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101.
Username/Password is still the prevailing authentication mechanism for internet based services — but it is not secure! We show how new authentication and identification mechanisms focused on usability and security can change this.  相似文献   
102.
The free‐radical graft polymerization of vinyl acetate onto nonporous silica particles was studied experimentally. The grafting procedure consisted of surface activation with vinyltrimethoxysilane, followed by free‐radical graft polymerization of vinyl acetate in ethyl acetate with 2,2′‐azobis(2,4‐dimethylpentanenitrile) initiator. Initial monomer concentration was varied from 10 to 40% by volume and the reaction was spanned from 50 to 70°C. The resulting grafted polymer, which was stable over a wide range of pH levels, consisted of polymer chains that are terminally and covalently bonded to the silica substrate. The experimental polymerization rate order, with respect to monomer concentration, ranged from 1.61 to 2.00, consistent with the kinetic order for the high polymerization regime. The corresponding rate order for polymer grafting varied from 1.24 to 1.43. The polymer graft yield increased with both initial monomer concentration and reaction temperature, and the polymer‐grafted surface became more hydrophobic with increasing polymer graft yield. The present study suggests that a denser grafted polymer phase of shorter chains was created upon increasing temperature. On the other hand, both polymer chain length and polymer graft density increased with initial monomer concentration. Atomic force microscopy–determined topology of the polymer‐grafted surface revealed a distribution of surface clusters and surface elevations consistent with the expected broad molecular‐weight distribution for free‐radical polymerization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 300–310, 2003  相似文献   
103.
Summary: Segmented block copolymers, consisting of non‐polar soft segments from hydroxyl‐terminated liquid natural rubber (HTNR) and polar hard segments from α,ω‐diisocyanato telechelics obtained by “criss‐cross”‐cycloaddition, have been synthesized. The block copolymer formation took place under relatively mild reaction conditions at 80 °C in dichloroethane in the presence of dibutyltin dilaurate as a catalyst. The resulting block copolymers were characterized by spectroscopic techniques (1H NMR, FTIR, UV‐vis spectroscopy) as well as GPC for molar mass determination. The block copolymers were compression molded in a hot stage press, and the resulting samples were characterized by DSC and stress‐strain measurement. The solubility and phase morphology of the materials have also been studied.

Segmented block copolymer from HTNR and α,ω‐diisocyanato telechelics  相似文献   

104.

Background  

Parents of six children are facing a trial on charges of aggravated manslaughter in the care a 5 1/2 month old infant who died suddenly and neglect of their four older children for causing them to be malnourished by feeding them all an exclusively raw foods vegan diet. Both parents declined plea bargains and plan to defend themselves in court.  相似文献   
105.
This paper presents a three node curved three dimensional beam element for linear static analysis where the element displacement approximation in the axial () and transverse directions ( and ) can be of arbitrary polynomial orders p , p and p . This is accomplished by, first constructing one dimensional hierarchical approximation functions and the corresponding nodal variable operators in , and directions using Lagrange interpolating polynomials and then taking the products (also called tensor product) of these hierarchical one dimensional approximation functions and the corresponding nodal variable operators. The resulting approximation functions and the corresponding nodal variables for the three dimensional beam element were hierarchical. The formulation guarantees C 0 continuity. The element properties are established using the principle of virtual work. In formulating the properties of the element all six components of the stress and strain tensor are ratained. The geometry of the beam element is defined by the coordinates of the nodes located at the axis of the beam and node point vectors representing the nodal cross-sections. The results obtained from the present formulation are compared with analytical solutions (when available) and the h-models using isoparametric three dimensional solid elements. The formulation is equally effective for very slender as well as deep beams since no assumptions are made regarding such conditions during the formulation.  相似文献   
106.
International Journal of Control, Automation and Systems - In this paper, we consider the fuzzy moving sliding surface anti-sway control problem for container cranes. We first introduce the dynamic...  相似文献   
107.

The satellite-based regression model provides the data model that identifies water quality for inland and coastal waters. However, the satellite regression usually depends on the selection of observation, satellite data, and model type. A resampling simulation technique, such as sequential simulation using geographically weighted regression (GWR simulation), can be applied in generating multiple realizations for water quality estimation to reduce the sampling effect and consider spatial heterogeneity. Traditional models often result in considerable underestimation in extreme observations. The GWR simulation provides the best goodness of fit and spatial varying relationship between observed water quality and remote sensing considering parameter outlier and noise removal for parameter stability. This simulation model can increase the sampling diversity from various observations and reduce the neighboring effects of observations using outlier and noise removal. The model that handles spatial uncertainty and heterogeneity is a novel tool for inferring the characteristics of water quality from a series of sample subsets.

  相似文献   
108.
目的解决传统平面环抛过程中存在的两种问题:(1)抛光液受抛光盘和工件旋转离心力作用而抛光液在加工区域分布不均,导致加工工件高平面度差;(2)抛光液受到的离心力作用限制了抛光盘转速,导致抛光效率低。方法提出一种基于介电泳效应的平面抛光方法(DEPP),在抛光区域增加一个非均匀电场,利用中性粒子在非均匀电场中极化后受介电泳力的作用,使其具有向电极和抛光区域中心运动的现象,降低旋转离心力对抛光液的甩出作用,实现对平面工件的高速、高精度抛光。采用有限元分析软件数值模拟极化后磨粒所受介电泳力对离心力的抑制作用,优化产生非均匀电场的不同电极宽度,得到最优非均匀电场电极分布参数,实际测量优化电极后抛光液所受介电泳力的大小和方向,最后搭建试验平台验证介电泳效应高速抛光平面工件的有效性。结果提高抛光盘转速,进行抛光磨砂玻璃对比实验,加工1 h以后,采用介电泳效应抛光能完全去除玻璃磨砂层,工件平整度好,最终RMS值为0.276λ;无介电泳效应抛光后,工件中心部分磨砂层仍有存在,工件平整度相对较差,最终RMS值为0.694λ。通过测量加工去除量,介电泳效应抛光比无介电泳效应抛光的去除率提升了18%结论通过仿真模拟和实验验证,证明了调整电极布置形式以及优化电极分布参数后,介电泳效应高速平面抛光的方法能够有效提升抛光效率和抛光后工件表面平面度。  相似文献   
109.
Microsystem Technologies - This paper reports a design and fabrication process of a micro cam system (MCS) with a flat-faced translating follower. The cam rim with cover diameter of 2.4 mm...  相似文献   
110.
This paper presents a three-electrode capacitive fluidic sensor for detecting an air bubble inside a fluidic channel such as blood vessels, oil or medical liquid channels. The capacitor is designed and fabricated based on a printed circuit board (PCB). The electrodes are fabricated by using copper via structure through top to bottom surface of the PCB. A plastic pipe is layout through the capacitive sensor and perpendicular to the PCB surface. Capacitance of sensor changes when an air bubble inside fluidic flow cross the sensor. The capacitance change can be monitored by using a differential capacitive amplifier, a lock-in amplifier, filter and an NI acquisition card. Signal is processed and calculated on a computer. Air bubble inside the liquid flow are detected by monitor the unbalance signal between the three electrode potential voltages. Output voltage depends on the volume of the air bubble due to dielectric change between capacitor’s electrodes. Output voltage is up to 53 mV when an 2.28 mm3 air bubble crosses the sensing channel. Air bubble velocity can be estimated based on the output pulse signal. This proposed fluidic sensor can be used for void fraction detection in medical devices and systems; fluidic characterization; and water–gas, oil–water and oil–water–gas multiphase flows in petroleum technology. That structure also can apply to the micro-size for detecting in microfluidic to monitor and control changes in microfluidic channels.  相似文献   
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