visualizations and bull's eye plots, partially inspired by approaches currently common in medical practice. Our approach results in a comprehensive visualization of the coronary anatomy that compares well to visualizations commonly used for other scanning technologies. We demonstrate techniques giving detailed insight in blood supply, coronary territories and feeding coronary arteries of a selected region. We demonstrate the advantages of our approach through visualizations that show information which commonly cannot be directly observed in scanning data, such as a separate visualization of the supply from each coronary artery. We thus show that the results of a computational simulation can be effectively visualized and facilitate visually correlating these results to for example perfusion data. 相似文献
147.
Dolors Costal Cristina Gómez Anna Queralt Ruth Raventós Ernest Teniente 《Software and Systems Modeling》2008,7(4):469-486
An important aspect in the specification of conceptual schemas is the definition of general constraints that cannot be expressed
by the predefined constructs provided by conceptual modeling languages. This is generally achieved by using general-purpose
languages like OCL. In this paper we propose a new approach that facilitates the definition of such general constraints in
UML. More precisely, we define a profile that extends the set of predefined UML constraints by adding certain types of constraints
that are commonly used in conceptual schemas. We also show how our proposal facilitates reasoning about the constraints and
their automatic code generation, study the application of our ideas to the specification of two real-life applications, and
present a prototype tool implementation.
相似文献
Ernest TenienteEmail: |
148.
Cole JN Henningham A Gillen CM Ramachandran V Walker MJ 《Proteomics. Clinical applications》2008,2(3):387-410
Gram-positive streptococci are non-motile, chain-forming bacteria commonly found in the normal oral and bowel flora of warm-blooded animals. Over the past decade, a proteomic approach combining 2-DE and MS has been used to systematically map the cellular, surface-associated and secreted proteins of human pathogenic streptococcal species. The public availability of complete streptococcal genomic sequences and the amalgamation of proteomic, genomic and bioinformatic technologies have recently facilitated the identification of novel streptococcal vaccine candidate antigens and therapeutic agents. The objective of this review is to examine the constituents of the streptococcal cell wall and secreted proteome, the mechanisms of transport of surface and secreted proteins, and describe the current methodologies employed for the identification of novel surface-displayed proteins and potential vaccine antigens. 相似文献
149.
We consider time-space tradeoffs for static data structure problems in the cell probe model with word size 1 (the bit probe model). In this model, the goal is to represent n-bit data with s=n+r bits such that queries (of a certain type) about the data can be answered by reading at most t bits of the representation. Ideally, we would like to keep both s and t small, but there are tradeoffs between the values of s and t that limit the possibilities of keeping both parameters small. 相似文献
150.
Anna Korzynska Wojciech Strojny Andreas Hoppe David Wertheim Pawel Hoser 《Pattern Analysis & Applications》2007,10(4):301-319
This paper describes a segmentation method combining a texture based technique with a contour based method. The technique
is designed to enable the study of cell behaviour over time by segmenting brightfield microscope image sequences. The technique
was tested on artificial images, based on images of living cells and on real sequences acquired from microscope observations
of neutrophils and lymphocytes as well as on a sequence of MRI images. The results of the segmentation are compared with the
results of the watershed and snake segmentation methods. The results show that the method is both effective and practical.
相似文献
Anna KorzynskaEmail: |