Combination of Reaction and Separation in Heterogeneous Catalytic Hydrogenation of Ethylformate

Continuous hydrogenation reaction of ethyl benzoylformate was studied over a (–)‐cinchonidine (CD)‐modified Pt/Al₂O₃ catalyst. The catalyst showed a good stability, and high enantioselectivity was achieved in the fixed‐bed reactor. Chromatographic separation of (R)‐ and (S)‐ethyl mandelate originating from a post‐continuous hydrogenation reaction of ethyl benzoylformate over the (–)‐CD‐modified Pt/Al₂O₃ catalyst was investigated in the same reaction mixture. A commercial column filled with a chiral selector resin was chosen as a perspective preparative‐scale adsorbent. Since adsorption equilibrium isotherms were linear within the entire investigated range of concentrations, they were determined by pulse experiments for the isomers present in a post‐reaction mixture. Breakthrough curves were measured and described successfully by the dispersive plug‐flow model with linear driving force approximation.     

Effects of feeding bentonite clay upon ochratoxin A–induced immunosuppression in broiler chicks

A presence of mycotoxins in feed is one of the most alarming issues in the poultry feed industry. Ochratoxins, produced by several Aspergillus and Penicillium species, are important mycotoxin regarding the health status of poultry birds. Ochratoxins are further classified into to several subtypes (A, B, C, etc) depending on their chemical structures, but ochratoxin A (OTA) is considered the most important and toxic. Bentonite clay, belonging to phyllosilicates and formed from weathering of volcanic ashes, has adsorbent ability for several mycotoxins. The present study was designed to study the effects of bentonite clay upon OTA-induced immunosuppression in broiler chicks. For this, 480 day-old broiler chicks were procured from a local hatchery and then different combinations of OTA (0.15, 0.3, or 1.0 mg/kg) and bentonite clay (5, 10, and 20 g/kg) were incorporated into their feed. At 13, 30, and 42 days of age, parameters such as antibody responses to sheep red blood cells, in situ lymphoproliferative responses to mitogen (PHA-P), and in situ phagocytic activity (i.e., via carbon clearance) were determined respectively. The results indicated there was a significant reduction of total antibody and immunoglobulin titres, lymphoproliferative responses, and phagocytic potential in OTA-treated birds, suggesting clear immunosuppression by OTA in birds in a dose-dependent manner. These results were also significantly lower in all combination groups (OTA with bentonite clay), suggesting few to no effects of feeding bentonite clay upon OTA- induced alterations in different immune parameters.     

Performance improvement of microbial fuel cell through artificial intelligence

The current work introduces an enhancement in the performance of the microbial fuel cell through estimating the optimal set of controlling parameters. The maximization of both power density (PD) and the percentage of chemical oxygen demand (COD) removal were considered as the enhancement in the cell's performance. Three main parameters in terms of performance as well as commercialization are the system's inputs; the Pt which takes the range of 0.1‐0.5 mg/cm², the degree of sulphonation in sulfonated‐poly‐ether‐ether‐ketone that changes in the range of 20‐80%, and the rate of aeration of cathode which varies between 10 and 150 mL/min. From the experimental dataset, two robust adaptive neuro‐fuzzy inference system models based on the fuzzy logic technique have been constructed. The comparisons between the models' outputs and the experimental data showed well‐fitting in both training and testing datasets. The mean squared errors of the PD model, for testing and whole datasets, were found 2.575 and 0.909 while for the COD model it showed 19.242 and 6.791, respectively. Then, based on the two fuzzy models, a Particle Swarm Optimization algorithm has been used to determine the best parameters that maximize both of the PD and the COD removal of the cell. The optimization process was utilized for single and multi‐object optimization processes. In the single optimization, the resulting maximums of the PD and the COD removal were found 62.844 (mW/m²) and 99.99 (%), respectively. Whereas, in the multi‐object optimization, the values of 61.787 (mW/m²) and 96.21 (%) were reached as the maximums for the PD and COD, respectively. This implies that, in both cases of optimization processes, the adopted methodology can efficiently enhance the microbial fuel cell performances than the previous work.     

Efficient Photomodulation of Visible Eu(III) and Invisible Yb(III) Luminescences using DTE Photochromic Ligands for Optical Encryption

This work describes a class of complex combining three dithienylethene units and a lanthanide ion used as an optical system displaying a double encryption method: i) a colorful code, drawn and erased under UV and visible irradiations respectively, due to coloration and discoloration of the photochromic entities, and ii) a concomitant gradual disappearance and progressive restoration of the associated lanthanide ion luminescence triggered with the same stimuli. The innovation of the system stems from the emission color tunability, i.e., with either a lanthanide ion emitting only in the visible range (Eu³⁺) or with another lanthanide ion emitting only in the near infrared (NIR) range (Yb³⁺), therefore observable, or not, to the naked eye. This system is the very first one to achieve efficient repeatable modulation of pure NIR luminescence on photochemical command. Furthermore, it is proven to be highly efficient when embedded in a PDMS polymer opening real opportunities for practical applications as anti‐counterfeiting.     

Exploring network-level performances of wireless nanonetworks utilizing gains of different types of nano-antennas with different materials

Wireless nanonetworks are not a simple extension of traditional communication networks at the nano-scale. Owing to being a completely new communication paradigm, existing research in this field is still at an embryonic stage. Furthermore, most of the existing studies focus on performance enhancement of nanonetworks via designing new channel models and routing protocols. However, the impacts of different types of nano-antennas on the network-level performances of the wireless nanonetworks remain still unexplored in the literature. Therefore, in this paper, we explore the impacts of different well-known types of antennas such as patch, dipole, and loop nano-antennas on the network-level performances of wireless nanonetworks. We also investigate the performances of nanonetworks for different types of traditional materials (e.g., copper) and for nanomaterials (e.g., carbon nanotubes and graphene). We perform rigorous simulation using our customized ns-2 simulation to evaluate the network-level performances of nanonetworks exploiting different types of nano-antennas using different materials. Our evaluation reveals a number of novel findings pertinent to finding an efficient nano-antenna from its several alternatives for enhancing network-level performances of nanonetworks. Our evaluation demonstrates that a dipole nano-antenna using copper material exhibits around 51% better throughput and about 33% better end-to-end delay compared to other alternatives for large-size nanonetworks. Furthermore, our results are expected to exhibit high impacts on the future design of wireless nanonetworks through facilitating the process of finding the suitable type of nano-antenna and suitable material for the nano-antennas.

     

Polylactide‐perylene derivative for blue biodegradable organic light‐emitting diodes

In this work we demonstrate, for the first time, the use of polylactic acid (PLA) as a biodegradable host matrix for the construction of the active emissive layer of organic light‐emitting diode (OLED) devices for potential use in bioelectronics. In this preliminary study, we report a robust synthesis of two fluorescent PLA derivatives, pyrene‐PLA ( AH10 ) and perylene‐PLA ( AH11 ). These materials were prepared by the ring opening polymerisation of l ‐lactide with hydroxyalkyl‐pyrene and hydroxyalkyl‐perylene derivatives using 1,8‐diazabicyclo[5.4.0]undec‐7‐ene as catalyst. OLEDs were fabricated from these materials using a simple device architecture involving a solution‐processed single‐emitting layer in the configuration ITO/PEDOT:PSS/PVK:OXD‐7 (35%): AH10 or AH11 (20%)/TPBi/LiF/Al (ITO, indium tin oxide; PEDOT:PSS, poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonic acid); PVK, poly(vinylcarbazole); OXD‐7, (1,3‐phenylene)‐bis‐[5‐(4‐tert‐butylphenyl)‐1,3,4‐oxadiazole]; TPBi, 2,2′,2″‐(1,3,5‐benzenetriyl)tris(1‐phenyl‐1H‐benzimidazole)). The turn‐on voltage for the perylene OLED at 10 cd m^–2 was around 6 V with a maximum brightness of 1200 cd m^–2 at 13 V. The corresponding external quantum efficiency and device current efficiency were 1.5% and 2.8 cd A^–1 respectively. In summary, this study provides proof of principle that OLEDs can be constructed from PLA, a readily available and renewable bio‐source. © 2020 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry.     

A green approach for modification and functionalization of wool fabric using bio- and nano-technologies

In the present work, we propose a green and sustainable strategy for eco-friendly surface modification of wool structure using biosynthesized kerationlytic proteases, from C4-ITA-EGY, Streptomyces harbinensis S11-ITA-EGY and Streptomyces carpaticus S33-ITA-EGY, followed by subsequent environmentally sound functionalization of the bio-treated substrates using ZnONPs, ZrO₂NPs, ascorbic acid and vanillin, individually, to provide durable antibacterial as well as UV-protection properties. Both surface modification changes and the extent of functionalization of the final products were characterized by SEM, EDX, antibacterial efficacy, UV-blocking ability, loss in weight, nitrogen content and durability to washing analysis. The obtained data reveal that the developed green wool fabrics exhibit outstanding durable antibacterial activity and UV-blocking ability for fabricating multi-functional textile products that can be utilized in a wide range of sustainable protective textiles, irrespective of the used post-finishing formulation ingredients. The results also show that both modification and functionalization processes are governed by the type of enzyme and kind of active material respectively. Moreover, the biosynthesized kerationlytic proteases could be accessibly used to remove protein-based stains like blood and egg.

Graphical abstract