Hygrothermal properties of glass fiber reinforced cements subjected to elevated temperature

The effect of elevated temperatures on basic hygric and thermal properties of three types of glass fiber reinforced cement composites (GFRC) is analyzed in the paper. The main difference in the composition of particular GFRC is the use of wollastonite and vermiculite in two of them instead of usual sand aggregates. The composites containing wollastonite and vermiculite are found to have about four times lower thermal conductivity and two to three times lower thermal diffusivity in room temperature conditions. After heating the samples to 800°C and subsequent cooling, a decrease in room-temperature thermal conductivity as high as 50% and an increase in moisture diffusivity in the range of one to two orders of magnitude are observed for all types of studied materials. The application of wollastonite and vermiculite exhibits a positive effect on the high temperature linear thermal expansion coefficient. On the other hand, for temperatures higher than 450°C the thermal diffusivity of materials with wollastonite and vermiculite is higher than of common GFRC with sand aggregates.

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Résumé L'effet des températures élevées sur les principales propriétés hygriques et thermiques de trois types de matériaux composites à base de ciment renforcés par des fibres de verre (GFRC) est analysé dans cet article. La différence majeure de composition de ces matériaux est l'utilisation de wollastonite et de vermiculite dans deux d'entre eux au lieu des granulats de sable habituels. Les matériaux composites contenant de la wollastonite et de la vermiculie s'avèrent posséder une conductivité thermique environ quatre fois inférieure et une diffusivité thermique deux à trois fois inférieure en conditions de température ambiante. Après avoir chauffé les échantillons à 800°C puis les avoir refroidis, on observe pour tous les types de matériaux étudiés une diminution de la conductivité thermique à température ambiante, à hauteur de 50%, et une augmentation de la diffusivité d'humidité, d'environ un à deux ordres de grandeur. L'application de la wollastonite et de la vermiculite montre un effet positif sur le coefficient linéaire à haute température de dilatation thermique. D'autre part, pour les températures supérieures à 450°C, la diffusivité thermique des matériaux contenant de la wollastonite et de la vermiculite est plus élevée que celle des GFRC communs avec des granulats de sable.

     

Anomalous Excess Heat Capacities of Ethanol + Alkane Mixtures

A thermodynamic study at atmospheric pressure on the ethanol + n-dodecane and ethanol + n-tridecane binary systems near their liquid-liquid critical points has been carried out. To this end, densities and speeds of sound were determined in the temperature range from 288.15 to 308.15 K, whereas differential scanning calorimetry was used to obtain isobaric heat capacities per unit volume from 288.15 to 303.15 K as well as liquid-liquid equilibrium curves. All these results for the mentioned properties were obtained over the complete composition range. They were used to obtain molar volumes, isentropic compressibilities, isobaric thermal expansivities, isothermal compressibilities, isochoric heat capacities, and the excess quantities of all these properties. An untypical behavior of the excess heat capacities at the lowest measuring temperatures resulting from the critical behavior of the isobaric heat capacity is observed. No clear anomalies for the excess volumetric properties are detected.     

Large Deflection Stability of Slender Beam-Columns with Semirigid Connections: Elastica Approach

The large-deflection elastic analysis of slender beam-columns of symmetrical cross sections with semirigid connections under end loads (forces and moments) including the effects of out-of-plumbness is developed in a classical manner. The classical theory of the “Elastica” and the corresponding elliptical functions are utilized in the proposed method which can be used in the large-deflection stability analysis of slender beam-columns with rigid, semirigid, and simple connections under any combination of end loads (conservative and nonconservative). The proposed method consisting of a closed-form solution of the Elastica can also be utilized in the large deflection analysis of beam-columns whose connections suffer from flexural degradation or, on the contrary, flexural stiffening. The main limitation of the Elastica is that only flexural strains are considered (the effects of axial and shear strains are neglected). Therefore results from the proposed method are theoretically exact from small to very large curvatures and transverse and longitudinal displacements for plane beam-columns under bending actions. The large-deflection analysis of a beam-column with flexible connections at both ends becomes a complex problem requiring the simultaneous solution of at least two highly nonlinear equations with elliptical integrals. The solution of this problem becomes even more complex when the end connections are nonlinear or the direction of the applied end load changes (like “follower” loads). The validity and effectiveness of the proposed method and equations are verified against available solutions of very large deflection elastic analysis of beam-columns. Four comprehensive examples are included for verification and easy reference.     

Benchmarking System for Evaluating Management Practices in the Construction Industry

This paper presents the results obtained for the initial application of a management evaluation system whose objective is to provide a continuous improvement tool for construction companies through benchmarking management practices. The outlined system seeks to support a benchmarking system that has been recently established in the Chilean construction industry by incorporating qualitative management aspects in addition to performance indicators. Different analyses were made to determine trends in the sector and to establish correlations between qualitative aspects coming from surveys and quantitative aspects coming from performance indicators. Thirteen construction companies participated in the initial application of the benchmarking system. A correlation analysis found that safety performance was strongly related to companies having superior planning and control, quality management, cost control, and subcontractor management policies. A factor analysis found that central office priorities focus on strategic management policies having longer-term competitive impact, while site management emphasizes tactical management dimensions having short-term impact. There is scope to elevate the profile of continuous improvement initiatives to strategic significance at the central office level.     

Ethnicity, Expressed Emotion, Attributions, and Course of Schizophrenia: Family Warmth Matters.

The authors examined the role of family factors and the course of schizophrenia by carrying out additional assessments and analyses in 2 previously published studies of Mexican American and Anglo American patients and families. The authors found partial support for an attributional model of relapse for families who are low in emotional overinvolvement. Attributions of control, criticism, and warmth together marginally predicted relapse. The data also indicated that for Mexican Americans, family warmth is a significant protective factor, whereas for Anglo Americans, family criticism is a significant risk factor. These findings suggest that the sociocultural context shapes the pathways by which family processes are related to the course of illness. Moreover, the warmth findings suggest that families may contribute to preventing relapse. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Assuring Microstructural Homegeniety in Dual Phase and Trip Steels

The presence of ferrite/pearlite bands in dual phase and TRIP assisted steels is a consequence of microchemical segregation which causes mechanical properties anisotropy. Such inhomogeneous phase distribution produces a lowering of the mechanical properties such as fracture behaviour. This anisotropy is commonly not accounted in micromechanics computations which often assume a random distribution of phases in the solid. The present paper deals with an integral model for this undesirable band formation accounting for the solute segregation caused by solidification, microcomponent diffusion present in the austenitisation process, and the nucleation of the transformed phase in segregated regions. In the present work, the model was applied to two industrial grade dual phase steels and two TRIP assisted steels. The influence of such parameters on band formation is summarised in a number of “band prevention plots”, which are aimed at providing the optimum processing conditions for ferrite/pearlite band prevention.     

Utilization Bounds for EDF Scheduling on Real-Time Multiprocessor Systems

The utilization bound for earliest deadline first (EDF) scheduling is extended from uniprocessors to homogeneous multiprocessor systems with partitioning strategies. First results are provided for a basic task model, which includes periodic and independent tasks with deadlines equal to periods. Since the multiprocessor utilization bounds depend on the allocation algorithm, different allocation algorithms have been considered, ranging from simple heuristics to optimal allocation algorithms. As multiprocessor utilization bounds for EDF scheduling depend strongly on task sizes, all these bounds have been obtained as a function of a parameter which takes task sizes into account. Theoretically, the utilization bounds for multiprocessor EDF scheduling can be considered a partial solution to the bin-packing problem, which is known to be NP-complete. The basic task model is extended to include resource sharing, release jitter, deadlines less than periods, aperiodic tasks, non-preemptive sections, context switches, and mode changes.     

A Suite of Tools for Debugging Distributed Autonomous Systems

This paper describes a set of tools that enables developers to log and analyze the run-time behavior of distributed control systems. A feature of the tools is that they can be applied to distributed systems. The logging tools enable developers to instrument C or C++ programs so that data indicating state changes can be logged automatically in a variety of formats. In particular, run-time data from distributed systems can be synchronized into a single relational database. Tools are also provided for visualizing the logged data. Analysis to verify correct program behavior is done using a new interval logic that is described in this paper. The logic enables system engineers to express temporal specifications for the autonomous control program that are then checked against the logged data. The data logging, visualization, and interval logic analysis tools are all fully implemented. Results are given from a NASA distributed autonomous control system application.     

A Mixed Closure-CSP Method for Solving Scheduling Problems

Scheduling problems can be viewed as a set of temporal metric and disjunctive constraints and so they can be formulated in terms of CSP techniques. In the literature, there are CSP-based methods which sequentially interleave search efforts with the application of consistency enforcing mechanisms and variable/ordering heuristics. Therefore, the number of backtrackings needed to obtain a solution is reduced. In this paper, we propose a new method that effectively integrates the CSP process into a limited closure process: not by interleaving them but rather as a part of the same process. Such an integration allows us to define more informed heuristics. These heuristics are used to limit the complete closure process to a maximum number of disjunctions, thereby reducing its complexity while at the same time reducing the search space. Some open disjunctive solutions can be maintained in the CSP process, limiting the number of backtrackings necessary, and avoiding having to know all the problem constraints in advance. Our experiments with flow-shop and job-shop instances show that this approach obtains a feasible solution/optimal solution without having to use backtracking in most cases. We also analyze the behaviour of our algorithm when some constraints are known dynamically and we demonstrate that it can provide better results than a pure CSP process.