铂与氢、水和苯分子相互作用的量子化学研究

采用量子化学程序Gaussian98(A.9)从头算的B3LYP方法，全优化计算铂对氢、水和苯的化学吸附作用，得到了3种相关络合物PtX、PtXX和Ptxxx(X=H，H2O或C6H6)的平衡几何构型和电子结构信息，并探讨了这些络合物的成键性质，以及苯环与铂原子之间的分子轨道作用性质。结果表明，苯环与铂原子之间有很强的成键作用，并随着游离氢原子和水分子的参与，作用强度有很大变化。苯分子吸附在金属铂上，它的芳香性得到不同程度的降低，苯环被活化，苯环与铂原子之间形成η^2型π键络合物；水参与作用后，苯环与铂原子之间形成σ络合物；氢和水同时参与作用后，苯环与铂原子之间仅有很弱的π轨道作用。     

基于Delphi开发的POS系统的研究

零售业是生活中常见的行业，在零售业中引入了电子收款机系统（Point of Sells，POS）即进销存管理系统，是商店经营中的最热门的话题之一。这种进销存管理系统一般是现在比较常见的客户端／服务器模式也即C／S模式。文章介绍了采用INSPRISE公司的DELPHI7.0开发工具结合SQL SERVER2000数据库服务器。首先在短时间内建立系统应用原型，然后，对初始原型系统进行需求更迭，不断修正和改进，直到形成用户满意的可行系统。     

Effects of Heat Treatment on the Transformation Temperature and the Microstructure of Ni-Ti-Nb Shape Memory Alloy

The effects of heat treatment on the phase transformation temperature and the microstructure of Ni-Ti-Nb alloy have been investigated by means of R-T method, TEM and EPMA. With the increase of annealing temperature, cooling rate and ageing temperature, the Ms temperature increases. TEM observations show no new precipitated phase was found in the B2 parent phase after heat treatment, but EPMA shows the content of Ni (or Ni/Ti ratio) in the B2 matrix changed. The main reason for the change of transformation temperature lies in the change of the matrix composition (or Ni/Ti ratio) with the variation of heat treatment procedure.     

Computer Simulation of the Structure and Propertiesof Nanocrystals

This paper provides a computer modeling method for the study of nanocrystals. Structural features,such as the boundary component proportion, the reduced density proportion, the excess lattice parameter, and the radial distribution function, have been atomistically simulated. The energy and elastic properties also have been investigated. Simulation results indicate that the structure of grain boundaries in nanocrystals is different from those of the amorphous and the gas, or rather, it is a special structure with some degree of short-range order. Moreover, the structure of crystallites is not entirely the same as that in the perfect crystal lattice. The present simulation method may become one of the foundations of the theoretical study of nanocrystals.     

A new approach of formation navigation derived from multi-robots cooperative online FastSLAM

A new formation navigation approach derived from multi-robots cooperative online FastSLAM is proposed. In this approach,the leader and follower robots are defined.The posteriori estimation of the leader robot state is treated as a relative reference for all follower robots to correct their state priori estimations.The control volume of individual follower will be achieved from the results of the corrected estimation.All robots are observed as landmarks with known associations by the others and are considered in their landmarks updating.By the method,the errors of the robot posterior estimations are reduced and the formation is well kept.The simulation and physical experiment results show that the multi-robots relative localization accuracy is improved and the formation navigation control is more stable and efficient than normal leader-following strategy.The algorithm is easy in implementation.     

基于进化计算的兴趣建模

为实现对个体的兴趣建模,提出基于进化计算的建模(Evolutionary Computation Based Modeling,ECBM)方法。该方法采用定性和定量相结合的方式对个体的兴趣系统进行建模,首先通过定性分析构建个体的兴趣模型框架,然后通过进化计算(Evolutionary Computation)方法对模型参数自动进化。实验结果表明,ECBM能够通过数据驱动模式优化模型参数,并利用更新信息进化模型,使其不断逼近真实系统。     

基于时延抖动的主动队列管理算法

随着Internet的迅速发展,致使IP业务的快速增长和多样化,用户数量急剧增加,网络流量呈爆炸式增长,网络拥塞问题变得越来越严重,因此服务质量(QoS)成为了当今世界研究热点之一.为了能达到相对的QoS的性能指标,拥塞控制发挥着相当重要的作用,而主动式队列管理(Active Queue Management,AQM)机制又是实现拥塞控制的重要手段之一,AQM成为了IP网络拥塞控制研究领域中备受关注和深入研究的热点问题.文中在增强CHOKe算法的公平性上,提出一种新的基于时延抖动的AQM算法-CZ-CHOKe.路由器通过时延抖动和队列的平均队长检测网络拥塞,同时采用动态采样击中和自适应丢包技术.仿真结果表明,该算法能有效地保护响应流,提高非响应流的击中概率,提高其算法的公平性.     

基于CC2530的ZigBee数据采集系统设计

为了使工业生产中的技术人员不用亲自去现场或者恶劣的环境就可以实时采集现场设备的数据信息及状态参数,结合ZigBee技术适用于数据采集系统的特点,首先在ZigBee技术的理论基础上介绍了数据采集系统采集数据的原理,然后详细讨论了基于CC2530芯片的数据采集节点的硬件设计方法及组网设计中的协调器建立网络、节点加入和脱离网络的软件设计方法,最后给出了该设计方案在LED路灯电压数据采集实验中的应用实例。实验结果表明这种设计方案不仅能有效地采集设备的各项数据,而且使系统的扩展、维护变得更加方便。     

基于LABVIEW的电能质量在线监测和分析

本文讨论了国家标准规定的电能质量参数的计算方法,并利用LabVIEW创建了频率、谐波、三相不平衡度的测量和数据分析程序,同时采用DataSocket技术进行网络通信。设计出了基于LABVIEW的电能质量在线监测和分析系统,该系统提高了在线监测的灵活性和参数的精度并能及时记录相关的电压事件,能够长时间稳定工作,具有一定的实用价值。