Bioactive ceramic coatings containing carbon nanotubes on metallic substrates by electrophoretic deposition

A range of potentially bioactive ceramic coatings, based on combinations of either hydroxyapatite (HA) or titanium oxide nanoparticles with carbon nanotubes (CNTs), have been deposited on metallic substrates, using electrophoretic deposition (EPD). Sol–gel derived, ultrafine HA powders (10–70 nm) were dispersed in multi-wall nanotube-containing ethanol suspensions maintained at pH = ∼3.5 and successfully coated onto Ti alloy wires at 20 V for 1–3 min For TiO₂/CNT coatings, commercially available titania nanopowders and surface-treated CNTs in aqueous suspensions were co-deposited on stainless steel planar substrates. A field strength of 20 V/cm and deposition time of 4 min were used working at pH = 5. Although the co-deposition mechanism was not investigated in detail, the evidence suggests that co-deposition occurs due to the opposite signs of the surface charges (zeta potentials) of the particles, at the working pH. Electrostatic attraction between CNTs and TiO₂ particles leads to the creation of composite particles in suspension, consisting of TiO₂ particles homogenously attached onto the surface of individual CNTs. Under the applied electric field, these net negatively charged “composite TiO₂/CNT” elements migrate to and deposit on the anode (working electrode). The process of EPD at constant voltage conditions was optimised in both systems to achieve homogeneous and reasonably adhered deposits of varying thicknesses on the metallic substrates_.     

Power·delay product in COSMOS logic circuits

In this simulation work, we use COSMOS logic devices—a novel single gate CMOS architecture recently announced [1]—in multi-input logic gates, assessing its performance in terms of power·delay product. We consider three different multi-input logic circuits: a two-input NOR gate, a three-input NOR gate, and a three-input composite NOR/NAND (NORAND) gate. For this power·delay analysis, the transient TCAD simulations are employed in a mixed-mode approach where circuit and device simulations are coupled together, culminating in the delay response of the circuits as well as the static/dynamic current components. The analysis shows that all circuits, except the 3-input NOR gate, has acceptable characteristics at low-power applications and static leakage limits all COSMOS circuits at high-bias conditions.     

Dynamic soil–structure interaction analysis of layered unbounded media via a coupled finite element/boundary element/scaled boundary finite element model

In this paper, a coupled model based on finite element method (FEM), boundary element method (BEM) and scaled boundary FEM (SBFEM) (also referred to as the consistent infinitesimal finite element cell method) for dynamic response of 2D structures resting on layered soil media is presented. The SBFEM proposed by Wolf and Song (Finite‐element Modelling of Unbounded Media. Wiley: England, 1996) and BEM are used for modelling the dynamic response of the unbounded media (far‐field). The standard FEM is used for modelling the finite region (near‐field) and the structure. In SBFEM, which is a semi‐analytical technique, the radiation condition at infinity is satisfied exactly without requiring the fundamental solution. This method, also eliminates the need for the discretization of interfaces between different layers. In both SBFEM and BEM, the spatial dimension is decreased by one. The objective of the development of this coupled model is to combine advantages of above‐mentioned three numerical models to solve various soil–structure interaction (SSI) problems efficiently and effectively. These three methods are coupled (FE–BE–SBFEM) via substructuring method, and a computer programme is developed for the harmonic analyses of SSI systems. The coupled model is established in such a way that, depending upon the problem and far‐field properties, one can choose BEM and/or SBFEM in modelling related far‐field region(s). Thus, BEM and/or SBFEM can be used efficiently in modelling the far‐field. The proposed model is applied to investigate dynamic response of rigid and elastic structures resting on layered soil media. To assess the proposed SSI model, several problems existing in the literature are chosen and analysed. The results of the proposed model agree with the results presented in the literature for the chosen problems. The advantages of the model are demonstrated through these comparisons. Copyright © 2004 John Wiley & Sons, Ltd.     

Characterization of Clay Particle Surfaces for Contaminant Sorption in Soil Barriers Using Flow Microcalorimetry

Clays such as kaolinite and bentonite are widely used in various industries as sorbents. The sorptive characteristics of clays are exploited when they are used in contaminant barrier systems. To use clays effectively, their surface characteristics need to be known; especially, when they are used for contaminant sorption. Available surface area of clay minerals and the characteristics that depend on it are very sensitive to environmental changes such as those that can be induced by changes in the composition of pore fluid. Flow microcalorimetry with a down-stream concentration was used to determine the heats and amounts of adsorption of acids and bases on the clays. Test results presented herein revealed that both kaolinite and bentonite exhibit significantly different adsorption isotherms and heat of wetting under high pH and low pH conditions. Kaolinite has the capacity to adsorb both acidic and basic molecules almost equally. However, it has a tendency to adsorb more base than acid because of its stronger complexation capacity with acids than with bases. On the other hand, bentonite has a tendency to adsorb more acidic than basic molecules per gram. These results also indicate that both kaolinite and bentonite have different heats of wetting characteristics. As the concentrations of the acids and bases increase, the heat of wetting of kaolinite decreases while that of bentonite increases.     

Tuning PI controllers for stable processes with specifications on gain and phase margins

In industrial practice, controller designs are performed based on an approximate model of the actual process. It is essential to design a control system which will exhibit a robust performance because the physical systems can vary with operating conditions and time. Gain and phase margins are well known parameters for evaluating the robustness of a control system. This paper presents a tuning algorithm to design and tune PI controllers for stable processes with a small dead time while meeting specified gain and phase margins. Simulation examples are given to demonstrate that the proposed design method can result, in a closed-loop system, in better performances than existing design methods which are also based on user-specified gain and phase margins.     

Synthesis,Thermal and Morphological Properties of Polyurethanes Containing Azomethine Linkage

This paper presents synthesis, photophysical, electrochemical, thermal and morphological properties of Schiff bases containing various side-group substitutions and polyurethanes (PUs) containing azomethine linkage. Morphological properties of PUs containing azomethine bonding were investigated by scanning electron microscopy (SEM). SEM images showed that PU containing azomethine consist of semi-crystalline particles. Thermal transitions in PUs containing azomethine units were studied using DSC. The obtained DSC curves showed that PUs containing azomethine are semi-crystalline materials due to they contain both crystallization and melting peaks. Electrochemical properties also investigated by using cyclic voltammetry (CV). According to the cyclic voltommagrams and CV data, PUs containing azomethine have below 2.0 eV electrochemical band gap.     

The use of basalt powder as a natural heterogeneous catalyst in the Fenton and Photo-Fenton oxidation of cationic dyes

The use of naturally present heterogeneous catalysts has recently been an essential issue in the Fenton and photo-Fenton processes. In this study, the uses of basalt as a catalyst for the Fenton and photo-Fenton reactions for methylene Blue (MB) and Basic Red 18 (BR18) degradations were investigated. Basalt was selected because of the presence of the iron (III) oxide in the structure. Basalt was characterized by X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD) analysis to obtain the chemical composition and the crystalline phase. The surface charge and the surface area were obtained by zeta potential and Brunauer Emmett-Teller (BET) analysis. Fourier Transform Infrared Spectroscopy (FTIR) and scanning electron microscope (SEM) were utilized to explore the functional group and the surface morphology. Fenton and photo-Fenton processes were applied to explore the best degradation method. Adsorption was also tested and the adsorption process had minimum removal efficiency (12% for MB and 17% for BR18). The removal efficiencies for MB and BR18 by the Fenton process were 87% and 28%, respectively. The photo-Fenton process had maximum removal efficiency with 100% for MB and 70% for BR18. The optimum conditions were 70 mg/L dye concentration, 5 mM H₂O₂, 1.0 g/L basalt loading and pH 2. Basalt has shown reuse capability as a catalyst for three consecutive cycles.     

Effect of replacing disc cutters with chisel tools on performance of a TBM in difficult ground conditions

A summary of a research program covering a period of two years on the performance of a TBM in a very complex and difficult geology is presented in this study. The formations in the study area varied from alluvium, sludge, mudstone, shale and limestone to quartzite with strengths from soft to very hard. The dykes frequently intruded the sedimentary rocks resulting in different degrees of weathering and fracturing in the country rock causing tremendous delays in progress rate of the TBM. The disc cutters started cutting inefficiently in clayey medium strength ground with extreme water income, at where also excessive disc consumptions started due to insufficient friction between the disc cutters and very soft (sludgy) formation, and it was decided to replace all disc cutters with chisel tools (ripper, scraper). Before making this important decision that could affect totally the excavation efficiency and production rate, some theoretical estimations were performed using the Evans’ cutting theory after some modifications based on the previous experimental studies for relieved cutting mode and wear flat, front ridge and vee-bottom angles found in complex shapes of chisel tools to estimate deterministically the torque and thrust requirements of the TBM.Field measurements of the torque and thrust requirements of the TBM equipped with the chisel tools validated the theoretical considerations and the deterministic model used for predicting the performance. Statistical analysis indicated that the model could be used reliably for performance prediction. This study also gave a unique opportunity to compare the performance of disc cutters and chisel tools used on the same TBM at variety of grounds and to analyze the effect of replacing disc cutters with chisel tools on the performance of the TBM. The field measurements indicated that the chisel tools were superior to the disc cutters in especially soft to medium strength rocks.     

Innovative hydrogen release from sodium borohydride hydrolysis using biocatalyst-like Fe2O3 nanoparticles impregnated on Bacillus simplex bacteria

For the first time in this innovative study, microorganisms such as Bacillus simplex bacteria, mostly used in biological activity studies, are used as a bio-supporter agent of iron to release hydrogen from sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The goal is to investigate thoroughly sodium borohydride hydrolysis catalyzed by Fe₂O₃ nanoparticles impregnated on microorganism such as Bacillus simplex (BS) bacteria (Fe₂O₃@BS NPs) known with strong antibacterial properties, which makes innovative them a candidate for hydrolysis reaction. This study was focused on the preparation, identification, and catalytic use of biocatalyst-like Fe₂O₃@BS NPs for hydrogen release from the sodium borohydride hydrolysis at 25.0 ± 0.1 °C. The characterization results made after and before hydrolysis reaction using by SEM/SEM-EDX, FT-IR, XRD, UV–vis, XPS, DLS, ELS Zeta potential, ESR, and TEM techniques reveal the formation of highly active, stable, durable, and long-lived biocatalysts-like Fe₂O₃@BS NPs.