Control of structure and tack properties of acrylic pressure‐sensitive adhesives designed by a polymerization process

Free radical emulsion polymerization of methyl methacrylate (MMA) and 2‐ethylhexyl acrylate (EHA) results in the synthesis of pressure‐sensitive adhesives (PSAs) with good tack properties. Management of both the copolymer composition and the polymerization process allows one to control the behavior of the PSA. Semicontinuous (SC) processes create polymer particles whose instantaneous composition is close to that of the feed particle The SC Mixture process (continuous feeding with comonomer blends) affords nearly homogeneous latex particles and PSA films. The SC Gradient process (separate feedings at inversely varying rates) affords heterogeneous particles and films. The Batch process leads to somewhat heterogeneous films, but the hard (MMA‐rich) microdomains are made compatible with their soft (EHA‐rich) matrix because of the assumed formation of tapered‐type copolymers. Tack measurements indicate the importance of the particle and film structures. Too much hardness or softness leads to unacceptable lacks of adhesion and cohesion, respectively. Homogeneous structures prove adequate, but their tack properties collapse with rising temperature. Heterogeneous structures, with extensive phase segregation, prove unsatisfactory because they lack adhesion and cohesion. Finally, the association of well‐balanced composition and compatible heterogeneity is the criterion for suitable PSA behavior. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2749–2756, 2003     

地域通信网的干扰技术研究

本文在分析地域通信网结构及组成的基础上,研究了对地域通信网实施的节点破坏、末端信息封锁、局部阻塞瘫痪等对抗方法,并使用干扰地域通信网的程度、节点干扰率、末端节点封锁率和传递信息误差率等指标对干扰效果进行评估。     

Training sequence design and channel estimation of OFDM-CDMA broadband wireless access networks with diversity techniques

In this paper, an OFDM-CDMA system employing various diversity schemes is considered for a possible candidate of broadband wireless access networks and broadcasting applications. With an emphasis on a preamble design for multi-channel separation, we address a channel estimation based on the time-domain windowing and its imperfectness in OFDM-based multiple-antenna transmission systems. By properly designing each preamble for multiple antennas to be orthogonal in the time domain, the channel estimation can be applied to the HIPERLAN/2 and IEEE 802.11a standards in the case of more than two transmit antennas. Also, the effect of diversity techniques on the performance of OFDM-CDMA based broadband wireless access networks is investigated and the maximum achievable diversity gain for a two-path Rayleigh fading environment is evaluated. Simulation results show that the OFDM-CDMA system applying a space-time-frequency diversity with a full-rate full diversity code can give the diversity of D=4 and D=8 for both multi-user cases of maximum user and half user capacities, respectively.     

Metal-semiconductor-metal photodetectors with InAlGaP capping and buffer layers

To improve the Schottky contact performance and carrier confinement of GaAs metal-semiconductor-metal photodetectors (MSM-PDs), we employed the wide bandgap material, In/sub 0.5/(Al/sub 0.66/Ga/sub 0.34/)/sub 0.5/P, for the capping and buffer layers. We directly evaluated the Schottky contact parameters on the MSM-PD structure. The reverse characteristics of the Schottky contacts were examined by taking into account the Schottky barrier height depended on the electric field in the depletion region, and hence on the applied bias. The ideality factor and Schottky barrier height of Ti-Pt-Au contacts to In/sub 0.5/(Al/sub 0.66/Ga/sub 0.34/)/sub 0.5/P are 1.02 and 1.05 eV, respectively. Extremely low dark currents of 70 and 620 pA were obtained for these MSM-PDs when they were operated at a reverse bias of -10 V at room temperature and at 70/spl deg/C, respectively.     

3.5代通信中链路自适应技术的研究和仿真

3.5代移动通信中的链路自适应技术使用自适应调制编码和快速混合重传技术替代了3代中使用的功率控制技术。仿真结果比较了这两种新技术与功率控制技术的性能,证明了这两个新技术显著地提高了网络平均的吞吐量。     

Manipulation of microenvironment with a built-in electrochemical actuator in proximity of a dissolved oxygen microsensor

Biochemical sensors for continuous monitoring require dependable periodic self diagnosis with acceptable simplicity to check its functionality during operation. An in-situ self-diagnostic technique for a dissolved oxygen microsensor is proposed in an effort to devise an intelligent microsensor system with an integrated electrochemical actuation electrode. With a built-in platinum microelectrode that surrounds the microsensor, two kinds of microenvironments, called the oxygen-saturated or oxygen-depleted phases, can be created by water electrolysis, depending on the polarity. The functionality of the microsensor can be checked during these microenvironment phases. The polarographic oxygen microsensor is fabricated on a flexible polyimide substrate (Kapton) and the feasibility of the proposed concept is demonstrated in a physiological solution. The sensor responds properly during the oxygen-generating and oxygen-depleting phases. The use of these microenvironments for in-situ self-calibration is discussed to achieve functional integration, as well as structural integration, of the microsensor system.     

办公自动化系统中基于RBAC的授权模型

在基于角色的访问控制(RBAC)中,只给角色分配权限,用户必须成为角色中的一员才能取得相应的访问权限。基于角色授权的基本思想是:系统中某个成员将自己所拥有的权限授予另外一个成员,使之代表自己完成一定的工作。由于授权特征的多样性,授权模型有多种不同的状态。首先归纳出与授权有关的几种基本特征,然后根据办公自动化系统的具体业务情况将授权特征的组合进行精简,找出一组合适的状态,从而建立起办公自动化系统的授权模型。     

基于变轴力和定轴力试验对比的钢筋混凝土柱恢复力滞回特性研究

在讨论了框架柱在地震作用下轴力变化规律的基础上,通过由变轴力柱和定轴力柱的低周交变加载试验获得的恢复力滞回曲线对比,给出了用各个“轴力变化半周”的“等效滞回轴力”修正恢复力骨架曲线,和用“等效累积滞回轴力”随时间步长调整累积强度退化系数从而修正恢复力滞回曲线的再加载刚度的建议。该建议能更有效、更方便地反映轴力变化的整个历程对变轴力柱恢复特征的影响,有利于提高钢筋混凝土杆系结构非弹性地震反应分析的有效性。     

用沸石处理含磷废水的试验研究

对沸石处理含磷废水进行了试验研究，探讨了沸石用量，废水酸度，接触时间，温度及磷酸盐浓度对除磷效果的影响，结果表明，在废水pH值2－10，磷浓度0－100mg/L范围内，按磷与沸石重量比为1：200投加沸石进行处理，磷去除率可达90％，且处理后废水pH值近中性。