Water vapor transport in liquid crystalline and non-liquid crystalline epoxies

This paper presents a comparison of moisture permeation in liquid crystalline and non-liquid crystalline epoxy systems. The permeability is obtained using a dynamic method. It is found that diffusion in both epoxy systems is Fickian. The liquid crystalline epoxy network exhibits higher barrier properties to moisture transport than the conventional epoxy network. The efficient chain packing of the smectic mesophase of the liquid crystalline epoxy is the main factor for this difference. The stoichiometry has a large effect on the moisture permeation. The diffusion coefficient decreases monotonically with increasing amine/epoxide functional ratio. The permeability (P) and solubility coefficient (S) reach a minimum for a functional ratio of one. The results are described on the basis of hydrogen bonding of water to the epoxy network and the two phase morphology of cured epoxies.     

PCL Nanopillars Versus Nanofibers: A Contrast in Progenitor Cell Morphology,Proliferation, and Fate Determination

The role of nanotopography on the long‐term response of progenitor cells is explored using polycaprolactone (PCL) nanopillar and nanofiber surfaces seeded with plastic‐adherent rat multipotent mesenchymal stromal cells (MSCs). After 4 weeks in culture under normal expansion media conditions, MSCs cultured on nanofibers exhibit better adherence, increased proliferation, and maintain increasingly dense fibroblast‐like morphologies. In contrast, MSCs seeded on nanopillar surfaces display lowered adherence, reduced proliferation, and adopt highly elongated cellular morphologies. Immunofluorescent staining of MSCs on PCL nanopillars reveals the presence of two bone marker proteins, osteopontin and osteocalcin, providing evidence for surface induced differentiation into osteoblast‐like cells. Unlike the nanopillar topography, MSCs cultured on nanofiber and smooth PCL surfaces did not appear to undergo osteogenesis. Observed differences in cellular response to the PCL nanotopographies offer strategies to direct progenitor cell populations solely based upon submicron surface modifications. This study provides a foundation for future work exploring variations in PCL nanopillar topography with the goal of optimizing adherence and osteogenic response of MSCs.     

Proofs, Programs, Processes

The objective of this paper is to provide a theoretical foundation for program extraction from inductive and coinductive proofs geared to practical applications. The novelties consist in the addition of inductive and coinductive definitions to a realizability interpretation for first-order proofs, a soundness proof for this system, and applications to the synthesis of non-trivial provably correct programs in the area of exact real number computation. We show that realizers, although per se untyped, can be assigned polymorphic recursive types and hence represent valid programs in a lazy functional programming language such as Haskell. Programs extracted from proofs using coinduction can be understood as perpetual processes producing infinite streams of data. Typical applications of such processes are computations in exact real arithmetic. As an example we show how to extract a program computing the average of two real numbers w.r.t. the binary signed digit representation.     

Benchmarking flexible job-shop scheduling and control systems

Benchmarking is comparing the output of different systems for a given set of input data in order to improve the system’s performance. Faced with the lack of realistic and operational benchmarks that can be used for testing optimization methods and control systems in flexible systems, this paper proposes a benchmark system based on a real production cell. A three-step method is presented: data preparation, experimentation, and reporting. This benchmark allows the evaluation of static optimization performances using traditional operation research tools and the evaluation of control system's robustness faced with unexpected events.     

Machine learning in continuous casting of steel: a state-of-the-art survey

Journal of Intelligent Manufacturing - Continuous casting is the most important route for the production of steel today. Due to the physical, mechanical, and chemical components involved in the...     

Improvement of YBCO Superconductor Magnetic Shielding by Using Multiple Bulks

HTS bulks present a high critical current density which can be used as magnetic shields. Previous works showed that BSCCO bulks can screen magnetic fields up to 0.1 T. For large scale applications like electrical machines, stronger magnetic field is usually needed. In so doing, (RE)BCO materials are more suitable since they can shield much higher magnetic fields. Another key issue concerns the size of the bulks. Nowadays, it is possible to manufacture 150-mm diameter class cylindrical YBCO bulk. In order to get larger magnetic shielding areas, multiple bulk superconductors should be arrayed and stacked in layers. This paper presents experimental results on screening performances of layered YBCO pellets. These results are compared with 2D simulations. The experiments are carried out at 77 K under external magnetic fields of 150 mT. Different topologies are considered: single-layer configuration with 9 square pellets and double-layer configuration with respectively 9 and 4 square pellets. Experimental and simulation results show that a checkerboard of one layer configuration does not fully shield the external magnetic field. Improved shielding properties are obtained when the double-layer configuration is used.     

Application potential of coarse-grained diamond grinding wheels for precision grinding of optical materials

Fine-grained resin bonded diamond tools are often used for ultra-precision machining of brittle materials to achieve optical surfaces. A well-known drawback is the high tool wear. Therefore, grinding processes need to be developed exhibiting less wear and higher profitability. Consequently, the presented work focuses on conditioning a mono-layered, coarse-grained diamond grinding wheel with a spherical profile and an average grain size of 301 µm by combining a thermo-chemical and a mechanical-abrasive dressing technique. This processing leads to a run-out error of the grinding wheel in a low-micrometer range. Additionally, the thermo-chemical dressing leads to flattened grains, which supports the generation of hydrostatic pressure in the cutting zone and enables ductile-mode grinding of hard and brittle materials. After dressing, the application characteristics of coarse-grained diamond grinding wheels were examined by grinding optical glasses, fused silica and glass–ceramics in two different kinematics, plunge-cut surface grinding and cross grinding. For plunge-cut surface grinding, a critical depth of cut and surface roughness were determined and for cross-grinding experiments the subsurface damage was analyzed additionally. Finally, the identified parameters for ductile-machining with coarse-grained diamond grinding wheels were used for grinding a surface of 2000 mm² in glass–ceramics.