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排序方式: 共有214条查询结果,搜索用时 15 毫秒
61.
Fairous Salleh Maratun Najiha Abu Tahari Alinda Samsuri Tengku Shafazila Tengku Saharuddin Siti Sarahah Sulhadi Mohd Ambar Yarmo 《International Journal of Hydrogen Energy》2021,46(48):24814-24830
The physical and chemical behaviour of bulk tungsten oxide (WO3) and Ni doped tungsten oxide (15% Ni/WO3) were examined by performing a temperature-programmed reduction (TPR) technique. The chemical composition, morphology, and surface composition of both samples before and after reduced were analysed by X-ray diffraction (XRD), scanning electron microscopy (FESEM), and X-ray photoelectron spectroscopy (XPS) analysis. The XRD pattern of calcined Ni doped tungsten oxide powder comprised of WO3 and nickel tungstate (NiWO4) phases. The reduction behaviour was investigated by a non-isothermal reduction up to 900 °C achieved under (10 and 20% v/v) hydrogen in nitrogen (H2 in N2) and (20 and 40% v/v) carbon monoxide in nitrogen (CO in N2) atmospheres. The H2-TPR were indicated the reduction of bulk WO3 and 15% NiWO3 proceed in three steps (WO3 → WO2 → WO2 + W) and (WO3 → WO2 → W + Ni4W) respectively under 20% H2. Whereas, the reduction of 15% WO3 under 40% CO involves of two following stages: (i) low temperature (<800 °C) transformation of WO3 → WO2.72 → WO2 and, (ii) high temperature (>800 °C) transformation of WO2 → W → WC. Furthermore, NiWO4 alloy phase was transformed according to the sequence NiWO4 → Ni + WO2.72 → Ni + WO2 → Ni + W → Ni4W + W at temperature >700 °C and >800 °C in H2 and CO atmospheres, respectively. It can be concluded that the reduction behaviour of WO3 is matched with the thermodynamic data. In addition, the reduction under H2 is more favourable and have better reducibility compared to the CO gas. It is due to the small molecule size and molecule mass of H2 that encourages the diffusion of H2 molecule into the internal surface of the catalyst compared to CO. Moreover, Ni additive had improved the WO3 reducibility and enhancing the CO adsorption and promotes the formation of tungsten carbide (WC) by carburisation reaction. Besides, the formation of Ni during the reduction of 15% Ni/WO3 under CO reductant catalysed the Boudouard reaction to occur, which disproportionated the carbon monoxide to carbon dioxide and carbon (CO → CO2 + C). 相似文献
62.
Norazlianie Sazali Wan Norharyati Wan Salleh Ahmad Fauzi Ismail Yuji Iwamoto 《International Journal of Hydrogen Energy》2021,46(48):24855-24863
In this study, three thermally labile additives microcrystalline cellulose (MCC), nanocrystalline cellulose (NCC), and polyvinylpyrrolidone (PVP) were introduced to the P84-copolyimide (PI) solution. PI-based carbon tubular membranes were fabricated using dip-coating method, followed by sample characterizations in order to determine their structural morphologies, thermal stability and gas permeation performance. NCC was added as the membrane pore former for the hydrogen gas (H2) separation. While tests involving pure H2 and N2 permeation were carried out at room temperature, carbon membranes were carbonized at a final temperature of 800 °C, with the heating rate of 3 °C/min under the Ar flow. Excellent result of H2/N2 selectivity was obtained with value of 430.06 ± 4.16. Addition of NCC has significantly increased the number of pore channels in the membrane, hence, contributing to high gas permeance and selectivity. NCC has shown potential as a good additive for an enhanced hydrogen separation performance. 相似文献
63.
Nor Asikin Awang Wan Norharyati Wan Salleh Farhana Aziz Norhaniza Yusof Ahmad Fauzi Ismail 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2023,98(1):22-44
Heavy metal pollution of water is a global concern, which adversely affects human health because of its resistance to biodegradation and thus its transmission in the food chain via bioaccumulation. Nano zerovalent iron (nZVI) is very effective for the removal of heavy metals and is cost effective in terms of production. However, the main problems of nZVI are agglomeration and ease of oxidation. Several stabilization materials have been implemented to limit the aggregation of nZVI, such as silica, activated carbon and biochar. In comparison, as a support material, biochar possesses a large surface area, high stability and strong adsorption capacity, as well as being obtainable from various types of materials. Thus, this work aims to establish the opportunities available on the use of biochar-supported nZVI in utilizing its ability to stabilize and immobilize the nZVI. This review also reports the preparation, modification and surface enhancement of biochar, nZVI and biochar-nZVI for practical use as adsorbents. This review shows that modifications of the nZVI surface can help in their stabilization and reduction of aggregation. Additionally, this review is able to increase one's understanding of heavy metal sorption behavior by biochar-supported nZVI as it is the important as heavy metal sorption is driven based on biochar-nZVI type and heavy metal species which involve numerous mechanisms, including physical binding, complexation, ion exchange, surface precipitation and electrostatic interactions. Furthermore, this research reviews the adsorption parameters, including the crucial adsorption mechanism of heavy metals onto biochar-nZVI; the reusability of the biochar-nZVI is also discussed in this work. © 2022 Society of Chemical Industry (SCI). 相似文献
64.
Wan Nor Anasuhah Wan Yusoff Mahendra Rao Somalu Nurul Akidah Baharuddin Andanastuti Muchtar Lai Jian Wei 《国际能源研究杂志》2020,44(14):11783-11793
LiCoO2-based materials are well-known cathode materials used in lithium ion batteries. Moreover, these materials are currently utilized in low-temperature proton-conducting solid oxide fuel cells (SOFCs). Various dopants, such as Mn, Sr, and Zn, are introduced into LiCo2-based materials to improve their properties and performance for proton-conducting SOFC applications. In this regard, Mn-, Sr-, and Zn-doped LiCoO2 and LiCo0.6X0.4O2 (X = Mn, Sr, or Zn) powders are synthesized via the glycine-nitrate combustion method. Their properties are characterized using different techniques. The precursor cathode powder is dried at 100°C and subjected to thermogravimetric analysis (TGA). The phase formation and morphology of calcined LiCo0.6Mn0.4O2 (LCMO), LiCo0.6Sr0.4O2 (LCSO), and LiCo0.6Zn0.4O2 (LCZO) powders at 600°C to 700°C are examined via X-ray diffraction. At 600°C, both calcined LCSO and LCZO powders show few secondary phases, but these phases greatly decrease as calcination temperature increases to 700°C. By contrast, calcined LCMO powders exhibit a single phase structure at both calcination temperatures of 600°C and 700°C. The measured crystallite sizes of LCMO, LCSO, and LCZO powders are 23.32 ± 0.20, 21.08 ± 0.72, and 21.24 ± 0.32 nm, respectively. TEM images indicate that the particles in LCMO and LCZO powders highly agglomerate compared with those in LCZO powders. This result confirms that LCSO cathodes have the highest electrical conductivity (356.66 S cm−1) and the lowest area specific resistance (0.29 Ω cm2 in humidified [3%] air) at 700°C. In conclusion, LCSO materials are the best cathodes with high potential for proton-conducting SOFC applications. 相似文献
65.
Mustafa Anwar Muhammed Ali S.A. Nurul Akidah Baharuddin Nor Fatina Raduwan Andanastuti Muchtar Mahendra Rao Somalu 《Ceramics International》2018,44(12):13639-13648
This study examined the effects of samarium and erbium co-doping on the structural, optical, and electrical properties of ceria (CeO2). Ceramic (Ce0.8Sm0.2-xErxO2-δ; x?=?0, 0.05, 0.10, 0.15, 0.20) electrolytes were synthesized via sol-gel assisted citric acid–nitrate combustion and calcined at 850?°C for 5?h. The calcined electrolytes possessed a cubic fluorite crystal structure without impure phases. The direct band gap of the calcined electrolytes increased as the erbium content increased and the lowest band gap was obtained for Ce0.8Sm0.2O2-δ (SDC) electrolyte. The calcined electrolyte powders were subsequently pressed into cylindrical pellets by uniaxial die pressing, and the pellets were sintered at 1400?°C for 5?h. The sintered densities of the pellets were measured with Archimedes’ method. The relative density of Ce0.8Sm0.1Er0.1O2-δ co-doped ceria electrolyte was higher than those of singly doped ones, and these findings were further confirmed through field emission scanning electron microscopy. Electrochemical impedance spectroscopy indicated that the conductivity of erbium-doped ceria increased as the samarium content increased. The maximum total ionic conductivity was observed in Ce0.8Sm0.1Er0.1O2-δ co-doped electrolyte. However, the singly doped SDC electrolyte exhibited the highest ionic conductivity of 13.12 mS/cm and the lowest activation energy of 0.580?eV at 600?°C among all other Ce0.8Sm0.2-xErxO2-δ co-doped ceria electrolytes. 相似文献
66.
A network of gold nanostructures exhibiting one-dimensional gold nanostructure properties may become a prospective novel structure for optical, electrical and catalytic applications benefited by its unusual characteristics resulting from the collective properties of individual nanostructures in the network. In this paper, we demonstrate a facile method for the formation of high-density gold nanonetwork film on the substrate surface composed of quasi-1D nanoparticles (typically fusiform) with length ca. 10 nm - via reduction of gold ions in the presence of nanoseeds attached surface, binary surfactants of cetyltrimethylammonium bromide and hexamethyleneteramine and Ag+ ions. The length of the nanonetworks can be up to ca. 100 nm, which corresponds to the aspect ratio of ca. 10. The quasi-1D gold nanostructures as well as the nanonetworks were found to be sensitive to the binary surfactants system and the Ag+ ions as they can only be formed if all the chemicals are available in the reaction. The nanonetworks exhibit unique 1D optical properties with the presence of transverse and longitudinal surface plasmon resonance absorption. Owing to their peculiar structures that are composed of small quasi-1D nanoparticles, the nanonetworks may produce unusual optical and catalytic properties, which are potentially used in surface-enhanced Raman scattering, catalysis and optical and non-linear optical applications. 相似文献
67.
Roswanira Abdul Wahab Mahiran Basri Mohd Basyaruddin Abdul Rahman Raja Noor Zaliha Raja Abdul Rahman Abu Bakar Salleh Thean Chor Leow 《International journal of molecular sciences》2012,13(9):11666-11680
The substitution of the oxyanion Q114 with Met and Leu was carried out to investigate the role of Q114 in imparting enantioselectivity on T1 lipase. The mutation improved enantioselectivity in Q114M over the wild-type, while enantioselectivity in Q114L was reduced. The enantioselectivity of the thermophilic lipases, T1, Q114L and Q114M correlated better with log p as compared to the dielectric constant and dipole moment of the solvents. Enzyme activity was good in solvents with log p < 3.5, with the exception of hexane which deviated substantially. Isooctane was found to be the best solvent for the esterification of (R,S)-ibuprofen with oleyl alcohol for lipases Q114M and Q114L, to afford E values of 53.7 and 12.2, respectively. Selectivity of T1 was highest in tetradecane with E value 49.2. Solvents with low log p reduced overall lipase activity and dimethyl sulfoxide (DMSO) completely inhibited the lipases. Ester conversions, however, were still low. Molecular sieves employed as desiccant were found to adversely affect catalysis in the lipase variants, particularly in Q114M. The higher desiccant loading also increased viscosity in the reaction and further reduced the efficiency of the lipase-catalyzed esterifications. 相似文献
68.
Lina Jassim Umer Rashid Suraya Abdul Rashid Mohamad Amran Salleh Sonny Irawan 《Chemical Engineering Communications》2016,203(4):463-470
A stable ester was synthesized to overcome the ester hydrolysis problem during the drilling of oil or gas wells using a conventional ester-based drilling fluid. The thermal and hydrolytic stability of the produced ester was high owing to the transesterification method employed in this study. The reaction was performed using 2-ethylhexanol and methyl laureate esters in the presence of sodium methoxide as a catalyst. In order to obtain the optimum synthesis conditions, a response surface methodology (RSM) was appraised based on the central composite design (CCD). The optimum conditions were determined as follows: 0.6 wt.% catalyst, 70°C reaction temperature, 1:1.5 molar ratio, and 11.5 min of reaction time. The results of 77 wt.% 2-ethylhexyl ester (2-EH) illustrated a high agreement between the experimental and RSM models. The reaction product contained 77 wt.% 2-EH and 23% 2-ethylhexanol. The kinematic viscosity was 5 mm2/s at 40°C and 1.5 mm2/sec at 100°C; the specific gravity was 0.854, flash point was 170°C, and pour point was ?7°C. The produced product showed similar properties to the available commercial product. However, it was observed that the mud formulation using the synthesized base oil had superior rheological properties at 121°C. 相似文献
69.
A new non-predictive video codec for mobile applications is presented. The scheme omits the prediction step in the temporal axis and increases robustness of its transmission in the mobile channel. The same subbands from each frame in the group of frames (GOP) are joined together to exploit their spatial-temporal redundancies. The significant vectors of the joined subbands within the GOP are quantised using a novel multi-stage lattice vector quantisation. This process reduces quantisation errors and enhances the reconstructed frame quality. Experimental results are shown to be significantly better than H.263 and comparable to the current H.264 standards in an erroneous hilly terrain mobile environment using the TETRA channel simulator for some test video sequences. 相似文献
70.
This paper presents the implementation of two hardware architectures, i.e., A2 Lattice Vector Quantization (LVQ) and Multistage A2LVQ (MA2LVQ), using a Field-Programmable Gate Array (FPGA). First, the renowned LVQ quantizer by Conway and Sloane is implemented followed by a low-complexity A2LVQ based on a new A2LVQ algorithm. It is revealed that the implementation requires high number of multiplier circuits. Then the implementation of a low-complexity A2LVQ is presented. This implementation uses only the first quadrant of the A2 lattice Voronoi region formed by W and T regions. This paper also presents the implementation of a multistage A2LVQ (MA2LVQ) with an architecture built from successive A2 quantizer blocks. Synthesis results show that the execution time of the low-complexity A2LVQ reaches up to 35.97 ns. The MA2LVQ is implemented using both low-complexity A2LVQ and ordinary A2 architectures. The system with the former architecture utilizes less logic and register elements by 47%. 相似文献