CHARAC TERIZATION OF TiAl POWDER PRODUCED BY MECHANICAL ALLOYING

The microstructure,alloying reaction and sintering behavior of the powder produced by Mechanical Al-loying(MA)for 8 h from 64 wt.-% Ti powder and 36 wt.-% Al powder were studied by scanning electronmicroscopy,optical microscopy,X-ray diffractometry,differential scanning calorimetry(DSC)and dilatometry.The mechanically alloyed powder partictes are Ti-Al composite particles.Thus,titanium aluminides can formeasily in the powder through diffusion during heat treatment.It is shown that the sintering behavior of this pow-der,different from the behaviors of TiAl alloy powder and mixed powder of 64 wt.-% Ti powder and 36 wt.-%Al powder,changes from expansion at temperatures below 1000℃ to shrinkage at temperatures above 1000℃.Homogeneously alloyed TiAl material with a density over 96% of the theoretical density can be produced fromthe mechanically alloyed powder by compaction-sintering.     

Mold-filling characteristics of AZ91 magnesium alloy in the low-pressure expendable pattern casting process

The magnesium (Mg) alloy low-pressure expendable pattern casting (EPC) process is a newly developed casting technique combining the advantages of both EPC and low-pressure casting. In this article, metal filling and the effect of the flow quantity of inert gas on the filling rate in the low-pressure EPC process are investigated. The results showed that the molten Mg alloy filled the mold cavity with a convex front laminar flow and the metal-filling rate increased significantly with increasing flow quantity when flow quantity was below a critical value. However, once the flow quantity exceeded a critical value, the filling rate increased slightly. The influence of the flow quantity of inert gas on melt-filling rate reveals that the mold fill is controlled by flow quantity for a lower filling rate, and, subsequently, controlled by the evaporation of polystyrene and the evaporation products for higher metal velocity. Meanwhile, the experimental results showed that the melt-filling rate significantly affected the flow profile, and the filling procedure for the Mg alloy in the low-pressure EPC process. A slower melt-filling rate could lead to misrun defects, whereas a higher filling rate results in folds, blisters, and porosity. The optimized filling rate with Mg alloy casting is 140 to 170 mm/s in low-pressure EPC.     

Implementation of pole placement adaptive controller for force control of non-minimum phase end milling operations

The design and implementation of a pole placement adaptive controller are discussed for force control of the end milling process. The end milling process considered is a non-minimum phase system whose computational delay exceeds one half of the control interval. The internal model principle is included in the controller design to ensure a zero steady-state tracking error. Experimental results show that the pole placement adaptive controller is effective for force control of the non-minimum phase end milling operation and the closed-loop control system is stable over a wide range of cutting conditions.     

LD-氯站流程生产Q235B钢连铸板坯中间裂纹的分析与控制

针对LD-氩站流程生产Q235B钢230 mm连铸板坯出现的中间裂纹,利用光学显微镜、扫描电镜和能谱仪对中间裂纹宏观和微观特征进行了系统分析。结果表明,判断扇形段接弧不良、辊缝精度差、辊子错位等是中间裂纹形成的外因;裂纹带上有粗大的晶粒,且有明显的Mn、S等元素以及复合夹杂物形态聚集是铸坯产生中间裂纹的内因。通过控制接弧精度≤±0.3mm、辊缝精度≤±0.5 mm、二冷比水量0.50 L/kg、成品[S]≤0.030%、[Mn]/[S]≥15等工艺措施,减少甚至杜绝板坯中间裂纹的发生,提高了连铸板坯的心部质量。     

粉末冶金法制备云母/羟基磷灰石玻璃陶瓷

为了获得良好的可加工性和生物活性,采用粉末冶金法制备了云母/羟基磷灰石玻璃陶瓷.随着烧结温度的提高,材料的力学性能有所增加.在1100℃下、保温1.5 h可以获得材料的最佳力学性能,其相对密度、抗弯强度和断裂韧性分别为95%、124 MPa和2.1 MPa·m1/2.随着温度的提高,烧结过程中玻璃相的扩散速度加快并填充到剩余的孔隙中,使得材料的相对密度增加,从而提高了材料的抗弯强度.断裂韧性的提高来源于材料中高长径比的云母晶体相互交错的微观结构.     

硬脆材料专用ELID磨削液的研制

本文在已有新型通用ELID磨削液(HDMY-20型)的基础上，根据硬脆材料的磨削特点和ELID磨削过程中磨削液的电解修锐生膜缓蚀作用、结合通用ELID磨削液的研制经验．通过增添表面活性剂、稳定剂、防锈剂、油性极压剂和调整无机盐等成分的比例关系．优化出适合硬脆材料ELID磨削最佳状态的专用ELID磨削液。应用此磨削液磨削硬质合金表面粗糙度可达Ra0．007μm比通用型磨削液磨削的硬质合金Ra值降低了0．005μm。     

渗碳工艺CAD软件的研究开发

研究开发的渗碳工艺CAD软件,采用模块结构,菜单式操作,可对不同钢种进行不同渗碳工艺的工艺参数设计和渗碳过程模拟。     

Influence of alloy ingredients on mechanical properties of ternary boride hard alloy clad materials

Using Mo, B-Fe alloy and Fe powders as raw materials, and adding C, Cr and Ni ingredients, respectively, or C, Cr and Ni mixed powders, ternary boride hard alloy clad materials was prepared on Q235 steel substrate by means of in-situ reaction and vacuum liquid phase sintering technology. The influence of alloy ingredients on the mechanical properties of ternary boride hard alloy clad materials was investigated. The results indicate that a mixture of 0.8% C, 5% Cr and 2% Ni ingredients gives a ternary boride hard alloy clad material with optimal mechanical properties, such as high transverse rupture strength, high hardness and good wear resistance.     

Thermal stability behaviors of Cr(N,O)/CrN double-layered coatings by TGA/DTA analysis

In this study, Cr(N,O)/CrN double-layered coatings were synthesized using the cathodic arc deposition (CAD) process. CrN film was first deposited onto a substrate as an interlayer to ensure better adhesion, and Cr(N,O) film was subsequently deposited on top of the CrN layer as the surface layer. Variation in the Cr(N,O) coating composition was achieved through changing the O₂/N₂ flow ratio during the last stage of processing. Phase structure, chemical composition, and morphology of the resulting coatings were analyzed and observed using the X-ray diffractometer, Auger electron spectrometer and SEM. In addition, oxidation behavior of the coatings was investigated using TGA/DTA methods. The tests were carried out by increasing temperature up to 1000 °C in ambient air. With the introduction of oxygen gas during the CAD process, a superficial layer was produced in the Cr(N,O) constituent containing CrN and Cr₂O₃ phases. The formation of the oxide phase attributed to the reaction of chromium and oxygen was more favorable than that of chromium and nitrogen. The results also showed that Cr(N,O)/CrN double-layered coatings exhibited superior oxidation resistance at elevated temperature than that of CrN single-layer coated specimen (870 °C vs. 750 °C).     

银粉对PZT压电陶瓷电极表面结构和性能的影响

本文重点讨论不同银粉对PZT（PbZrO3-PbTiO3)压电陶瓷电极表面结构及性能的影响。选择合适的银粉，配制成银浆，可以烧结出结构平整，致密，性能优良的PZT表面银电极。