The effects of silicon on the properties of tantalum

The microalloying of tantalum with silicon has been effectively used on a commercial scale. However, data on effects of microalloying on processibility, microstructure and mechanical properties are not readily available. To develop some data, tantalum powder with various levels of silicon (0–50 ppm) was processed under identical conditions. Sheet samples were then annealed at different temperatures and evaluated via microstructural, chemical and mechanical tests. The recrystallization temperature was found to increase with silicon content, most probably as a result of the presence of an intermetallic (Ta₃Si) phase. The mechanical properties of unrecrystallized tantalum are, as expected, significantly different from those of recrystallized tantalum.     

Scheduling evacuation operations

In this paper, we consider a large-scale evacuation problem after a major disaster. The evacuation is assumed to occur by means of a fleet of buses, thus leading to scheduling the evacuation operations by buses [(bus evacuation problem (BEP)]. We propose time-indexed formulations as well as heuristic algorithms such as greedy algorithms and a matheuristic. This matheuristic uses the former formulation to improve the best solution obtained by the greedy heuristics. In computational experiments, we analyze and evaluate the efficiency of the proposed solution algorithms.     

Composite web QoS with workflow conditional pathways using bounded sets

In our previous work (Dillon and Mansour 2009), a stochastic reliability model of atomic web services was proposed. Using the well-known classic two-state bounded set technique, we developed a service-oriented model that dynamically calculates the reliability of composite web services with rollback recovery (Mansour and Dillon in IEEE Trans Serv Comput 4(4), 2011). In order to improve the Quality of Service, fault tolerance techniques have been introduced using recovery block adaptation. Our workflow was based on series-parallel structures that constitute parts of existing structures. It is worth mentioning that major service-oriented systems contain larger and more complex structures than the simple series and parallel ones. This is a limitation in our previous approach. In order to consider more realistic service-oriented systems, other main structures, such as AND, XOR and Loop, should be included into our model. In this article, our previous structures are generalized to include AND, XOR and Loops. In addition to generalized structures, we extended the existing two-state bounded set technique to include three-state systems. This extension was especially motivated by XOR-based structures. A comparative study between bounded set techniques and a new stochastic model is also presented. Our simulation results accurately reflect the performance of the new proposed model and confirm our theoretical studies. Furthermore, Monte Carlos simulations were performed and the results obtained clearly validate our stochastic model.     

Accessible e-learning material: a no-frills avenue for didactical experts

Different organizations adopt accessibility for various and diverse reasons. Interesting and inspiring as such reasons may be, it is important to ensure that the motivation for supporting accessibility is that it is the right thing to do, i.e. a commitment to the provision of equal opportunities for accessing resources for people with special needs. Among the various efforts for supporting the development of accessible e-learning material, most of them propose guidelines that prevalently address technical accessibility issues (such as the format and navigation of learning material) with little or no consideration for the didactical experts, and thus their didactical experience, in developing learning material. Moreover, the aforementioned guidelines tend to provide generic indications on alternative forms of didactical content for equivalent access to it. None the less, the sole provision of equivalent forms does not guarantee the retention of desirable user interface aspects and may therefore have a negative impact on learning effectiveness. While this paper acknowledges the role of such guidelines, it does propose that the didactical experts be provided with a non-technical recourse, improving their development of accessible e-learning content. By tapping into the experience of the didactical experts, this work provides them with an avenue leading to enhance the accessibility of e-learning material.     

On analyzing the intra-frame power saving potentials of the IEEE 802.16e downlink vertical mapping

Worldwide Interoperability for Microwave Access (WiMAX) is generally considered as a competitive candidate networking technology for the realization of the 4G vision. Among the key factors towards its successful and widespread deployment are the effective support of mobility and the provision of mechanisms for enabling service access at a high quality level in an efficient and cost-effective manner. Nonetheless, this effort should take into account and adequately address strict and severe energy limitations that the mobile devices are currently facing. Power saving constitutes an issue of vital importance, as mobile terminals continue to incorporate more and more functionalities and energy-hungry features in order to support the ever increasing user requirements and demands. The standard employs variations of power saving classes in a frame-to-frame basis, while recent power saving mechanisms proposed in related research literature limit their activity in whole frames, neglecting, thus, the intra-frame power saving capabilities. In this work, the intra-frame energy conservation potentials of the mobile WiMAX network are studied and a novel analytical approach is provided, focusing on the downlink direction where the bandwidth allocation involves idle intervals and dynamic inactivity periods. Specifically, we endeavour to accurately analyse the potential energy conservation capabilities in an intra-frame point of view, applying the well-known simple packing algorithm to distribute the available bandwidth to the various subscribers. Our analytical findings are thoroughly cross-validated via simulation, providing clear insights into the intra-frame energy reduction capabilities.     

Working towards sustainable urban water management: the vulnerability blind spot

The unprecedented water scarcity in Australia coincides with the adoption of a new urban water rhetoric. The 'Security through Diversity' strategy has been adopted in a number of Australian cities as a new and innovative approach to urban water management. Although this strategy offers a more holistic approach to urban water management, in practice, the Security through Diversity strategy is largely being interpreted and implemented in a way that maintains the historical dependence on large scale, centralised water infrastructure and therefore perpetuates existing urban water vulnerabilities. This research explores the implementation of Security through Diversity as the new water scarcity response strategy in the cities of Perth and Melbourne. Through a qualitative study with over sixty-five urban water practitioners, the results reveal that the practitioners have absorbed the new Security through Diversity language whilst maintaining the existing problem and solution framework for urban water management. This can be explained in terms of an entrenched technological path dependency and cognitive lock-in that is preventing practitioners from more comprehensively engaging with the complexities of the Security through Diversity strategy, which is ultimately perpetuating the existing vulnerability of our cities. This paper suggests that greater engagement with the underlying purpose of the security though diversity strategy is a necessary first step to overcome the constraints of the traditional technological paradigm and more effectively reduce the continued vulnerability of Australian cities.     

The fate of 14C-radiolabelled diclofenac and 4'-hydroxydiclofenac in membrane bioreactor treatment of wastewater

This study aimed at enhancing knowledge on the fate of diclofenac (DF), together with its main human metabolite 4'-hydroxydiclofenac (4'OHDF), during wastewater treatment by using a laboratory-scale membrane bioreactor (MBR). The reactor was fed continuously with non-radiolabelled diclofenac for a one month period prior to a single pulse of a 14C-radiolabelled solution of DF and 4'OHDF. The solution spike contained approximately 25% 4'OHDF and 65% DF, which corresponds to the ratio observed in municipal sewage, as well as traces of two other metabolites. The radioactivity was monitored for a total of twelve days in the various output streams. The calculation of the complete mass balance in the system demonstrated that the major part of the radioactivity left the reactor with the permeate (88.7%), while 2.1% was recovered in the excess sludge. Negligible amounts were recovered in the off-gas traps and on the membranes. Chromatographic analyses of effluent samples, by means of HPLC-MS coupled in parallel to a radiodetector, displayed a different pattern than the one of the spiked solution. It showed the occurrence of three additional metabolites.     

Sensitivity analysis for the SimpleTreat model to simulate fate of chemicals in sewage treatment plants

SimpleTreat 3.1 predicts the distribution and elimination of chemicals by sewage treatment. The model is used as the default calculation in EUSES 2.0 to estimate exposure concentration in the receiving water, soil and air. A sensitivity analysis was performed to rank input parameters according to their influence on model predictions. Triclosan was selected for the base case. The sewage flow, degradation rates and parameters describing the raw sewage were shown to be the most sensitive inputs. The pH and dissociation constant are very sensitive parameters when working with ionisable compounds. Variation in certain input parameters was propagated through the model to yield greater variation in output parameters with a maximum ratio of 4.0. SimpleTreat 3.1 is a steady state model describing a highly non-steady system. A large variability in the most sensitive parameters is expected within a single sewage plant and parameters should therefore be selected to cover this variability.     

Sex-related differences in foot shape

The purpose of the study was to investigate sex-related differences in foot morphology. In total, 847 subjects were scanned using a 3-D-footscanner. Three different analysis methods were used: (1) comparisons were made for absolute foot measures within 250-270 mm foot length (FL); (2) and for averaged measures (% FL) across all sizes; (3) the feet were then classified using a cluster analysis. Within 250-270 mm FL, male feet were wider and higher (mean differences (MD) 1.3-5.9 mm). No relevant sex-related differences could be found in the comparison of averaged measures (MD 0.3-0.6% FL). Foot types were categorised into voluminous, flat-pointed and slender. Shorter feet were more often voluminous, longer feet were more likely to be narrow and flat. However, the definition of 'short' and 'long' was sex-related; thus, allometry of foot measures was different. For shoe design, measures should be derived for each size and sex separately. Different foot types should be considered to account for the variety in foot shape. Improper footwear can cause foot pain and deformity. Therefore, knowledge of sex-related differences in foot measures is important to assist proper shoe fit in both men and women. The present study supplements the field of knowledge within this context with recommendations for the manufacturing of shoes.