Treatment of saline wastewater contaminated with hydrocarbons by the photo-Fenton process

The application of the photo-Fenton process to the treatment of saline wastewater contaminated with hydrocarbons is investigated. Aqueous saline solutions containing raw gasoline were used as a model oil-field-produced water. The dependence on concentrations of the following reagents has been appropriately evaluated: hydrogen peroxide (100-200 mM), iron ions (0.5-1 mM), and sodium chloride (200-2000 ppm). The reactions were monitored by measurement of the absorption spectra and total organic carbon (TOC). Experimental results demonstrate that the photo-Fenton process is feasible for the treatment of wastewaters containing hydrocarbons, even in the presence of high concentrations of salt. The effect of the salt in this process is described through a series of reactions. A simple feedforward neural network model was found to correlate well the observed data for the degradation process.     

Monitoring particle adsorption by use of laser reflectometry near the critical angle

We investigate the use of laser reflectometry near the critical angle to monitor particle adsorption onto a flat glass surface. Experimental results show that positive particles are adsorbed onto the glass surface and that their adsorption kinetics depend strongly on the volume fraction occupied by the particles in suspension but not appreciably on the particle size. The reflectance near the critical angle is dominated by the particles on the surface, with the contribution of the particles in suspension being very low. We compare the reflectance change near the critical angle with the change in reflectance near the Brewster angle when particles are adsorbed onto the glass surface. We find that reflectometry near the critical angle is 3000 times more sensitive than it is near the Brewster angle. Some optical images are presented to validate our results.     

A Refinement Strategy for Circus

We present a refinement strategy for Circus, which is the combination of Z, CSP, and the refinement calculus in the setting of Hoare and Hes unifying theories of programming. The strategy unifies the theories of refinement for processes and their constituent actions, and provides a coherent technique for the stepwise refinement of concurrent and distributed programs involving rich data structures. This kind of development is carried out using Circuss refinement calculus, and we describe some of its laws for the simultaneous refinement of state and control behaviour, including the splitting of a process into parallel subcomponents. We illustrate the strategy and the laws using a case study that shows the complete development of a small distributed program.     

Synthesis and optimization of the recovery route for residual products under uncertain product demand

The present work describes an optimization model for managing the recovery of residual products that originate at industrial plants. The framework for the proposed general network superstructure, where all possible process transformations, storage, transports and auxiliary operations are accounted for, is modeled using a maximal state task network representation. This framework is combined with the evaluation of a set of environmental impacts, quantified by metrics (for air, water pollution, etc.) through the minimum environment impact analysis methodology and is associated with waste generation at utility production and transportation levels. The final model is described as a mixed-integer linear programming model, which, once solved, is able to suggest the optimal processing and transport routes, while optimizing a given objective function and meeting design and environmental constraints. For each solution obtained, a stochastic flexibility index is computed, allowing for the drawing of trade-off curves for investment decision support.     

Amnestic mild cognitive impairment: Difference of memory profile in subjects who converted or did not convert to Alzheimer's disease.

Episodic long-term, short-term, and implicit memory were investigated in 79 elderly subjects who fulfilled criteria for the amnestic form of mild cognitive impairment (a-MCI; i.e., by having an idiopathic amnestic disorder with absence of impairment in cognitive areas other than memory and without confounding medical or psychiatric conditions) and who developed Alzheimer's disease (AD) after 2 years as well as in 111 subjects affected by a-MCI who did not develop dementia. Results document a memory profile in a-MCI subjects characterized by preserved short-term and implicit memory and extensive impairment of episodic long-term memory. In virtually all episodic memory indexes examined (learning, forgetting, recognition abilities), a-MCI subjects who converted to AD were more severely impaired than were subjects who did not become demented. This memory profile, which closely resembles that exhibited by amnestic patients with bilateral mesial-temporal lobe lesions, confirms a precocious phase in preclinical AD characterized by selective involvement of mesial-temporal areas and worsening of the memory impairment as atrophic changes progress in hippocampal structures. In this context of pervasive episodic memory impairment, tests assessing the free recall of verbal material following a delay interval demonstrated the greater sensitivity to memory deficits of a-MCI subjects who developed AD. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Fracture toughness of the interface between Ni–Cr/ceramic,alumina/ceramic and zirconia/ceramic systems

Few studies have focused on the interface fracture performance of bi‐layered structures, which have an important role in dental restorations, using ceramic materials. The purpose of this study is to evaluate the fracture mechanics performance of the Ni–Cr/ceramic, alumina/ceramic and zirconia/ceramic interfaces by investigating the propagation of an interfacial crack under a wide range of mode mixities. The effect of the mechanical properties of the base materials and the interface, on the crack initiation and crack path, will also be studied. The finite element method (FEM) was used to calibrate the production of the experimental specimens, allowing to obtain the minimum dimensions and amounts of material needed to correctly characterize the fracture event. The specimens were tested until failure using a three‐point bending test machine. The interface fracture parameters were obtained using the FEM. For all specimens, the cracks propagated into the ceramic. The results suggest that, in Ni–Cr/ceramic, alumina/ceramic and zirconia/ceramic bi‐layered structures, the ceramic is weaker than the interface, which can be used to explain the clinical phenomenon that the ceramic chipping rate is larger than interface delamination rate. Consequently, a ceramic material with a larger fracture toughness is needed to decrease the failure rate of ceramic restorations.     

Industrial capacity planning in oligopolistic markets

Available productive capacity is determinant of a company’s success once it allows meeting the current and future demand. This article proposes a quantitative model for determining long-term productive capacity in competitive oligopolistic markets, based on the Nash Equilibrium formulated as a Variational Inequality problem. Numerical examples enable an analytical evaluation of the economic equilibrium’s sensitivity to marginal costs, investment costs, hurdle rate, and market saturation. Results show that, in order to achieve a greater market share, it is important to adopt strategies that reduce marginal costs. On the other hand, variations in the hurdle rate may or may not reinforce the position of a competitor in the market and his interest in investing in capacity expansion. Additionally, market saturation may be achieved, beyond which investment becomes unattractive. Each of these is a positive outcome for society, triggering diversified investments and competition in economic sectors where competition is low and profits are high.     

Bellaso's Reciprocal Ciphers

Abstract

A tableau with reciprocal alphabets used with a long keyword is commonly attributed to Della Porta. This cipher had actually been published a decade before by Giovan Battista Bellaso in a rare booklet containing other original ciphers.     

The generalised discrete algebraic Riccati equation in linear-quadratic optimal control

This paper investigates the properties of the solutions of the generalised discrete algebraic Riccati equation arising from the classic infinite-horizon linear quadratic (LQ) control problem. In particular, a geometric analysis is used to study the relationship existing between the solutions of the generalised Riccati equation and the output-nulling subspaces of the underlying system and the corresponding reachability subspaces. This analysis reveals the presence of a subspace that plays an important role in the solution of the related optimal control problem, which is reflected in the generalised eigenstructure of the corresponding extended symplectic pencil. In establishing the main results of this paper, several ancillary problems on the discrete Lyapunov equation and spectral factorisation are also addressed and solved.     

Design and evaluation of an ambient assisted living system based on an argumentative multi-agent system

This paper focuses on ambient assisted living systems employed to monitor the ongoing situations of elderly people living independently. Such situations are represented here as contexts inferred by multiple software agents out of the data gathered from sensors within a home. Sensors can give an incomplete, sometimes ambiguous, picture of the world; hence, they often lead to inconsistent contexts and unreliability on the system as a whole. We report on a solution to this problem based on a multi-agent system where each agent is able to support its understanding of the context through arguments. These arguments can then be compared against each other to determine which agent provides the most reliable interpretation of the reality under observation.