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101.
Measurements of relaxation times, T1 and T2, and self-diffusion coefficients, D, for small molecules, viz., H2O, dioxane and t-butanol, in the gel system cellulose/H2O are reported and compared with those for H2O in a polyacrylamide gel of the same polymer content. The temperature dependence of T1 and D can for all the penetrants be represented by Arrhenius type relations which merely are parallel shifts by the same amount, towards smaller values, of those obtained without polymer. The T2 values for H2O in both gels pass through a shallow minimum over the considered temperature interval (14°?44°C). Furthermore, relaxation times T1 of D2O in the gel system cellulose/D2O are reported; in a plot of ln T1 vs. 1/T, a plateau region is observed at higher temperatures. 相似文献
102.
Using a novel sorption technique, the diffusion of some series of solutes in polyacrylamide gels has been investigated with regard to: (a) molecular size of solute; (b) concentration of solute and gel polymer; and (c) temperature. The approach used also yields the partition coefficient pertaining to sorption equilibrium. The ratio, , where Do refers to diffusion in the pure solvent, is found to reflect in part the characteristic interactions between solute and gel polymer. The temperature results indicate that the apparent activation energy for solute diffusion is approximately independent of the polymeric component for dilute gels. 相似文献
103.
Various metal halides have been dispersed in high and low molecular weight, amorphous poly(propylene oxide), by solution blending techniques, to give single phase polymeric complexes which remained thermoplastic even at very high salt loadings. These complexes were amorphous and showed a single well-defined glass transition temperature (Tg) by differential thermal analysis with the Tg of the complex up to 140°C greater than the Tg of the parent polymer. The Tg elevation depended upon both the amount and the type of salt added and for a given salt the elevation followed a sigmoidal curve which levelled out at high salt concentrations. The Tg data have been interpreted in terms of a chelate ring model involving the co-ordination of two adjacent ether oxygen atoms in the polymer backbone to the salt. Using this model it was possible to consider the complex as a random copolymer consisting of complexed and uncomplexed monomer units. The contribution of crosslinking by metal salts to the elevation of Tg was assessed by studying poly(tetramethylene glycol)-zinc chloride complexes in which chelate formation is entropically unfavourable. Mechanical data are reported for ZnCl2 complexes with high molecular weight poly(propylene oxide). The results indicate that ZnCl2 increased the rubbery modulus and this has been interpreted in terms of ZnCl2 forming a few, weak intermolecular crosslinks. 相似文献
104.
C. J. Brown D. Pletcher F. C. Walsh J. K. Hammond D. Robinson 《Journal of Applied Electrochemistry》1993,23(1):38-43
Measurements of the mass transport limited current for the reduction of ferricyanide in 1M m potassium hydroxide and of copper(II) in 1.5 m sulphuric acid as a function of electrolyte flow rate are used to characterize the space-averaged mass transport properties of the FM01 laboratory electrolyser, with and without six types of polymer mesh turbulence promoters. In the absence of a promoter, the results followed the equation
For the cell with the preferred turbulence promoter, the corresponding equation is
Pressure drop data are also reported and it is confirmed that the presence of a turbulence promoter need not lead to a significant increase in the pressure drop over the reactor. 相似文献
105.
A new type of ion implantation technique is used to create a non-equilibrium Pt-Sn(IMP) near-surface alloy with ca. 8.6 at%
Sn. The surface composition was determined by low-energy ion-scattering (LEIS). The kinetics of the electrooxidation of CO
and 2% CO/H2 mixtures on Pt-Sn(IMP) is essentially identical to that of Pt3Sn(110). The fact that any non-equilibrium composition can be easily prepared by this implantation method opens an interesting
practical opportunity to create a new Pt-Sn alloy fuel cell catalyst having an otherwise unobtainable surface composition
of Sn. This method also appears to have general utility in alloy catalysis as a means of exploring compositions in thermodynamically
unfavorable regions of the bulk phase diagram.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
106.
P. H. Eaves H. P. Dupuy L. L. Holzenthal E. T. Rayner L. E. Brown 《Journal of the American Oil Chemists' Society》1968,45(4):293-295
Two simple but effective pilot-plant processes were developed to produce Halphen-negative cottonseed oil. Both involve treatment
of the oil with cottonseed fatty acids in a conventional batch type of deodorizer in conjunction with deodorization. In one
process, in which the acids were added to the oil, the cyclopropenoids were inactivated in as short a time as 5 min after
the oil reached the maximum temperature of 450–455 F. In the other, in which the acids were generated in situ, the oil did
not become Halphennegative until about an hour and 45 min after it reached maximum temperature. The excess acids produced
by both methods were readily removed during conventional deodorization. In contrast, deodorization alone reduced the cyclopropenoid
content of the oil to a low level (0.02%) but did not render it Halphen-negative even after 3 hr at maximum temperature.
These new processes are directly applicable for use by refineries that have the batch type of deodorizers. For refineries
that operate continuous or semicontinuous deodorizers, it should be relatively simple to design preheating vessels or heat
exchangers to inactivate partially or completely the cyclopropenoids before deodorization.
Presented at the AOCS Meeting, New Orleans, May 1967.
So. Utiliz. Res. Dev. Div., ARS, USDA. 相似文献
107.
A review of analytical modeling of particulate reinforcement is made as a prelude to the problem of microstructural inhomogeneity in nanocomposite materials. Noting the inevitability of dispersion nonuniformity, and variations in agglomerate morphology and filler‐matrix interaction, the need to question the application of such models to novel materials arises. Employing the mechanical properties of alumina/epoxy nanocomposites, with known dispersion characteristics, an evaluation of the predictive capability of various models for Young's modulus, strength, and failure strain is made. Comparison between models is accompanied by a discussion of the parameters used in the fitting of macroscopic behavior to microstructural features. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 869–879, 2005 相似文献
108.
T. J. WEiss Mona Brown H. J. Zeringue Jr. R. O. Feuge 《Journal of the American Oil Chemists' Society》1971,48(4):145-148
Thin layer chromatography was adapted for direct quantitative estimation of sucrose esters of palmitic acid. Urea-phosphoric
acid spray was used to detect the sucrose moiety of the various esters. The photometrically metermined density density of
each spot on the thin layer plate was found to be proportional to its sucrose content. Ester content was then obtained by
multiplying sucrose found by the factor, mol. wt. ester/mol. wt. sucrose. Ester mixtures were prepared by interesterifying
sucrose with various proportions of methyl palmitate in dimethylformamide solution. Positional isomers were observed at each
level of substitution but could not be adequately separated from each other for quantitative evaluation.
Presented at the AOCS Meeting, Minneapolis, October 1969.
So. Utiliz. Res. Dev. Div., ARS, USDA. 相似文献
109.
A series of low molecular weight (≈40000) copolymers of methylmethacrylate (MMA) and 4-(methacryloyloxy)butylpentamethyldisiloxane (MBPD) have been synthesized by free radical polymerization in dimethylformamide solution. The microstructure, as derived from 13C NMR spectra, indicates that the copolymers are about 80% syndiotactic with an overall random distribution of mers. At room temperature, copolymers rich in MMA are clear, rigid glasses but become liquid at high MBPD content. Blends of these copolymers with PMMA are all heterogeneous with visible phase separation over most of the composition range. Differential scanning calorimetry studies show the presence of two Tg's when the relative concentration of PMMA to copolymer is high. Blends of two co-polymers of similar siloxane content produce clear films with no indication of phase separation. The permeability to oxygen at 25°C increases from 0.20 for pure PMMA to 3.0 (fmol/m·s·Pa.) for a copolymer of MMA/MBPD of the mole ratio of 3:1. Evaluation of the permeation behaviors of the blends suggests that blends rich in siloxane exist as a layered structure with the PMMA rich component dominating the observed permeability. 相似文献
110.
子午线轮胎出现不久,就采用钢丝带束层代替了纤维带束层,这对于实现子午线轮胎提高使用寿命和改善操纵性能的潜能是必要的。 相似文献