Biological Removal of High Loads of Thiosulfate Using a Trickling Filter Under Alkaline Conditions

Uncontrolled release of thiosulfate can cause high oxygen demand, or generate toxic compounds under anaerobic scenarios. Biooxidation of thiosulfate in a biotrickling filter (BTF) colonized by an alkaliphilic sulfide-oxidizing bacterial consortium was studied at pH ≈10. Inlet thiosulfate concentrations were varied from 3.5 to 21.3 g L^?1, with a residence time of 216 s, emulating conditions encountered in wastewater from mining processes. Sulfate production, oxygen concentration, and biomass in both packing and effluent were periodically analyzed to characterize bioreactor performance. Removal efficiencies near 100 % were obtained during the entire experimental period, with a maximum elimination capacity of 242 g thiosulfate m^?3 h^?1. Although the BTF was able to transfer large amounts of oxygen to biooxidize thiosulfate to sulfate, under high initial thiosulfate loads, thiosulfate was not completely oxidized to sulfate, since biooxidation was conditioned to oxygen supply. Respirometric tests performed to investigate biomass adaptation and activity revealed oxygen consumption values of 0.5 mmol O₂ (g protein)^?1 min^?1 for the period with the highest thiosulfate inlet load.     

TETRA radio performance evaluated via the software package TETRASIM

TETRA (TErrestrial Trunked RAdio) is a digital mobile radio standard for voice and data transmission. It aims at satisfying the growing request of applications and facilities coming from professional users and emergency services. The system has been standardized by ETSI (European Telecommunications Standards Institute) and is provided with an European harmonized frequency band. The first TETRA networks appeared on the market in 1997. This paper reports TETRA radio performance evaluated via a simulation software package, named TETRASIM, entirely developed at CSELT according to TETRA specifications. The simulation results have been obtained for some of the traffic and control channels specified by the standard, in terms of BER (Bit Error Rate) and MER (Message Erasure Rate). As far as the simulated receiver scheme is concerned, the characteristics of the equivalent low-pass filters and the adopted synchronization technique are reported. The simulated demodulator uses a differential detection scheme with soft decision outputs in the case of coded channels. Performance analyses and results comparison are provided by taking into account the effects of signal-to-noise ratio, co-channel interference, adjacent channel interference, propagation models defined in the standard and mobile unit speed. The simulation results reported in this work have been included in the ETR (ETSI Technical Report) “TETRA Designers’ Guide Part 2: Radio and Traffic Performance”. This revised version was published online in June 2006 with corrections to the Cover Date.     

Biochemical mechanism of the effect of barbital on rifamycin B biosynthesis by Amycolatopsis mediterranei (M18 strain)

It is well known that 5,5-diethylbarbituric acid (barbital) in the culture medium can stimulate the production of rifamycin B by Amycolatopsis mediterranei, particularly in industrial processes. However, the mechanism by which barbital exerts this effect is unknown. Results in this work show that the barbital effect is only evident under low aeration conditions (50-ml microfermentors with 7 ml of medium, 0.08 l/h air flow). Under these conditions, cultures with barbital showed similar CO2 production (in relation to a control without barbital), but higher oxygen uptake indicated that the extra O2 consumed was used in the increased rifamycin biosynthesis. Moreover, using a resting cell system where no antibiotic is produced, it was possible to show that barbital inhibits the respiratory chain, since O2 uptake decreased by 30%. Finally, we present biochemical results that suggest that a cytochrome P450-type monoxygenase, which can use atmospheric oxygen, is induced by barbital in an industrial-type strain of A. mediterranei.     

Raman lidar monitoring of extinction and backscattering of African dust layers and dust characterization

Results on the monitoring of strong African dust outbreaks at Lecce in the southeastern corner of Italy (40 degrees 20' N, 18 degrees 6' E) during May 2001 are presented. This activity has been performed in the framework of the European Aerosol Research Lidar Network (EARLINET). The lidar station of Lecce is located on a flat rural area that is approximately 800 km from the northern Africa coast. So it is closer to Africa than most of all other EARLINET stations and allow monitoring African dust transport early in its life cycle, at all levels in the plume. An elastic-backscatter Raman lidar based on a XeF excimer laser (351 nm) has been used to monitor the time evolution and vertical structure of the dust layers and get independent measurements of the aerosol extinction and backscatter coefficients. The findings are presented in terms of vertical profiles of the extinction and backscatter coefficients and of the lidar ratio. A quite deep dust layer extending between 2 and 6 km and characterized by a backscatter coefficient of approximately 0.0016 (km sr)(-1), a lidar ratio of approximately 50 sr, and an aerosol optical depth of 0.26 was observed on 17 May 2001 between 18:55 and 20:07 UT. The layer persisted for approximately five days. Dust layers of lower optical thickness and shorter persistence time have generally been monitored at the lidar site during African dust outbreaks. Results on the chemical and morphological characterization of the dust collected at the lidar station are also given to further support the origin of the monitored aerosol layers.     

Melting and crystallization of UHMWPE skived film

Commercial skived film from ultra-high molecular-weight polyethylene (UHMWPE) with considerable uniaxial orientation of lamellae is studied by ultra-small-angle X-ray scattering (USAXS) and wide-angle X-ray scattering (WAXS) during melting and crystallization in order to identify its mechanisms of crystallization. For the analysis of the nanostructure two-dimensional USAXS patterns are analyzed by means of the multidimensional chord distribution function (CDF) method. WAXS shows that crystallization is always isotropic and fast. WAXS reflections are observed before—under certain processing conditions—the SAXS pattern becomes anisotropic. Thus crystallization is decoupled from a slower process of oriented nanostructure formation (nanoforming). If nanoforming is performed isothermally at 105 °C, the evolving nanodomain layers obtain some preferential orientation, as long as the orientation of the melt has not previously been erased by melt-annealing at temperatures of 140 °C or above. Crystallization at temperatures ≥110 °C followed by quenching leads to isotropic nanostructure. Although crystallization is always observed early in the WAXS patterns, the USAXS patterns exhibit only weak discrete scattering during isothermal treatment at temperatures of 110 °C and higher. At 105 °C anisotropic isothermal nanoforming starts after 1.5 min. The melting of the original material resembles an inverted random car-parking mechanism. Only next-neighbor correlations are observed among the crystalline layers. The average nanodomain layer thickness is only slightly increasing (26–30 nm), whereas the long period increase is strong (from 60 nm to 140 nm).     

Accident under-reporting among employees: Testing the moderating influence of psychological safety climate and supervisor enforcement of safety practices

We examined accident under-reporting with data from 425 employees employed in 5 industries with above average risk for employee injuries. We expected that rates for unreported accidents would be higher than rates for reported accidents; and that organizational safety climate and perceptions of supervisor enforcement of safety policies would moderate the relationship between unreported accidents and reported accidents. Results showed that the number of unreported accidents was significantly higher than the number of reported accidents. There was an average of 2.48 unreported accidents for every accident reported to the organization. Further, under-reporting was higher in working environments with poorer organizational safety climate or where supervisor safety enforcement was inconsistent. We discuss the implications of these findings for improving accident under-reporting and occupational safety in the workplace.     

Visualisation of the structure transfer between an oriented polymer melt and the semi-crystalline state

Structure evolution of highly oriented polyethylene during cautious melting and crystallization is investigated with both high time resolution and high signal-to-noise ratio by means of small-angle X-ray scattering (SAXS) and wide-angle X-ray scattering (WAXS). The two-dimensional SAXS patterns are transformed to the multidimensional chord distribution function (CDF) in physical space. The results are continuous and smooth movies of the nanostructure, which elucidate the mechanisms of the evolution of semicrystalline structure.We find that in our material crystallization is preceeded by a rather diffuse mesomorphic nanostructure. Based on its variation in relation to other observed features like row nuclei and crystalline lamellae, we propose to associate it to phase separated regions of entangled and disentangled chain segments, respectively. The movies show that the mesophase structure holds the key for the understanding of crystallite orientation and arrangement in the fibre.     

Lignin valorization by forming toughened thermally stimulated shape memory copolymeric elastomers: Evaluation of different fractionated industrial lignins

Lignin‐based thermal responsive dual shape memory copolymeric elastomers were prepared with a highly branched prepolymer (HBP, A₂B₃ type) via a simple one‐pot bulk polycondensation reaction. The effect of fractionated lignin type (with good miscibility in the HBP) on copolymer properties was investigated. The thermal and mechanical properties of the copolymers were characterized by DMA, DSC, and TGA. Tensile properties were dominated by HBP <45% lignin content while lignin dominated >45% content. The copolymers glass transition temperature (T_g) increased with lignin content and lignin type did not play a significant role. Thermally stimulated dual shape memory effects (SME) of the copolymers were quantified by cyclic thermomechanical tests. All copolymers had shape fixity rate >95% and >90% shape recovery for all compositions. The copolymer shape memory transition temperature (T_trans) increased with lignin content and T_trans was 20°C higher than T_g. Lignin, a renewable resource, can be used as a netpoint segment in polymer systems with SME behavior. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41389.     

Synthesis and Characterization of Nanostructured Cerium Dioxide Thin Films Deposited by Ultrasonic Spray Pyrolysis

Nanostructured thin films of cerium dioxide have been prepared on single-crystalline silicon substrates by ultrasonic spray pyrolysis using cerium acetylacetonate as a metal–organic precursor dissolved in anhydrous methanol and acetic acid as an additive. The morphology, structure, optical index, and electrical properties were studied by X-ray diffraction, scanning electron microscopy, atomic force microscopy, ellipsometry, and impedance spectroscopy. The use of additives is very important to obtain crack-free films. The substrate temperature and flow rate was optimized for obtaining smooth ( R _a<0.4 nm), dense ( n >2), and homogeneous nanocrystalline films with grain sizes as small as 10 nm. The influence of thermal annealing on the structural properties of films was studied. The low activation energy calculated for total conductivity (0.133 eV) is attributed to the nanometric size of the grains.