Some microwave applications of BaSrTiO3 and high temperature superconductors

Abstract

The group at the University of Colorado has been working on the applications of BaSrTiO₃ and high temperature superconductors to microwave circuits and systems with support from Superconducting Core Technologies, NASA and ONR. This work has included the development of a voltage tunable oscillator, a phase shifter, and a voltage tunable phased array antenna system. An important aspect of this program is the lattice match between the high temperature superconductor and the ferroelectric materials which enables us to grow thin films of either material on each other. By choosing the appropriate barium stronium ratio we are able to obtain changes in the dielectric constant of 5 to 1 in bulk capacitors at 77 K, the liquid nitrogen boiling temperature. Phase shifts of a little less than 126° at 10 Ghz have been obtained by applying 5 volts on a one centimeter coplanar line. The proposed phased array systems should enable us to point the beam radiated from the antenna in an arbitrary direction using two control voltages of less than 50 volts. We believe this approach leads to the possibility of inexpensive electronically scannable antenna systems which could be used for mobile communications with satellites and cellular systems.     

NUMERICAL SIMULATION OF THE THERMAL CONTROL OF HEAT EXCHANGERS

The temperature control of outlet air by changing the water flow rate in a single-pass waterto-air cross-flow heat exchanger is investigated. The conservation laws are applied to finite control volumes and an implicit formulation is used for transient numerical solutions. Conjugate forced convection heat transfer from the tube is solved to calculate the temperatures of the air and water coming out of the heat exchanger. In the simulations the outlet air temperature is controlled by changing the water flow rate entering the heat exchanger using a proportional-integral (PI) controller. The range of controllability of the heat exchanger was studied first. Then disturbances in the form of step changes in the inlet air temperature, the air flow rate, and the set point temperature were separately introduced. The effects of the limiting-condition constraints and different control parameters on controlling the outlet air temperature are presented. The results show that the control behavior can be simulated numerically and that this control methodology is effective within limits.     

Project affinity: the role of emotional attachment in construction projects

Although a wide range of human and organizational factors have been found to be important in the operation of projects, those determined by cultural variables are less well defined. One such influence concerns the notion of ‘project affinity’, the commitment and attachment by stakeholders and participants to projects and their outcomes. The temporal nature and transient involvement context provided by construction projects arguably presents a climate in which many participants are less likely to display commitment to its goals. This note is concerned with the issue of whether an attachment to a project's goals or to the completed product can lead to improved commitment among those involved. The concept of project affinity was developed in the course of a case study investigation in which operatives' attitudes towards the construction of a cancer research facility were explored. Because of the contribution of the facility to the future care of cancer sufferers, the concept of project affinity proved helpful in understanding a factor that appeared to be influencing the commitment of those involved. The results suggest a complementary concept to that of ‘project chemistry’ (c.f. Nicolini, 2002 Nicolini, D. 2002. In search of ‘project chemistry’.. Construction Management and Economics, 20: 167–77.  ).     

Australia's housing choices: Retrospect and prospect

This article identifies issues around the Auckland Region's strategy for urban intensification and discusses the ensuing policy implications. Medium density housing forms an important element of the strategy for growth management. Implications for its success are primarily drawn from research into a major housing development in Waitakere City. It is argued that for ideological, political and technical reasons the strategy could be easily undermined. The article also suggests that something of a paradigm shift is underway in urban planning.     

Structural frame selection: case studies of hybrid concrete frames

Hybrid concrete construction (HCC) uses a combination of in-situ and precast concrete and is an example of ‘mixed’ construction, which is the term for an innovative combination of different materials or framing methods. Examples of HCC exist in many countries to fulfil varying structural requirements, so it is not clear why HCC is not better used in the UK. Research was undertaken to gain a better understanding of the selection and use of HCC. Two case study projects were investigated to explore decision-making criteria, the roles of project participants and the challenges particular to HCC. The findings suggest that HCC is selected when measurable cost or programme advantages are not the most important criteria, but where other factors such as satisfying architectural requirements (finish, colour, etc.) or operational demands (such as internal comfort or maintenance) are critical. In both cases, clients and architects were found to be the most influential team members in the frame-selection process.

La construction en béton hybride (HCC) utilise une combinaison de béton in situ et de béton précoulé; c'est un exemple de ‘construction mixte’; cette expression définit une combinaison innovante de différents matériaux et méthodes de coffrage. Il existe des exemples de HCC dans de nombreux pays qui répondent à différentes exigences structurales; on peut donc difficilement expliquer pourquoi la HCC n'est pas mieux utilisée au Royaume-Uni. Des recherches ont été entreprises pour mieux comprendre les choix et les usages de la HCC. Deux études de cas ont été engagées, l'objectif étant d'explorer les critères décisionnels, le rôle des participants à ces projets et les défis particuliers propres à la HCC. Les résultats laissent à penser que la HCC est retenue lorsque le coût mesurable ou les avantages du programme ne sont pas les critères les plus importants et lorsque d'autres facteurs comme la réponse aux exigences architecturales (finition, couleur, etc.) ou d'autres exigences opérationnelles (comme le confort intérieur ou la maintenance) sont critiques. Dans les deux cas, les clients et les architectes sont apparus comme les membres les plus influents des équipes lors du processus de sélection du cadre.

Mots clés: processus de conception, construction en béton hybride, construction mixte, critères de performances, cadre structural     

The building performance sketch

A new approach to the creation of design tools is proposed that addresses the real information needs of designers in the early stages of design of non-residential buildings. Traditional simplified design tools are typically too limited to be of much use, even in conceptual design. The proposal is to provide access to the power of detailed simulation tools at a stage in design when little is known about the final building, but at a stage also when the freedom to explore options is greatest and the ability to improve the design is greatest. The concept of the building performance sketch forms the basis of the proposed design tool. It was derived from consultation with design analysis teams as part of the development of the COMFEN tool for fenestration design. Tools like COMFEN are explored to understand how they were shaped by consultation and how requests from these teams for real-world relevance might shape such tools in the future. The simulation process can effectively utilize some of the as-built, as-occupied and as-managed lessons on behaviours and technical outcomes from the Post-occupancy Evaluation (PoE) of buildings.

Il est proposé pour la création des outils de conception une nouvelle approche répondant aux véritables besoins d'information des concepteurs dans les premières phases de conception des bâtiments non résidentiels. Les outils de conception simplifiée traditionnels sont habituellement trop limités pour être très utiles, même en design conceptuel. Ce qui est proposé est de pouvoir accéder à la puissance d'outils de simulation détaillée à un stade de la conception où l'on sait encore peu de choses concernant le bâtiment final, mais également à un stade auquel la liberté d'exploration des options possibles comme la capacité d'amélioration de la conception sont les plus grandes. Le concept du schéma de performance du bâtiment constitue la base de l'outil de conception proposé. Il découle de la consultation des équipes chargées de l'analyse de la conception dans le cadre du développement de l'outil COMFEN de conception du fenêtrage. Des outils tels que COMFEN sont examinés afin de comprendre comment ils ont été modelés par la consultation et comment les demandes de ces équipes en termes de pertinence réelle pourraient façonner ces outils à l'avenir. Le processus de simulation peut tirer efficacement parti de certaines des leçons, conformes à l'exécution, à l'occupation et à la gestion, en matière de comportements et de résultats techniques, retirées de l'Evaluation Après Occupation des bâtiments.

modèles d'information du bâtiment?bâtiments?processus de conception?outils de conception?début de conception?efficacité énergétique?retour d'information?simulation des performances?évaluation après occupation     

Thermal Expansion of Alkaline‐Doped Lanthanum Ferrite Near the Néel Temperature

The thermal expansion and magnetic behaviors of divalent, alkaline‐doped lanthanum ferrites (La_0.9M_0.1FeO₃, M=Ca, Sr, Ba) were assessed using a combination of dilatometry, magnetometry, time‐of‐flight neutron diffraction, and high‐temperature X‐ray diffraction. Néel temperatures were determined through vibrating sample magnetometry and correlated well with changes in thermal expansion behavior observed during both dilatometry and X‐ray diffraction. The Néel temperatures observed for pure, Ca‐doped, Sr‐doped, and Ba‐doped lanthanum ferrites were 471°C, 351°C, 465°C, and 466°C, respectively. The effect of divalent substitutions on the magnetic behavior are attributed to charge compensation mechanisms and structural changes in the material.     

Energetics and Structure of Polymer‐Derived Si–(B–)O–C Glasses: Effect of the Boron Content and Pyrolysis Temperature

The structure and properties of polymer‐derived Si–(B–)O–C glasses have been shown to be significantly influenced by the boron content and pyrolysis temperature. This work determined the impact of these two parameters on the thermodynamic stability of these glasses. High‐temperature oxide melt solution calorimetry was performed on a series of amorphous samples, with varying boron contents (0–7.7 at.%), obtained by pyrolysis of precursors made by a sol–gel technique. Thermodynamic analysis of the calorimetric results demonstrated that at a constant pyrolysis temperature, adding boron makes the materials energetically less stable. While the B‐containing glasses pyrolyzed at 1000°C were energetically less stable than the competitive crystalline components, increasing the pyrolysis temperature to 1200°C led to their enthalpic stability. ²⁹Si and ¹¹B MAS nuclear magnetic resonance (NMR) spectroscopy measurements on selected samples confirmed a decrease in the concentrations of mixed Si‐centered SO_iC_4?i and B‐centered BO_jC_3?j bonds at the expense of formation of SiO₄ and B(OSi)₃ species (indicating a tendency toward phase separation) when the boron content and pyrolysis temperature increased. In light of the findings from calorimetry and NMR spectroscopy, we propose a structure–energetic relationship in Si–(B–)O–C glasses.     

Blends of natural rubber and polyurethane latices studied by 1H wideline and 13C MAS solid‐state NMR

¹H wideline and ¹³C magic‐angle spinning NMR have been used to study the morphology and dynamics of latex‐cast and solution‐cast film blends of natural rubber (NR) and a polyurethane (PU) based on poly(?‐caprolactone) diol and isophorone di‐isocyanate. ¹H T₁ and T_1ρ relaxation times have been measured, and the extent of interpenetration of the NR and PU constituents has been monitored using the Goldman–Shen technique. The NMR spectra and relaxation properties indicated that the NR and PI constituents largely occupy separated domains on a distance scale of >10 nm. The Goldman–Shen experiments indicated that there was slightly greater contact between NR and PU in the solution‐cast samples than in the latex‐cast. The tensile properties of the films have been measured. The tensile strength and initial Young's modulus pass through a maximum at a PU content of about 50 wt%. © 2002 Society of Chemical Industry     

Anodic reactions of Ni3S2, β-NiS and nickel matte

The anodic reactions of Ni₃S₂,-NiS and a commercial nickel matte have been investigated galvanostatically. It is shown that the matte as well as both compounds decompose with loss of nickel ions through the series of phases: Ni_1.5S₂ Ni_1.2S₂ NiS₂ Ni²⁺ + 2S⁰