Electrodeposition growth of nanowire arrays with height gradient profiles for microwave device applications

A simple and nonexpensive adapted dip-coating technique is presented and used to fabricate arrays of magnetic nanowires with a linear varying height profile. This approach allows controlling the wire height from tenths of nanometers up to several micrometers. Furthermore, the main parameters of this height gradient can be controlled, such as the maximum wire height and the lateral span of the wire array, which can be predicted with excellent accuracy using a proposed analytical model. Moreover, we show that by sequential electrodeposition with dip-coating, arrays of these height varying wires can be grown. This technique represents a novel method to fill porous templates with controlled spatial growth, leading to the fabrication of novel structures and providing control over structural features on the nanoscale level. In particular, the use of these asymmetrically loaded magnetic nanowired substrates to obtain improved microwave nonreciprocal behavior is shown for a microwave phase shifter.     

Decontamination of aflatoxin B1‐contaminated corn by ammonium persulphate during fermentation

The decontamination of aflatoxin B₁(AFB₁)‐contaminated corn, which is required if the corn is to be suitable for alternative use, by an ammoniation–fermentation integrated process was studied. This process could be used for the production of fuel ethanol from aflatoxin‐containing corn. Different concentrations (0.25, 0.50, 1.00, 1.5 and 2.0% w/w) of ammonium persulphate were tested in the detoxification of AFB₁‐contaminated corn during fermentation. In order to increase the decontamination of corn, 0.5 and 1.0% (w/w) azodicarbonamide, benzoyl peroxide and hydrogen peroxide were tested. Peroxides were added at three different stages of the fermentation process: liquefaction, saccharification and fermentation. Levels of AFB₁ and ethanol were determined after each fermentation process. Treated corn was tested for mutagenic potential using the Ames test with TA100 tester strain and pure AFB₁ as positive control. Addition of 2.0% (w/w) ammonium persulphate caused the highest level of decontamination without affecting ethanol production. Addition of peroxides did not significantly (P < 0.05) increase ethanol production or significantly (P < 0.05) improve the decontamination process. The best processes for decontamination of corn and for ethanol production included the addition of 2.0% (w/w) ammonium persulphate for both and of 1.0 and 0.5% (w/w) benzoyl peroxide respectively. All treated corn samples showed no mutagenic potential. Possible industrial use of these processes is discussed. © 2002 Society of Chemical Industry     

Effect of Eu-implantation and annealing on the GaN quantum dots excitonic recombination

Undoped self-assembled GaN quantum dots (QD) stacked in superlattices (SL) with AlN spacer layers were submitted to thermal annealing treatments. Changes in the balance between the quantum confinement, strain state of the stacked heterostructures and quantum confined Stark effect lead to the observation of GaN QD excitonic recombination above and below the bulk GaN bandgap. In Eu-implanted SL structures, the GaN QD recombination was found to be dependent on the implantation fluence. For samples implanted with high fluence, a broad emission band at 2.7 eV was tentatively assigned to the emission of large blurred GaN QD present in the damage region of the implanted SL. This emission band is absent in the SL structures implanted with lower fluence and hence lower defect level. In both cases, high energy emission bands at approx. 3.9 eV suggest the presence of smaller dots for which the photoluminescence intensity was seen to be constant with increasing temperatures. Despite the fact that different deexcitation processes occur in undoped and Eu-implanted SL structures, the excitation population mechanisms were seen to be sample-independent. Two main absorption bands with maxima at approx. 4.1 and 4.7 to 4.9 eV are responsible for the population of the optically active centres in the SL samples.     

Linear programs in a simple reversible language

Very simple reversible programming languages can be useful for the study of reversible transformations. For this purpose we define simple reversible language (SRL), a very simple reversible language, and analyse its properties. The language SRL is similar to the “loop” languages that have been used by several authors to characterise the set of primitive recursive functions. There are, however, important differences: SRL has domain instead of and only reversible programs can be written in SRL. The reversibility of linear homogeneous SRL programs is related to the fact that the corresponding set of matrices has the algebraic structure of a group. We show that such programs implement exactly the linear transformations corresponding to the group of integer positive modular matrices, while in ESRL, an extended version of SRL, the set of transformations that can be implemented by linear homogeneous programs corresponds exactly to the group of integer modular matrices.     

Synthesis, Characterization and Cold Workability of Cast Copper-Magnesium-Tin Alloys

The use of Mg as an alloying element in copper alloys has largely been overlooked in scientific literature and technological applications. Its supposed tribological compatibility with iron makes it an interesting option to replace Pb in tribological alloys. This work describes the casting process of high-quality thin slabs of Cu-Mg-Sn alloys with different compositions by means of conventional methods. The resulting phases were analyzed using X-ray diffraction, scanning electron microscopy, optical microscopy, and energy dispersive X-ray spectroscopy techniques. Typical dendritic α-Cu, eutectic Cu₂Mg(Sn) and eutectoid non-equilibrium microstructures were found. Tensile tests and Vickers microhardness show the excellent hardening capability of Mg as compared to other copper alloys in the as-cast condition. For some of the slabs and compositions, cold rolling reductions of over 95 pct have been easily achieved. Other compositions and slabs have failed during the deformation process. Failure analysis after cold rolling reveals that one cause for brittleness is the presence of casting defects such as microshrinkage and inclusions, which can be eliminated. However, for high Mg contents, a high volume fraction of the intermetallic phase provides a contiguous path for crack propagation through the connected interdendritic regions.     

Condensation Reactions of Lignin During Oxygen Delignification Under Acidic Conditions

Spruce wood (Picea abies) has been subjected to delignification by oxygen under acidic conditions using different solvent media. The residual and removed lignins were submitted to permanganate oxidation and the products analyzed by GC and GC-MS. Results from the analysis of the residual lignins indicate that lignin “condensation” depends on the nature of oxidation medium. It was found that the addition of acetone to the aqueous liquor decreases both acid catalyzed and radical side reactions. Lignin “condensation” in water containing media is dominated by radical reactions. Results from the analysis of the lignin removed during oxygen delignification in an acetone/water medium indicate that significant amounts of “condensed” structures are present, which are relatively stable towards oxidation. The presence of diphenylmethane, diarylether and biphenyl type structures in the removed lignin was confirmed by CP-MAS ¹³C NMR spectroscopy.     

Analysis of the conjugate heat transfer in a multi-layer wall including an air layer

Analysis of the conjugate heat transfer in a multi-layer furnace wall including an air layer, using computational fluid dynamics (CFD), is presented. The analysis consists of the study of the heat transfer in the air layer to determine the heat flow that passes through the wall of the furnace. In the study, the natural convection effect on the insulating capacity of the wall was determined. The multi-layer wall is found in industrial furnaces used in the baking process of ceramics. In this study a critical thickness of the air layer was determined, identifying the beginning of natural convection, which represents a reduction in the insulating effect of the wall. In addition, different combinations of air layer thickness with vertical partitions were analyzed in order to increase the total thickness of the multi-layer wall and to improve the insulating capacity of the wall. An air layer with 10 cm of thickness and four parallel partitions presents the best insulating capacity, reducing by 44% the heat losses through the multi-layer wall.     

Novel bacterial cellulose–acrylic resin nanocomposites

The preparation and characterization of new nanocomposite films based on two acrylic emulsions, composed of random copolymers of butyl acrylate and methyl methacrylate, and bacterial cellulose is reported. The new composite materials were obtained through a simple and green approach by casting water-based suspensions of the acrylic emulsions and bacterial cellulose nanofibrils. The excellent compatibility between these matrices and the natural reinforcing fibers, observed by scanning electron microscopy (SEM), was reflected in the enhanced thermal and mechanical properties of the ensuing composites. Thus, an increase of around 30 °C in the maximum degradation temperature was observed for a 10% content of bacterial cellulose. The new composites showed glass–rubber transition temperature profiles comparable to those of the pristine matrices, as shown by DMA, and increasing elastic moduli with increasing the bacterial cellulose content. The tensile tests revealed a substantial increase in Young’s modulus and tensile strength and a corresponding decrease in elongation at break with increasing bacterial cellulose load.     

Numerical assessment of steam ejector efficiencies using CFD

Ejector efficiencies for the primary nozzle, suction, mixing and diffuser were determined for the first time, according to their definitions, using an axi-symmetric CFD model. Water was considered as working fluid and the operating conditions were selected in a range that would be suitable for an air-conditioner powered by solar thermal energy. Ejector performance was estimated for different nozzle throat to constant section area ratios. The results indicated the existence of an optimal ratio, depending on operating conditions. Ejector efficiencies were calculated for different operating conditions. It was found that while nozzle efficiency can be considered as constant, the efficiencies related to the suction, mixing and diffuser sections of the ejector depend on operating conditions.     

The use of discrete Markov random fields in reservoir characterization

In this work, we discuss relevant aspects concerning the use of discrete Markov random fields (MRF) in the simulation of rock properties in petroleum reservoirs. The Strauss multi-color model is useful to describe complex image configurations, by handling with parameters of repulsion between the different rock facies, symbolized in this case, by the different colors. The transition between the facies and the porous medium anisotropy are imposed to the system, and it is possible to generate various types of arrangement of the facies on the image, in contrast to Gaussian stochastic process, that can only simulate diffusion-type images. Another point focused is the behavior of the spatial correlation in discrete Markov random fields, here studied by the calculus of the practical semivariogram function in the binary Markov images, generated by using the Metropolis algorithm. These images have a correspondence to Gaussian images with Gaussian-type correlation, after truncated in binary facies. This similarity is validated by analysis in the behavior of the semivariogram function of the discrete Gaussian processes.