Crop and soil nitrogen responses to phosphorus and potassium fertilization and drip irrigation under processing tomato

Shortage of water or nutrient supplies can restrict the high nitrogen (N) demand of processing tomato, leaving high residual soil N resulting in negative environmental impacts. A 4-year field experiment, 2006?C2009, was conducted to study the effects of water management consisting of drip irrigation (DI) and non-irrigation (NI), fertilizer phosphorus (P) rates (0, 30, 60, and 90?kg P?ha^?1), and fertilizer potassium (K) rates (0, 200, 400, and 600?kg?K?ha^?1) on soil and plant N when a recommended N rate of 270?kg?N?ha^?1 was applied. Compared with the NI treatment, DI increased fruit N removal by 101?%, plant total N uptake by 26?%, and N harvest index by 55?%. Consequently, DI decreased apparent field N balance (fertiliser N input minus plant total N uptake) by 28?% and cumulative post-harvest soil N in the 0?C100?cm depth by 33?%. Post-harvest soil N concentration was not affected by water management in the 0?C20?cm depth, but was significantly higher in the NI treatment in the 20?C100?cm depth. Fertilizer P input had no effects on all variables except for decreasing N concentration in the stems and leaves. Fertilizer K rates significantly affected plant N utilization, with highest fruit N removal and plant total N uptake at the 200?kg?K?ha^?1 treatment; therefore, supplementing K had the potential to decrease gross N losses during tomato growing seasons. Based on the measured apparent field N balance and spatial distribution of soil N, gross N losses during the growing season were more severe than expected in a region that is highly susceptible to post-harvest soil N losses.     

Direct substitution of polyolefins

Reaction of solutions of ethylene-propylene copolymer with carbonium ion sources, such as isopropylbenzene, in the presence of acid catalysts leads to the introduction of the aromatic and hydroxylic moieties onto the copolymer backbone. Major gaseous products are isobutane and propane. Chain scission accompanies the reaction.     

Energetics and Structure of Polymer‐Derived Si–(B–)O–C Glasses: Effect of the Boron Content and Pyrolysis Temperature

The structure and properties of polymer‐derived Si–(B–)O–C glasses have been shown to be significantly influenced by the boron content and pyrolysis temperature. This work determined the impact of these two parameters on the thermodynamic stability of these glasses. High‐temperature oxide melt solution calorimetry was performed on a series of amorphous samples, with varying boron contents (0–7.7 at.%), obtained by pyrolysis of precursors made by a sol–gel technique. Thermodynamic analysis of the calorimetric results demonstrated that at a constant pyrolysis temperature, adding boron makes the materials energetically less stable. While the B‐containing glasses pyrolyzed at 1000°C were energetically less stable than the competitive crystalline components, increasing the pyrolysis temperature to 1200°C led to their enthalpic stability. ²⁹Si and ¹¹B MAS nuclear magnetic resonance (NMR) spectroscopy measurements on selected samples confirmed a decrease in the concentrations of mixed Si‐centered SO_iC_4?i and B‐centered BO_jC_3?j bonds at the expense of formation of SiO₄ and B(OSi)₃ species (indicating a tendency toward phase separation) when the boron content and pyrolysis temperature increased. In light of the findings from calorimetry and NMR spectroscopy, we propose a structure–energetic relationship in Si–(B–)O–C glasses.     

Policy analysis model of a large electrical supply system

A simulation model of the capacity-acquisition process in a large electricity-supply system is described, and its output is compared with the actual behavior of the system. The model was built to be used in the testing and assessment of alternative capacity-acquisition policies, particularly the demand-forecasting element of such policies. A simple experiment is described that indicates that the performance of the acquisition policy is sensitive to relatively small changes in the forecasting technique employed. The value of the model in corporate planning is considered briefly.     

Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 1. Pyrite and magnetite

Abiotic reductive dechlorination of chlorinated ethylenes (tetrachloroethylene (PCE), trichloroethylene (TCE), cis-dichloroethylene (cis-DCE), and vinyl chloride (VC)) by pyrite and magnetite was characterized in a batch reactor system. Dechlorination kinetics was adequately described by a modified Langmuir-Hinshelwood model that includes the effect of a decreasing reductive capacity of soil mineral. The kinetic rate constant for the reductive dechlorination of target organics at reactive sites of soil minerals was in the range of 0.185 (+/- 0.023) to 1.71 (+/- 0.06) day(-1). The calculated specific reductive capacity of soil minerals for target organics was in the range of 0.33 (+/- 0.02) to 2.26 (+/- 0.06) microM/g and sorption coefficient was in the range of 0.181 (+/- 0.006) to 0.7 (+/- 0.022) mM(-1). Surface area-normalized pseudo-first-order initial rate constants for target organics by pyrite were found to be 23.5 to 40.3 times greater than those by magnetite. Target organics were mainly transformed to acetylene and small amount of chlorinated intermediates, which suggests that beta-elimination was the main dechlorination pathway. The dechlorination of VC followed a hydrogenolysis pathway to produce ethylene and ethane. The addition of Fe(II) increased the dechlorination rate of cis-DCE and VC in magnetite suspension by nearly a factor of 10. The results obtained in this research provide basic knowledge to better predict the fate of chlorinated ethylenes and to understand the potential of abiotic processes in natural attenuation.     

Reversible acetonitrile-induced inactivation/activation of thermolysin

Thermolysin is catalytically inactive in mixtures of 10-15 % acetonitrile in aqueous buffer. Unexpectedly, dilution of the inactive enzyme with acetonitrile leads to complete recovery of the catalytic activity in a similar way to dilution with aqueous buffer. Circular dichroism and fluorescence studies of thermolysin in the same solvent mixtures reveal discontinuous changes in the overall secondary and tertiary protein structure that correlate well with the reversible differences in catalytic activity. The spectra on either side of the minimum activity point are different from each other, a fact indicating that the enzyme may be able to access two active conformations which are thermodynamically stable in different solvent environments.     

Writing power into online discussion

This article considers the way in which control of interaction emerges as a function of personal agency and external factors in a group of students engaged in online asynchronous text-based communication in a distance education program. It is structured around the argument that control is partly related to the power that individuals have to give effect to their wishes, but also acknowledges that this sense of agency is always in relation to the powers of others and more structural constraints. A picture emerges of the choices students make in deciding when to initiate discussion and respond to others, and about decisions concerning whose messages they would read and when. The impact of other students, of online groups, and instructors seems to play an important role in determining how participants participate in online interaction. Consideration of broader issues shows how the context in which students engage in interaction impacts the nature and extent of that interaction. The article concludes that being aware, and taking advantage of the socially grounded nature of online interaction provides the basis from which educators can act to ensure that interaction in online learning communities is enabling for the learning of all students.     

From application service provision to service-oriented computing: A study of the IT outsourcing evolution

IT outsourcing is not a new concept. Originating from the early 60’s in the form of time sharing, IT outsourcing has evolved to the application service provision (ASP) model, in the late 90’s to pure services in the beginning of the century. Services, and their major representative web services, are actually the next phase of the movement toward Internet-based componentized software, known in the not so distant past as ASP. As the continuous expansion of the Internet and its relating technologies creates new marketing opportunities, traditional monolithic architectures are giving way to service-oriented computing (SOC), the architecture that enables service provision. SOC permits the utilization of large systems which are comprised of self-containing building blocks: services. Services may be made public, searched, reused and combined to form complex business processes while in the same time retaining a significant level of flexibility. Services and SOC have emerged as a response to a fundamental shift in enterprise business culture that started at the late 90’s. Although they are promising as an IT outsourcing enabler, many issues need to be dealt with before they can be considered suitable for wide adoption. These issues are of technological, business, economic and cultural nature and they were also faced by ASPs in the past. It is worth revisiting the successes and failures of the ASP model in order to get a better understanding of the evolving IT outsourcing industry. In this work, we describe the evolution of service provision from its initial form as software application, through the application service provision era and towards the new trend of web services.     

An Integrated Approach to High Integrity Software Verification

Using automated reasoning techniques, we tackle the niche activity of proving that a program is free from run-time exceptions. Such a property is particularly valuable in high integrity software, for example, safety- or security-critical applications. The context for our work is the SPARK Approach for the development of high integrity software. The SPARK Approach provides a significant degree of automation in proving exception freedom. Where this automation fails, however, the programmer is burdened with the task of interactively constructing a proof and possibly also having to supply auxiliary program annotations. We minimize this burden by increasing the automation, through an integration of proof planning and a program analysis oracle. We advocate a ‘cooperative’ integration, where proof-failure analysis directly constrains the search for auxiliary program annotations. The approach has been successfully tested on industrial data.     

Acoustic Plasmons in Layered Systems and the Phonon-Plasmon Mechanism of Superconductivity

We address the question whether or not acoustic collective modes contribute to superconductivity in a layered electron gas. We calculate T _c within the strong-coupling phonon-plasmon scheme. The plasmon pairing kernel is calculated explicitly. We demonstrate that plasmons may contribute constructively to superconductivity. The result shows that one can interpret the effect of low-energy collective modes in terms of an effective negative *.