Effects of fertilisation on the allyl isothiocyanate profile of above‐ground tissues of New Zealand‐grown wasabi

Wasabi (Wasabia japonica (Miq) Matsum) is a developing crop in New Zealand and is valued for its spicy taste and pungent smell. It is popular as a condiment for traditional and modern Japanese foods. However, the limited area suitable for wasabi production in Japan has resulted in inability to meet increasing market demand. Isothiocyanates (ITCs) are sulphur compounds responsible for the unique flavour of wasabi, with allyl isothiocyanate (AITC) being the main compound responsible for the pungency. In this study, AITC tissue concentration and yield were measured in three above‐ground tissues of the wasabi plant to investigate the effects of different fertiliser, manure and lime treatments. The highest tissue concentration of AITC was found in the rhizomes, ranging from 1564 to 3366 mg kg^?1 (fresh weight basis), while the petioles and leaves contained 254–373 and 453–643 mg kg^?1 respectively. Fertilisation with ammonium sulphate produced the highest‐quality rhizomes (72% increase in AITC yield) and petioles (64% increase), but the best response in the leaves (51%) resulted from the manure treatment. Nitrogen fertiliser alone reduced the AITC yield by up to 15%. These results should help in formulating guidelines for production of high‐quality wasabi tops containing high levels of AITC. © 2002 Society of Chemical Industry     

Laminated Polymer-Encapsulated Halide Perovskite Photoconductors

Herein, a simple, solvent-free method to fabricate polymer-encapsulated halide perovskite photoconductors is described. Dry mechanochemical synthesis is used to prepare CsPbBr₃ in the presence of poly(butyl methacrylate) (PBMA). The resulting composite powder is then heated and pressed into a free-standing disk with a thickness controlled by a metallic spacer ring. The disk can be laminated on a glass substrate patterned with interdigitated electrodes, resulting in a planar photoconductor device. The best photoconductive performance is obtained for disks that consist of 75 wt.% CsPbBr₃ in PBMA, reaching a detectivity of ≈2 × 10¹¹ Jones. Moreover, by adjusting the thickness of the disk, narrowband detectors can be obtained due to charge collection narrowing. Depending on the thickness of the pressed disk, the position and width of the detectivity peak can be tuned. At last, the disks are tested as possible absorber materials for X-ray detectors, where ow detection limit, and fast and linear response are measured for perovskite-polymer disks with 50 wt.% perovskite content. This work shows a simple and versatile approach toward the fabrication of halide perovskite photodetectors, which can be carried out in air and without the use of solvents.     

Volatiles from Psylla-Infested Pear Trees and Their Possible Involvement in Attraction of Anthocorid Predators

Previous work showed that anthocorid predators aggregate around gauze cages containing Psylla-infested trees in a pear orchard. Because anthocorids responded to odor from Psylla-infested leaves in a laboratory test, it was hypothesized that these aggregative responses in the field were triggered by olfaction of compounds associated with Psylla injury. We present chemical analyses of volatiles from damaged and undamaged plants and studies on behavioral responses of anthocorid predators to compounds released by damaged plants. Leaf headspace volatiles from clean and Psylla-infested pear trees were collected on Tenax and identified by GC-MS after thermodesorption. Twelve volatiles were found exclusively in headspace samples from Psylla-infested leaves. Six were present in significantly higher quantities in samples from infested leaves: the monoterpene, (E,E)-α-farnesene, the phenolic, methyl salicylate, and the green leaf compounds, (Z)-3-hexen-1-yl acetate, (Z)-3-hexen-1-ol, 1-hexyl-acetate, and 1-penten-3-ol. These compounds are known to be produced by plants, and damage by pear psyllids seems to trigger their emission. Blend composition varied and was partly correlated with tree or leaf age and degree of Psylla infestation. To study whether compounds associated with leaf injury elicit olfactory responses in anthocorid predators, apple-extracted (E,E)-α-farnesene, synthetic methyl salicylate, and (Z)-3-hexen-1-yl acetate were offered in a Y-tube olfactometer to field-collected adult Anthocoris spp. Significant positive responses were found to both the monoterpene and the phenolic, but not to the green leaf volatile. The results lend support to the hypothesis that predator attraction to herbivore-infested pear trees is mediated by herbivory-induced plant volatiles.     

CCS with Hennessy''s merge has no finite-equational axiomatization

This paper confirms a conjecture of Bergstra and Klop's from 1984 by establishing that the process algebra obtained by adding an auxiliary operator proposed by Hennessy in 1981 to the recursion free fragment of Milner's Calculus of Communicating Systems is not finitely based modulo bisimulation equivalence. Thus, Hennessy's merge cannot replace the left merge and communication merge operators proposed by Bergstra and Klop, at least if a finite axiomatization of parallel composition modulo bisimulation equivalence is desired.     

A multi-scale, multi-model approach for analyzing the future dynamics of European land use

Europe’s rural areas are expected to witness massive and rapid changes in land use due to changes in demography, global trade, technology and enlargement of the European Union. Changes in demand for agricultural products and agrarian production structure are likely to have a large impact on landscape quality and the value of natural areas. Most studies address these changes either from a macro-economic perspective focusing on changes in the agricultural sector or from a local perspective by analyzing recent changes in landscapes for small case studies. This paper describes a methodology in which a series of models has been used to link global level developments influencing land use to local level impacts. It is argued that such an approach is needed to properly address the processes at different scales that give rise to the land use dynamics in Europe. An extended version of the global economic model (GTAP) and an integrated assessment model (IMAGE) are used to calculate changes in demand for agricultural areas at the country level while a spatially explicit land use change model (CLUE-s) was used to translate these demands to land use patterns at 1 km² resolution. The global economic model ensures an appropriate treatment of macro-economic, demographic and technology developments and changes in agricultural and trade policies influencing the demand and supply for land use related products while the integrated assessment model accounts for changes in productivity as result of climate change and global land allocation. The land use change simulations at a high spatial resolution make use of country specific driving factors that influence the spatial patterns of land use, accounting for the spatial variation in the biophysical and socio-economic environment. Results indicate the large impact abandonment of agricultural land and urbanization may have on future European landscapes. Such results have the potential to support discussions on the future of the rural area and identify hot-spots of landscape change that need specific consideration. The high spatial and thematic resolution of the results allows the assessment of impacts of these changes on different environmental indicators, such as carbon sequestration and biodiversity. The global assessment allows, at the same time, to account for the tradeoffs between impacts in Europe and effects outside Europe.     

Colloidal organic matter fouling of UF membranes: role of NOM composition & size

The aim of this study was to fractionate pre-filtered surface water using a 3.5 and a 10 kDa dialysis membrane, and to compare the rate of fouling and the fouling reversibility/irreversibility of the NOM fractions. Trial dialyses (3.5 and 10 kDa) were carried out for 6 and 21 days with pre-filtered surface water using synthetic surface water as dialysate. The aim of the trials was to optimize the dialysis process for NOM fractionation. DOC, Ca²⁺, Mg²⁺, soluble silica and bacteria were monitored at intervals during the dialysis process. Thereafter, the various NOM fractions (with low and high Ca²⁺) were fed to a miniature UF system operated at a constant flux of 138.5 L/m2 h, filtration cycle times of 31.5 min and backwash duration of 1.75 min. A PES/PSV hollow fiber UF membrane (MWCO 100 kDa) with a surface area of 0.0125 m² was employed for the filtration tests (X-Flow). Transmembrane pressure (TMP) and UF feed and permeate (LC-OCD) were monitored at regular intervals. For a dialysate recirculation of 95 L/h, sample to dialysate ratio of 5.2:80 L and a dialysate change frequency of 3 times per 24 h, the shortest duration of dialysis was about 6–7 days for both 3.5 and 10 kDa dialyses membranes. The removal of organic carbon (OC) increased with dialysis duration and MWCO of the bags. The biopolymer fraction increased from 120% to 240% when the duration of dialysis was increased from 6 days (1.1 mg DOC/L, 151 mg Ca/L) to 21 days (0.82 mg DOC/L, 133 mg Ca/L) with the 10 kDa dialysis membrane. The increased biopolymer fraction in the NOM sample that was dialyzed for 21 days resulted in a doubling of the fouling rate from 3.5 to 6.6 mbar/min per mg DOC/L. The other NOM fractions (humics and building blocks) and the Ca/DOC ratio was more or less the same in both NOM samples suggesting that biopolymers were the major cause of UF fouling.     

Structural health monitoring system of the long-span bridges in Turkey

Abstract

This study presents the general features of the structural health monitoring (SHM) system of the long-span cable-supported bridges in Turkey, namely the First Bosphorus Bridge, the Second Bosphorus Bridge (Fatih Sultan Mehmet Bridge), the newly constructed the Third Bosphorus Bridge (Yavuz Sultan Selim) and the Osman Gazi Bridge (Izmit Bay Bridge). Due to the critical function of the bridges in the transportation networks of Istanbul, structural health under extreme and operational load cases without interruption of their operation is essential. The SHM systems are already available and in use for the First and Second Bosphorus Bridges; however, the Yavuz Sultan Selim and the Osman Gazi Bridges, only have the preliminary SHM systems established. General preferences of the current and planned SHM systems of the bridges are given based on the monitoring objectives and requirements. Data collected from the SHM systems are also exhibited as an illustration for structural modal identification of the First Bosphorus Bridge. Based on the experiences from the current SHM systems, future works and planning are recommended to effectively design new SHM system and to efficiently update the current ones.     

Real-time single-molecule imaging of oxidation catalysis at a liquid-solid interface

Many chemical reactions are catalysed by metal complexes, and insight into their mechanisms is essential for the design of future catalysts. A variety of conventional spectroscopic techniques are available for the study of reaction mechanisms at the ensemble level, and, only recently, fluorescence microscopy techniques have been applied to monitor single chemical reactions carried out on crystal faces and by enzymes. With scanning tunnelling microscopy (STM) it has become possible to obtain, during chemical reactions, spatial information at the atomic level. The majority of these STM studies have been carried out under ultrahigh vacuum, far removed from conditions encountered in laboratory processes. Here we report the single-molecule imaging of oxidation catalysis by monitoring, with STM, individual manganese porphyrin catalysts, in real time, at a liquid-solid interface. It is found that the oxygen atoms from an O2 molecule are bound to adjacent porphyrin catalysts on the surface before their incorporation into an alkene substrate.     

Drivers of European landscape change: stakeholders’ perspectives through Fuzzy Cognitive Mapping

Understanding complex processes of landscape change is crucial to guide the development of future landscapes and land resources. Through Fuzzy Cognitive Mapping, we studied the processes of landscape change of six different environmental zones in Europe. Results show that landscapes are complex systems, with many interactions. Except for one, all regions show a strong decline in landscape quality. Dominant drivers are EU policy and the global economy, sometimes in conjunction with environmental drivers or the governance system. The process of change differs for all cases, through urbanisation or land abandonment in some cases, and agricultural intensification in others. The (un)intended effects of policies are difficult to predict. Although some EU Policies directly improve landscape quality, their indirect effects as well as other EU policies outweigh this positive influence and jointly result in a decrease of landscape quality. To counter these negative side effects, targeted landscape policies are urgently needed.