Alternative mechanisms for improvements in fluid ability performance among older adults.

To cross-validate and extend previous work regarding fluid ability training, I randomly assigned 256 community-living older participants to either induction training, stress inoculation training, or no-contact control groups. Practice effects were common to almost all of the ability measures, whereas training effects were specific to measures of inductive reasoning. Both training groups demonstrated greater immediate posttest gains in Letter Sets performance relative to control groups, which were maintained to the greatest extent one month later for the induction training group. The control and stress inoculation groups experienced slight declines one month later, although performance differences still favored the latter. For Letter Series, one week follow-up findings favored both induction and stress inoculation conditions, whereas only the stress inoculation group demonstrated gains at one month follow-up. No differential pattern of training transfer to other components of Gf–Gc was observed. These data suggest alternative means by which the facilitation of intellectual competence in older adults may be accomplished. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Dynamic mathematical model of the crystallization kinetics of fats

A new model able to describe the kinetics of isothermal crystallization is presented: it is a model written in the form of a differential equation allowing use under dynamic temperature variations. It describes the crystallization process as if it is a reversible reaction with a first order forward reaction and a reverse reaction of order n. The model has the advantage of having an analytical solution under isothermal conditions that facilitates parameter estimation. The quality of this model was compared with the more traditional Avrami (with and without induction time) and Gompertz models using different model selection criteria. To show the universality of the model, different fat samples, different crystallization temperatures and different measuring techniques were used for model evaluation. The new model was selected as the best for the majority of the samples and this independent of the model selection criterion used.     

Time trends of selected persistent organic pollutants in lake sediments from Greenland

Sediments from seven lakes in West Greenland were used as natural archives to study past and present levels of PCBs (polychlorinated biphenyls, tri- to decachlorinated), tetra-BDE #47 (2,2',4,4'-bromodiphenyl ether), chlordane (cis- and trans-octachlordane) and HxCBz (hexachlorobenzene). The concentrations found are lower than or comparable to concentrations found in sediments from other Arctic regions and one to 2 orders of magnitude lower than concentrations typically found in sediments at lower latitudes. The observed temporal trends (direct and indirect dating) show a decreasing total PCB concentration. Even though local contamination sources exist, the POP deposition in the studied area is most likely a result from long-range transport. The hypothesis about "cold condensation" suggests a latitudinal fractionation to occur between different volatile compounds during the transport toward the pole. In this study a time delay in the deposition for the low-chlorinated PCBs (tri- and tetrachlorinated), compared to their emission histories and compared to higher chlorinated PCBs, was indicated. Although very low tetra-BDE #47 concentrations are observed in this study, there are indications for an increasing concentration in recent sediment layers that may reflect increasing environmental concentrations at lower latitudes. The investigated pesticides are still in use at lower latitudes, however neither chlordane nor HxCBz show any distinct temporal trend of increasing or decreasing concentration toward the sediment surface.     

The dynamics of assessment center validity: Results of a 7-year study.

The authors investigated temporal trends in the validity of an assessment center consisting of a group discussion and an analysis–presentation exercise for predicting career advancement as measured by average salary growth over a 7-year period in a sample of 679 academic graduates. The validity of the overall assessment rating for persons with tenure of 7 years, corrected for initial differences in starting salaries and restriction in range, was .39. There was a considerable time variation in the validity of both the overall assessment rating and the assessment center dimensions. In accordance with findings from research in managerial effectiveness and development, the interpersonal effectiveness dimension became valid only after a number of years, whereas the firmness dimension was predictive in the whole period and increased with time. For comparison, validity trends for 2 types of interviews and a mental test were also studied. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Biomass production,water use and photosynthesis of Salix clones grown in a wastewater purification system

An objective of the study was to identify leaf morphophysiological characteristics indicative of high aboveground woody biomass production of Salix clones growing in the vegetation filter of a wastewater purification system. It was hypothesized, that in these extra irrigated stands, the characteristics of photosynthesis are stronger determinants of the production than the characteristics of leaf water relations. The biomass production of the clones was correlated with numerous characteristics of leaf water relations and photosynthesis. Significant correlation was found between the biomass production and the following characteristics of top foliage leaves: daily decrease in water potential, stomatal conductance, stomatal sensitivity to increase in light intensity, and hydraulic conductance (positive); daily minimum and maximum water potentials, instantaneous water use efficiency, and stomatal sensitivity to decrease in leaf water potential (negative); maximum rate of photosynthetic electron transport, chlorophyll content, and the partitioning coefficient for leaf nitrogen into bioenergetics associated with electron transport (positive). In the most productive clones, the vertical gradient (through foliage) of values of almost all the characteristics was the smallest. The biomass correlated more strongly with the characteristics of photosynthesis light stage than with the characteristics of water relations. We conclude that the characteristics of photosynthesis light stage – high maximum rate of photosynthetic electron transport, high chlorophyll content, and also flat vertical gradient (through foliage) in values of the characteristics could be the strongest indicators of high biomass production of Salix clones growing in vegetation filter.     

Intensification of enzymatic conversion of glucose to lactic acid by reactive extraction

Lactic acid is an important commercial product and extracting this out of aqueous solution is a growing requirement in fermentation-based industries and recovery from waste streams. The design of an amine extraction process requires (i) equilibrium and (ii) kinetic data for the acid-amine (solvent) system used. Equilibria and kinetics for lactic acid extraction by Alamine 336 in octanol as a diluent have been determined and compared with other diluents studied earlier. An approach for extracting the lactic acid by a long-chain tertiary amine, which is in the dispersed phase as a liquid ion exchanger (LIX), is presented. A mathematical model for slurry phase reactor with glucose in the continuous aqueous phase, the amine with a diluent in the dispersed phase and the immobilized enzyme as the solid catalyst, has been developed using equilibrium and kinetic data for reactive extraction. Effects of various parameters affecting the conversion of glucose have been discussed. The model has been solved for batch and semi-batch modes. It has been shown that the semi-batch mode yields approximately five times higher productivity than batch mode.     

Application of differential quadrature to static analysis of structural components

The numerical technique of differential quadrature for the solution of linear and non-linear partial differential equations, first introduced by Bellman and his associates, is applied to the equations governing the deflection and buckling behaviour of one- and two-dimensional structural components. Separate transformations are used for higher-order derivatives, as suggested by Mingle, thus extending the method to treat fourth-order equations and to include multiple, boundary conditions in the respective co-ordinate directions. Results are obtained for various boundary and loading conditions and are compared with existing exact and numerical solutions by other methods. The application of differential quadrature to this class of problems is seen to lead to accurate results with relatively small computational effort.     

On the relationship between travel time and travel distance of commuters

This paper gives a detailed empirical analysis of the relationships between different indicators of costs of commuting trips by car: difference as the crow flies, shortest travel time according to route planner, corresponding travel distance, and reported travel time. Reported travel times are usually rounded in multiples of five minutes. This calls for special statistical techniques. Ignoring the phenomenon of rounding leads to biased estimation results for shorter distances. Rather surprisingly, the distance as the crow flies and the network distance appear to be slightly better proxies of the reported travel time compared with the shortest network travel time as indicated by the route planner. We conclude that where actual driving times are missing in commuting research the other three indicators mentioned may be used as proxies, but that the following problems may emerge: actual travel times may be considerably higher than network times generated by route planners, and the average speed of trips increases considerably with distance, implying an overestimate of travel time for long distance commuters. The only personal feature that contributes significantly to variations in reported travel times is gender: women appear to drive at lower average speeds according to our data. As indicated in the paper this may be explained by the differences in the car types of male and female drivers (females drive older and smaller cars) as well as higher numbers of stops/trip chaining among women. A concise analysis is carried out for carpoolers. Car-pooling leads to an increase in travel time of some 17% compared with solo drivers covering the same distance. In the case of car poolers, the above mentioned measures appear to be very poor proxies for the actual commuting times. Received: November 1996/Accepted: January 1998     

A priori tests of large eddy simulation of the compressible plane mixing layer

Three important aspects for the assessment of the possibilities of Large Eddy Simulation (LES) of compressible flow are investigated. In particular the magnitude of all subgrid-terms, the role of the discretization errors and the correlation of the turbulent stress tensor with several subgrid-models are studied. The basis of the investigation is a Direct Numerical Simulation (DNS) of the two- and three-dimensional compressible mixing layer, using a finite volume method on a sufficiently fine grid. With respect to the first aspect, the exact filtered Navier-Stokes equations are derived and all terms are classified according to their order of magnitude. It is found that the pressure dilatation subgrid-term in the filtered energy equation, which is usually neglected in the modelling-practice, is as large as e.g. the pressure velocity subgrid-term, which in general is modelled. The second aspect yields the result that second- and fourth-order accurate spatial discretization methods give rise to discretization errors which are larger than the corresponding subgrid-terms, if the ratio between the filter width and the grid-spacing is close to one. Even if an exact representation for the subgrid-scale contributions is assumed, LES performed on a (considerably) coarser grid than required for a DNS, is accurate only if this ratio is sufficiently larger than one. Finally the well-known turbulent stress tensor is investigated in more detail. A priori tests of subgrid-models for this tensor yield poor correlations for Smagorinsky's model, which is purely dissipative, while the non-eddy viscosity models considered here correlate considerably better.