Effects of composition and phase relations on mechanical properties and crystallization of silicate glasses

Crystallization, mechanical properties, and workability are all important for the commercialization and optimization of silicate glass compositions. However, the inter-relations of these properties as a function of glass composition have received little investigation. Soda-lime-silica glasses with Na₂O-MgO-CaO-Al₂O₃-SiO₂ compositions relevant to commercial glass manufacture were experimentally studied and multiple liquidus temperature and viscosity models were used to complement the experimental results. Liquidus temperatures of the fabricated glasses were measured by the temperature gradient technique, and Rietveld refinements were applied to X-Ray powder diffraction (XRD) data for devitrified glasses, enabling quantitative determination of the crystalline and amorphous fractions and the nature of the crystals. Structural properties were investigated by Raman spectroscopy. Acoustic echography, micro-Vicker's indentation, and single-edge-notched bend testing methods were used to measure Young's moduli, hardness, and fracture toughness, respectively. It is shown that it is possible to design lower-melting soda-lime-silica glass compositions without compromising their mechanical and crystallization properties. Unlike Young's modulus, brittleness is highly responsive to the composition in soda-lime-silica glasses, and notably low brittleness values can be obtained in glasses with compositions in the wollastonite primary phase field: an effect that is more pronounced in the silica primary phase field. The measured bulk crystal fractions of the glasses subjected to devitrification at the lowest possible industrial conditioning temperatures indicate that soda-lime-silica glass melts can be conditioned close to their liquidus temperatures within the compositional ranges of the primary phase fields of cristobalite, wollastonite, or their combinations.     

Growth and characterization of tetragonal bismuth ferrite–lead titanate thin films

Thin films of tetragonal bismuth ferrite–lead titanate (1 − x)BiFeO₃–xPbTiO₃ with x = 0.9–0.7 were prepared by pulsed laser deposition (PLD). The films exhibit a dense columnar grain growth. XRD analysis reveals that the films have a perovskite structure and exhibit a preferred (1 1 1) texture. The film microstructure was studied using SEM. The ferroelectric properties of the films are discussed in the light of polarization-field hysteresis behaviour and impedance spectroscopy. The remanent polarization values ranged between 2P_r  45 and 60 μC cm⁻² at a field amplitude of 500 kV cm⁻¹ and −10 °C, while the dielectric permittivity of the films ranged between 375 and 1096 at a frequency of 2 kHz.     

A density functional theory study of hydrogen recombination and hydrogen-deuterium exchange on Ga/H-ZSM-5

Density functional theory calculations have been carried out to determine the thermodynamic stability of various Ga species in gallium-exchanged ZSM-5, the thermodynamics of H₂ adsorption, and the most favorable pathway for H₂/D₂ exchange. The portion of the zeolite associated with Ga was represented by a cluster containing 7, 21, or 33 atoms. The B3LYP hybrid method was used to account for the effects of electron exchange and correlation. The most likely form of Ga expected in freshly exchanged and calcined ZSM-5 is ZGa(OH)₂. H₂ reduction of this species is projected to produce ZGa(H)(OH) and ZGa(H)₂. While the thermodynamics of H₂ desorption from ZGa(H)₂ are favorable, the process is projected to be slow because of a high activation barrier. The most favorable pathway for H₂/D₂ exchange over ZGa(H)₂ proceeds via Z(D)(Ga(H)₂(D)) as an intermediate. Similar calculations have been carried out for H₂/D₂ exchange over H-ZSM-5. This revised version was published online in June 2006 with corrections to the Cover Date.     

editorial

Fouling of heat exchangers is a chronic problem in processing industries. In addition to the appropriate selection of operating conditions and exchanger geometry, there are numerous chemical and mechanical methods to mitigate fouling and to remove deposits from the heat transfer surfaces. However, all methods to reduce fouling require some understanding of the mechanisms of the deposition process and of the structure and adhesion of deposits on the heat transfer surfaces. Almost exactly 50 years ago, D. Q. Kern and his co-author, R. E. Seaton, published a paper attempting to describe the growth of fouling deposits in terms of an unsteady-state heat and mass balance for the heat transfer surface. More or less at the same time, the TEMA fouling resistances were published based on operational and anecdotal evidence of fouling for a range of heat exchanger applications. These two approaches have since formed the basis for most heat transfer fouling models and heat exchanger designs. Increased costs of energy, raw materials, and production downtime have contributed to the growing interest in heat transfer fouling. More recently, environmental legislation has put additional pressure on fouling-related CO₂ emissions and disposal of cleaning chemicals. Despite these efforts, fouling of heat exchangers is still far from been understood in its whole complexity. The present paper documents the 2009 D. Q. Kern Award Lecture in which some selected aspects of fouling research to date have been presented and areas have been identified where significant research and development activities are still required.     

Short communication: Postruminal infusion of conjugated linoleic acids negatively impacts milk synthesis in Holstein cows

In view of the potential of rumen-protected conjugated linoleic acid (CLA) as a means to increase the CLA content of bovine milk, a study was undertaken to evaluate the effect of synthetic CLA on milk production and composition. Four Holstein cows received abomasal infusion of: 1) control, no lipid infusion, 2) 150 g/d of synthetic CLA, 31.7% cis-9, trans-11; 30.4% trans-10, cis-12, 3) 150 g/d of safflower oil, and 4) 150 g/d of tallow. Infusion was carried out for 20 to 22 h/d for 11-d periods in a 4 x 4 Latin square design. The milk fat concentration of cis-9, trans-11 and trans-10, cis-12 isomers of CLA was significantly increased with infusion of CLA. However, CLA infusion had other unexpected effects on milk production and composition. Milk yield dropped significantly during the period of CLA infusion. Furthermore, as well as the typical depression in milk fat reported with trans-10 isomers of CLA, other negative effects specific to CLA infusion were observed including a drop in lactose concentration and yield, a drop in protein yield, and an elevated somatic cell count. The important difference between synthetically produced CLA and CLA produced naturally in the cow is the much higher proportion of trans-10 isomers of CLA in the former. The results of this study suggest that the extent of enrichment possible for trans-10 isomers of CLA, and hence the usefulness of synthetic CLA for this purpose, may be limited because of unacceptable effects on milk yield and composition.     

Review of high level fault modeling approaches for mixed-signal systems

In the modern analogue design, Transistor Level Fault Simulation (TLFS) plays the important part since every fault in the whole circuit has to be simulated at that level. Unfortunately, it is a very CPU intensive task even though it maintains the high accuracy. Therefore, High Level Fault Modeling (HLFM) and High Level Fault Simulation (HLFS) are required in order to alleviate the efforts of simulation. In this paper, different HLFM approaches are reviewed at the device level during last two decades. We clarify their domains of application and evaluate their strengths and current limitations. We also analyze causes of faults and introduce various test approaches.     

Characterization of film-coated aerosol canisters using electrochemical impedance spectroscopy

Drug adhesion to the walls of an aerosol canister can be prevented/reduced by coating the canister with a hydrophobic polymer (e.g., a fluoropolymer). In this study, three batches of fluoropolymer-coated canisters were investigated by electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The EIS technique showed that only one of the batches presented as a monolithic, non-porous film. The other two batches were either partially porous or highly porous. Scanning electron micrographs showed evidence of cracks, within the films, but could not alone establish the porous nature of these defects. For the non-porous and partly porous films it was possible to use the EIS data to determine the approximate film thickness. Estimates of 2-4 µm were obtained for the mean film thickness. These values compared favorably with micrometer estimates obtained following acid dissolution of the aluminum canister. It remains to be seen whether the properties of the films (i.e., the porosity and film thickness, determined by EIS) translate to differences in drug adhesion. Nevertheless, the EIS technique was shown to be a powerful, non-destructive method that lends itself to the rapid analysis of batch-to-batch variation in film-coated canisters.     

Relationships among team ability composition, team mental models, and team performance.

This study examined the relationship between the similarity and accuracy of team mental models and compared the extent to which each predicted team performance. The relationship between team ability composition and team mental models was also investigated. Eighty-three dyadic teams worked on a complex skill task in a 2-week training protocol. Results indicated that although similarity and accuracy of team mental models were significantly related, accuracy was a stronger predictor of team performance. In addition, team ability was more strongly related to the accuracy than to the similarity of team mental models and accuracy partially mediated the relationship between team ability and team performance, but similarity did not. (PsycINFO Database Record (c) 2010 APA, all rights reserved)