The kinetics of B‐a and P‐a type copolybenzoxazine via the ring opening process

The structure of benzoxazines is similar to that of phenolic resin through thermal self‐curing of the heterocyclic ring opening reaction that neither requires catalyst nor releases any condensation byproduct. These polybenzoxazine resins have several outstanding properties such as high thermal stability and high glass transition temperature. To better understand the curing kinetics of this copolybenzoxazine thermosetting resin, dynamic and isothermal differential scanning calorimetry measurements were performed. Three models, the Kissinger method, the Flynn–Wall–Osawa method, and the Kamal method, were used to describe the curing process. Dynamic kinetic activation energies based on Kissinger and Flynn–Wall–Osawa methods are 72.11 and 84.06 KJ/mol, respectively. The Kamal method based on an autocatalytic model results in a total order of reaction between 2.66 and 3.03, depending on curing temperature. Its activation energy and Arrhenius preexponential are 50.3 KJ/mol and 7959, respectively. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 95: 730–737, 2005     

Rheology-processing-property relationships in tubular blown film extrusion. I. High-pressure low-density polyethylene

Three different grades of high-pressure low-density polyethylene resin were used to establish relationships between tubular film blowability and the molecular parameters, namely, the molecular weight distribution (MWD) and the degree of long-chain branching (LCB), and also between the processing conditions and the mechanical properties of the tubular blown films produced. For the study, both the shearing and elongational flow properties of the resins were determined. During the tubular film blowing experiment we measured the freeze-line position, the tubular bubble diameter, the takeup speed, the axial tension, the pressure inside the tubular bubble, and the mass flow rate of the resin. The thickness of the tubular blown films was measured from the samples collected. In order to determine the tubular film blowability, we measured the maximum takeup speed at which the tubular blown bubble broke, for various blowup ratios. The measurements described above permitted us to calculate the tensile stresses at the freeze line, in both the machine and transverse directions, and they were found to be correlatable to the processing conditions employed. It has been found that the tubular film blowability is increased as the resin's MWD becomes narrower and the degree of LCB is less. It has been found further that a resin having lower elongational viscosity tends to give a greater draw-down ratio, indicating a better tubular film blowability. Finally, the tensile properties of the tubular blown films were found correlatable to the processing variables, namely, blowup and takeup ratios.     

Thermal runaway prevention in catalytic packed bed reactor by solid temperature measurement and Control

Magnetic crystallite thermometry has been used to measure the average nickel crystallite temperature in packed bed reactors during ethane hydrogenolysis, an exothermic reaction. The technique is based on the temperature dependence of the magnetic moment of dispersed nickel catalysts. Measurement of the average catalyst temperature is very useful for reactor control because of its shorter time constant compared with exit fluid temperature. Bed temperature control based on the exit fluid temperature, which has often been used as a control variable, is too slow to protect thermal runaway of the bed. The advantage of short time constant by measuring the average catalyst temperature has been incorporated with enhanced feedback control system to control the bed temperature and prevent the thermal runaway of the catalyst bed. An enhanced feedback control structure with supervisory action performed better than the classical proportional-integral control in runaway prevention when the two control schemes were compared with each other on the basis of the trippoint (incipient thermal runaway).     

心理资本前因变量研究

采用心理资本问卷对分别属于医药、建筑、水利工程、电信、通讯运营和服务行业的6家企业的员工进行了调查.根据对回收的283份有效问卷的统计分析,认为员工的性别、受教育程度和所在企业的性质对员工心理资本不会产生显著性影响,而员工年龄的影响显著,50岁以上员工的总体心理资本水平高于其他年龄段员工.     

增强《马克思主义基本原理概论》课程教学实效的体会

上好<马克思主义基本原理课概论>,要对这门课的性质、地位和任务、基本要求以及课程的重点和难点有一个基本认识,并能正确面对教学中的困境.思想政治课教师要苦练内功,不断提高自己的学识水平,开动脑筋,转变观念,采取灵活多样的教学方法和手段,把教师的"教"与学生的"学"有机结合起来,想方设法提高学生的学习积极性,要把理论课教学和实践课教学结合起来,改革思想政治课的评价体系和方式,不断增强思想政治课教学的实效性.     

我国农业保险发展中存在的问题及对策

针对我国农业保险发展现状,分析了农业保险发展中存在的问题.认为目前我国农业保险的发展正处于最困难和最关键的时期.为推动农业保险的快速发展,提出了建立和完善有关法规、加大政策扶持力度,确立农业法定险种、成立综合性农业保险公司、建立再保险机制和多渠道农业保险体系等措施建议.     

基于约束满足的多目标双足机器人动态步态参数优化*

目前的步态优化算法仅仅实现了对单一目标的优化,把双足机器人步态优化看做是多目标优化问题,构建了衡量稳定性、能量消耗、步行速度三个目标评价函数。考虑到直接对多个目标加权求和的方法不能很好地处理多目标问题,提出一种新的基于约束满足的多目标步态参数优化算法,其思想是把基于惩罚函数的SPEA2(strength Pareto evolutionary algorithm2 )应用到多目标双足机器人动态步态参数优化问题上,规划出了同时满足这三个目标的动态优化步态。通过仿真实验表明了算法的有效性。     

18世纪晚期市民阶级在德国文化中的自我塑造:《奢侈与时尚期刊》研究

本文通过研究<奢侈与时尚期刊>来分析18世纪德国市民阶级的自我塑造.它宣扬奢侈品消费加速了经济与社会的发展,也为文化进步和国家民族富裕提供了动力.它主要关注私生活里的文化与社会自身的构建,并帮助市民阶级进行自我塑造且与其他阶级进行区分.它还阐述了时尚与奢侈品消费的重要性与必要性,并驳斥了神学与道学将时尚视为虚荣及道德缺陷的偏见.它认为作为文化差异的一部分,服装特色的区分成为一种衡量人民与国家成熟与否的标尺.时尚发挥了视觉艺术的功能,甚至于也是一种行为艺术.此外,时尚还与身体复杂地联系在一起,两者缺一不可.     

生活质量视阈下的大学生“精神贫困”测量指标研究

高校大学生＂精神贫困＂现象已引起人们重视,成为多方关注话题。本文在梳理前人研究成果基础上,对＂精神贫困＂测量指标进行研究,以获得科学的测量指标体系,为获得真实科学的一手资料打进行理论论证。     

气压驱动式自动离合器控制技术研究

为了以较低成本实现AMT系统中离合器执行机构的气压驱动,在对离合器控制过程深入分析的基础上结合气动控制特点,提出了通过高速开关电磁阀以PWM方式驱动纯气动离合器执行机构的方法,及离合器参考模型自适应控制方法.通过多位驾驶员在不同道路条件和环境条件下的实车道路考核,验证了这种控制方法的可行性,研究结果同时表明:采用该方法的离合器执行机构价格低廉,为进一步实现产业化奠定了基础.