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71.
72.
Fernando Romero and Armando Ramos of Fernando Romero EnterprisE (FREE) describe how the firm's design for an iconic museum in Mexico City, which adopted complex computational techniques, required them to develop an integrated and highly collaborative approach to design; with a central digital 3-D model being applied throughout the construction phase. 相似文献
73.
Gui‐Ling Zhao Jan Vesely Ramon Rios Ismail Ibrahem Henrik Sundn Armando Crdova 《Advanced Synthesis \u0026amp; Catalysis》2008,350(2):237-242
Highly enantioselective organocatalytic domino thia‐Michael/aldol reactions between 2‐mercaptoacetophenone and α,β‐unsaturated aldehydes are presented. The reactions proceed with excellent chemo‐, diastereo‐ and enantioselectivity to give the corresponding benzothiopyran derivatives in high yields with up to >15:1 dr and 96 to >99 % ee. 相似文献
74.
Telma F.S. Silva Elisabete C.B.A. Alegria Luísa M.D.R.S. Martins Armando J.L. Pombeiro 《Advanced Synthesis \u0026amp; Catalysis》2008,350(5):706-716
The new half‐sandwich scorpionate complexes [hydridotris(1‐pyrazolyl)methane]vanadium trichloride, ([VCl3{HC(pz)3}] 1 (pz=pyrazolyl), [tris(1‐pyrazolyl)methanesulfonate]vanadium trichloride, [VCl3{SO3C(pz)3}] 2 , [hydrido(1‐pyrazolyl)methane]iron dichloride, [FeCl2{HC(pz)3}] 3 , lithium [tris(1‐pyrazolyl)methanesulfonate]dichloroferrate, Li[FeCl2{SO3C(pz)3}] 4 , and [tris(1‐pyrazolyl)methanesulfonate]copper chloride, [CuCl{SO3C(pz)3}] 5 were synthesized, characterized and shown to act, as well as the related (tripyrazolylmethane)copper dichloride, [CuCl2{HC(pz)3}] 6 , as selective catalysts (or catalyst precursors) for the peroxidative oxidation (with hydrogen peroxide) of cyclohexane to cyclohexanol and cyclohexanone, under mild conditions (at room temperature and using an aqueous solution of H2O2). The iron complexes are the most active ones (reaching TON values up to ca. 690), the effects of a variety of factors are reported and the reaction is shown to proceed via both C‐ and O‐centred radical mechanisms, conceivably involving a metal‐based oxidant. 相似文献
75.
Daniel Fernández-Quiroz Jorge Loya-Duarte Erika Silva-Campa Waldo Argüelles-Monal Andre-í Sarabia-Sainz Armando Lucero-Acuña Teresa del Castillo-Castro Julio San Román Jaime Lizardi-Mendoza Alexel J. Burgara-Estrella Beatriz Castaneda Diego Soto-Puebla Martín Pedroza-Montero 《应用聚合物科学杂志》2019,136(32):47831
This work describes the preparation of thermosensitive chitosan-graft-poly(N-vinylcaprolactam) nanoparticles by ionic gelation and their potential use as a controlled drug delivery system, using doxorubicin as a model drug. A systematic study of the effect of the main processing parameters on both the size and thermoresponsive behavior of nanoparticles was investigated. The size of the particles is strongly dependent on the length of the poly(N-vinylcaprolactam) grafted chains and the concentration of the copolymer and crosslinking agent solutions. The molecular structure of the copolymer plays an essential role in the phase transition temperature of the particles, which decreases with the length of PVCL grafted chain. The system displayed proper drug-association parameters, and the drug-loaded nanoparticles exhibited dose-dependent cytotoxicity. A significant increase in the doxorubicin delivery rate was observed above the phase transition temperature (40 °C). These features indicate that these nanoparticles are suitable for the development of a new thermally controlled anti-cancer drug delivery system. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47831. 相似文献
76.
Gredson Keiff Souza Alexandre Diório Gracielle Johann Maria Carolina Sérgi Gomes Armando Mateus Pomini Pedro Augusto Arroyo Nehemias Curvelo Pereira 《Journal of the American Oil Chemists' Society》2019,96(1):51-61
This study investigated the effects of variations in oil contents and fatty-acid composition, density, viscosity, acid values, saponification values, specific oxidative stability, and antioxidant concentration of Acrocomia totai kernel oil during fruit maturation. Fatty acids were quantified using 1H nuclear magnetic resonance (NMR) spectroscopy, gas chromatograph-flame-ionization detector (GC-FID), and Fourier transform Raman (FT-Raman) spectroscopy analyses. The results showed that all physicochemical characteristics and oil composition changed during the ripening stage. The CG-FID analysis showed a reduction in the unsaturated fatty-acid content (from 78.8% to 22.1%), with a proportional increase in the saturated fatty-acid contents (from 21.6% to 77.9%). The difference in the fatty-acid composition was confirmed by analysis of the 1H NMR and FT-Raman spectra. The degree of unsaturation was calculated to determine the oxidative stability of oil. These results suggest that the fruit's maturation contributes to the specific oxidative stability. The antioxidant concentration revealed higher contents of carotenoids in the ripe fruit (0.16 mg of carotenoid per 100 gKERNEL) when compared to the unripe fruit (0.05 mg of carotenoid per 100 gKERNEL). In the total phenolics analysis, there was no change in concentration over ripening time. These results show that kernel oil has physicochemical properties comparable with high-quality commercial vegetable oils, suggesting that it is a promising alternative to conventional vegetable oils. 相似文献
77.
78.
Lipase production by solid‐state fermentation of olive pomace in tray‐type and pressurized bioreactors 下载免费PDF全文
79.
Water Resources Management - It is a challenge to develop models that can represent the stochastic behaviour of rivers and basins. Currently used streamflow models were constructed under rigid... 相似文献
80.
Narizzano Massimo Pulina Luca Tacchella Armando Vuotto Simone 《Innovations in Systems and Software Engineering》2019,15(3-4):307-323
Innovations in Systems and Software Engineering - Property specification patterns (PSPs) have been proposed to ease the formalization of requirements, yet enable automated verification thereof. In... 相似文献