Effect of inorganic constituents on chemical oxygen demand—I. Bromides are unneutralizable by mercuric sulfate complexation

Chemical oxygen demand (COD) assays are widely used for the estimation of the organic carbon content of water and wastewater. The procedure is subject to interference by free halogen ions, the oxidation of which creates artificially high COD values. As part of an investigation of the interferences involved in the COD determination of chemical industries wastewaters, we found that mercuric sulfate complexation, the standard procedure for neutralizing the halogen effects, is suitable for chlorides but is not applicable to bromides. This observation is true both in the presence or absence of chloride or ammonia. Care should therefore be exercised in the interpretation of COD data for bromide-containing samples.     

Children's goals and strategies in response to conflicts within a friendship.

Little is known about the skills required for friendship, as distinct from those required for peer acceptance. The present study examined whether children's goals and strategies in friendship conflict situations are predictive of their friendship adjustment, after accounting for level of peer acceptance. Fourth- and 5th-grade children (N?=?696) responded to 30 hypothetical situations in which they were having a conflict with a friend. Results indicated that children's goals were highly related to their strategies and that children's goals and strategies were predictive of their real-life friendship adjustment. Pursuing the goal of revenge toward a friend was the goal or strategy most strongly associated with lacking friends and having poor-quality friendships. Gender differences were also found for each goal and strategy, with girls displaying a more prosocial goal and strategy orientation than boys. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Noble Metal Ion-Directed Assembly of 2D Materials for Heterostructured Catalysts and Metallic Micro-Texturing

Assembling 2D-material (2DM) nanosheets into micro- and macro-architectures with augmented functionalities requires effective strategies to overcome nanosheet restacking. Conventional assembly approaches involve external binders and/or functionalization, which inevitably sacrifice 2DM's nanoscale properties. Noble metal ions (NMI) are promising ionic crosslinkers, which can simultaneously assemble 2DM nanosheets and induce synergistic properties. Herein, a collection of NMI–2DM complexes are screened and categorized into two sub-groups. Based on the zeta potentials, two assembly approaches are developed to obtain 1) NMI-crosslinked 2DM hydrogels/aerogels for heterostructured catalysts and 2) NMI–2DM inks for templated synthesis. First, tetraammineplatinum(II) nitrate (TPtN) serves as an efficient ionic crosslinker to agglomerate various 2DM dispersions. By utilizing micro-textured assembly platforms, various TPtN–2DM hydrogels are fabricated in a scalable fashion. Afterward, these hydrogels are lyophilized and thermally reduced to synthesize Pt-decorated 2DM aerogels (Pt@2DM). The Pt@2DM heterostructures demonstrate high, substrate-dependent catalytic activities and promote different reaction pathways in the hydrogenation of 3-nitrostyrene. Second, PtCl₄ can be incorporated into 2DM dispersions at high NMI molarities to prepare a series of PtCl₄–2DM inks with high colloidal stability. By adopting the PtCl₄–graphene oxide ink, various Pt micro-structures with replicated topographies are synthesized with accurate control of grain sizes and porosities.     

Experimental hepatitis E: pathogenesis in cynomolgus macaques (Macaca fascicularis)

Children with acute lymphoblastic leukemia (ALL) who have completed 2.5 to 3 years of initial chemotherapy have an off-therapy relapse rate of approximately 20%. In an attempt to improve the survival of children with a late bone marrow (BM) relapse (ie, occurring greater than 6 months after cessation of primary therapy), the Pediatric Oncology Group designed a randomized study to compare the efficacy of doxorubicin/prednisone and cytarabine/teniposide in a multidrug retreatment chemotherapy program. Treatment consisted of remission reinduction with vincristine, prednisone, and doxorubicin, central nervous system prophylaxis with triple intrathecal chemotherapy, and continuation therapy (for 132 weeks) with alternating cycles of oral 6-mercaptopurine/methotrexate and intravenous vincristine/cyclophosphamide. Patients received intermittent courses of either prednisone/doxorubicin (regimen 1) or teniposide/cytarabine (regimen 2) during continuation therapy and a late intensification phase with either vincristine, prednisone, and doxorubicin (regimen 1) or teniposide and cytarabine (regimen 2). One hundred two of 105 evaluable patients (97%) achieved a second complete remission. Twenty-eight of 50 patients on regimen 1 have failed compared with 28 or 52 patients on regimen 2 (log-rank analysis, P = .68), indicating that this trial was inconclusive as to which treatment regimen was superior. The overall 4-year event-free survival for children with a late BM relapse was 37% +/- 6%. Age less than 10 years at initial diagnosis (P < or = .001), white blood cell count less than 5,000/microL at relapse (P = .036) and duration of first remission greater than 54 months (P = .039) were independently associated with a more favorable outcome. While the randomized trial was inconclusive, prolonged second complete remissions were secured in more than one-third of children with a late BM relapse of ALL. The prognostic factors identified may help select children with a late BM relapse who can be successfully retreated with chemotherapy alone.     

Shadow allometry: Estimating tree structural parameters using hyperspatial image analysis

We present a novel approach to generating regional scale aboveground biomass estimates for tree species of the Lake Tahoe Basin using hyperspatial (< 1 m² ground resolution) remote sensing imagery. Tree crown shadows were identified and delineated as individual polygons. The area of shadowed vegetation for each tree was related to two tree structural parameters, diameter-at-breast height (DBH) and crown area. We found we could detect DBH and crown area with reasonable accuracy (field measured to image derived cross correlation results were 0.67 and 0.77 for DBH and crown area, respectively). Furthermore, the counts of the delineated polygons in a region generated overstory stem densities validated to manually photointerpreted stem densities (photointerpreted vs. image-derived stem densities correlation was 0.87). We demonstrate with accurate classification maps and allometric equations relating DBH or crown area to biomass, that these crown-level parameters can be used to generate regional scale biomass estimates without the signal saturation common to coarse-scale optical and RADAR sensors.     

Refractive-index matching avoids local field corrections and scattering bias in solid-state Na2SO4 ultraviolet Raman cross-section measurements

We report a refractive-index matching method to measure nonabsorbing solid ultraviolet (UV) Raman cross-sections that avoids the local field correction and interface scattering of incident light. We used refractive-index-matched chloroform as an internal standard to determine the solid-state 995 cm(-1) Na(2)SO(4) 244 nm Raman cross-sections. The pure liquid chloroform 668 cm(-1) 244 nm Raman cross-section was determined by using acetonitrile as an internal standard and by calculating the local field corrections for the observed Raman intensities. Our measured 244 nm UV Raman cross-section of the solid-state 995 cm(-1) SO4(2-) band of 1.97 ± 0.07 × 10(-28) cm(2)/(molc·sr) is about half of its aqueous solution Raman cross-section, indicating interactions between the sulfate species in the solid that decrease the Raman polarizability.     

New and conventional pore size tests in virus-removing membranes

Microorganisms are retained by ultrafiltration (UF) membranes mainly due to size exclusion. The sizes of viruses and membrane pores are close to each other and retention of viruses can be guaranteed only if the precise pore diameter is known. Unfortunately and rather surprisingly, there is no direct method to determine the membrane pore size. As a result, the UF membranes are not trusted to remove the viruses, and the treatment plants are required to enhance viral disinfection.Here we propose a new, simple and effective method for UF pore size determination using aquasols of gold and silver nanoparticles. We synthesized highly monodispersed suspensions ranging in diameter from 3 to 50 nm, which were later transferred through polymer and ceramic UF membranes. The retention percentage was plotted against the particle diameter to determine the pore size for which a membrane has a retention capability of 50, 90 and 100%. The d₅₀, d₉₀ and d₁₀₀ values were compared with data obtained from conventional transmembrane flux, polyethylene glycol, and dextran tests, and with the retention of phi X 174 and MS2 bacteriophages.The absolute pore size, d₁₀₀, for the majority of tested UF membranes is within 40-50 nm, and can only be detected with the new tests. The average 1.2 log retention of hydrophilic phi X 174 was predicted accurately by models based on the virus hydrodynamic radii and d₁₀₀ pore size. The 2.5 log MS2 retention suggests hydrophobic interactions in addition to simple ball-through-cylinder geometry.     

Combining static and dynamic array detection for binary synthesis with multiple memory ports

In High-Level Synthesis, Binary Synthesis is a method for synthesizing compiled applications for which the source code is not available. One of the advantages of FPGAs over processors is the availability of multiple internal and external memory banks. Binary synthesis tools use multiple memory banks if they are able to recover data-structures from the binary. In this work we improve the recovery of data-structures by introducing dynamic memory analysis and combining it with improved static memory analysis. We show that many applications can only be synthesized using dynamic memory analysis. We present two FPGA based architectures for implementing the bound-checking and recovery for the synthesized code. Our experiments show that the proposed technique accelerates the execution of applications which use multiple memory banks concurrently. We demonstrate that many binary applications indeed benefit from this technique.     

A New Method of Stereoscopic Viewing

A new kind of Stereoscopic Viewer is described which produces the illusion that the object viewed is actually in the room.