Comparative study of adsorption properties of Turkish fly ashes. II. The case of chromium (VI) and cadmium (II)

The purpose of the study described in this paper was to compare the removal of Cr(VI) and Cd(II) from an aqueous solution using two different Turkish fly ashes; Afsin-Elbistan and Seyitomer as adsorbents. The influence of four parameters (contact time, solution pH, initial metal concentration in solution and ash quality) on the removal at 20+/-2 degrees C was studied. Fly ashes were found to have a higher adsorption capacity for the adsorption of Cd(II) as compared to Cr(VI) and both Cr(VI) and Cd(II) required an equilibrium time of 2h. The adsorption of Cr(VI) was higher at pH 4.0 for Afsin-Elbistan fly ash (25.46%) and pH 3.0 for Seyitomer fly ash (30.91%) while Cd(II) was adsorbed to a greater extent (98.43% for Afsin-Elbistan fly ash and 65.24% for Seyitomer fly ash) at pH 7.0. The adsorption of Cd(II) increased with an increase in the concentrations of these metals in solution while Cr(VI) adsorption decreased by both fly ashes. The lime (crystalline CaO) content in fly ash seemed to be a significant factor in influencing Cr(VI) and Cd(II) ions removal. The linear forms of the Langmuir and Freundlich equations were utilised for experiments with metal concentrations of 55+/-2mg/l for Cr(VI) and 6+/-0.2mg/l for Cd(II) as functions of solution pH (3.0-8.0). The adsorption of Cr(VI) on both fly ashes was not described by both the Langmuir and Freundlich isotherms while Cd(II) adsorption on both fly ashes satisfied only the Langmuir isotherm model. The adsorption capacities of both fly ashes were nearly three times less than that of activated carbon for the removal of Cr(VI) while Afsin-Elbistan fly ash with high-calcium content was as effective as activated carbon for the removal of Cd(II). Therefore, there are possibilities for use the adsorption of Cd(II) ions onto fly ash with high-calcium content in practical applications in Turkey.     

Automatic detection of depression symptoms in twitter using multimodal analysis

The Journal of Supercomputing - Depression is the most prevalent mental disorder that can lead to suicide. Due to the tendency of people to share their thoughts on social platforms, social data...     

Robust non-aggressive three-axis attitude control of spacecraft: dynamic sliding mode approach

Conventional sliding mode control (SMC) has been extensively applied in controlling spacecrafts because of its appealing characteristics such as robustness and a simple design procedure. Several methods such as second-order sliding modes and discontinuous controllers are applied for the SMC implementation. However, the main problems of these methods are convergence and error tracking in a finite amount of time. This paper combines an improved dynamic sliding mode controller and model predictive controller for spacecrafts to solve the chattering phenomenon in traditional sliding mode control. To this aim, this paper develops dynamic sliding mode control for spacecraft’s applications to omit the chattering issue. The proposed approach shows robust attitude tracking by a set of reaction wheels and stabilizes the spacecraft subject to disturbances and uncertainties. The proposed method improves the performance of the SMC for spacecraft by avoiding chattering. A set of simulation results are provided that show the advantages and improvements of this approach (in some sense) compared to SMC approaches.     

Analytical design of optimal trajectory with dynamic load-carrying capacity for cable-suspended manipulator

This paper describes the development of an approach for trajectory planning of cable-suspended parallel robots using optimal control approach. A prototype has been built, and tests have been carried out to verify the theoretical results. This paper briefly illustrates this device and presents some initial tests. The final dynamic equations are organized in a closed form similar to serial manipulator equations. Dynamic load-carrying capacity problem is converted into a trajectory optimization problem which is fundamentally a constrained nonlinear optimization problem. The problem is formulated using optimal control theory, and the ideas are analyzed using Pontryagin’s minimum principle. The optimal solutions are found by solving the corresponding nonlinear two-point boundary value problems. The main objective is to find the manipulator load-carrying capacity in point-to-point task by considering actuator torque while cable forces are positive.     

Heavy paraffin dehydrogenation and hydrogenation of nitrobenzene to aniline: Effects of operating conditions

Auto-thermal heat exchanger configurations are recognized as a novel concept in process intensification. In the current study, the influence of operating conditions in a novel coupling reactor with radial-flow pattern is investigated for heavy paraffin dehydrogenation process. Catalytic hydrogenation of nitrobenzene to aniline takes place in the exothermic side and supplies the necessary heat for the endothermic dehydrogenation of heavy paraffin reaction. The performance of the reactor is numerically investigated for various key operating variables, such as inlet molar flow rates of exothermic and endothermic streams, number of subsections, and exothermic side angle. The reactor performance is analyzed based on temperature, olefin production rate, and nitrobenzene conversion.     

Free vibration analysis of solar functionally graded plates with temperature-dependent material properties using second order shear deformation theory

Second-order shear deformation theory (SSDT) is employed to analyze vibration of temperature-dependent solar functionally graded plates (SFGP’s). Power law material properties and linear steady-state thermal loads are assumed to be graded along the thickness. Two different types of SFGP’s such as ZrO₂/Ti-6Al-4V and Si₃N₄/SUS304 are considered. Uniform, linear, nonlinear, heat-flux and sinusoidal thermal conditions are imposed at the upper and lower surface for simply supported SFGPs. The energy method is applied to derive equilibrium equations, and solution is based on Fourier series that satisfy the boundary conditions (Navier’s method). Non-dimensional results are compared for temperature-dependent and temperature-independent SFGP’s and validated with known results in the literature. Numerical results indicate the effect of material composition, plate geometry, and temperature fields on the vibration characteristics and mode shapes. The results obtained using the SSDT are very close to results from other shear deformation theories.     

Eye gesture blink password: a new authentication system with high memorable and maximum password length

Multimedia Tools and Applications - Authentication systems in which eye is used for entering the password are categorized into two gaze-based and gesture-based groups. In the accurate...     

Two‐Layer Terminal Sliding Mode Attitude Control of Satellites Equipped with Reaction Wheels

This paper addresses the global stability and robust attitude tracking problem of a near polar orbit satellite subject to unknown disturbances and uncertainties. It is assumed that the satellite is fully actuated by a set of reaction wheels (RW) as control actuators because of their relative simplicity, versatility and high accuracy. The terminal sliding mode control (TSMC) approach is utilized in a two‐level architecture to achieve control objectives. In the lower layer a detumbling‐like controller is designed which guarantees the finite‐time detumbling and tracking of the desired angular velocities and based on this result a robust attitude tracking controller is designed in the upper layer to achieve 3‐axis attitude tracking in the presence of unknown disturbances and bounded uncertainties. Robust stability and tracking properties of designed controllers are proved using the Lyapunov theory. Finally, a set of numerical simulation results are provided to illustrate the effectiveness and performance of the proposed control method.