[Cu_2(Gly—GlyO)_2(OH)_2(4,4—bpy)]·9H_2O配合物合成、晶体结构研究

采用Gly—GlyOH,4,4＇—联吡啶与Cu(NO_3)_2·H_2O在二次水溶液中反应,合成出以4,4＇—bpy为中继基,Gly—Glyo为螯环新型双核铜配合物。经X射线单晶结构分析确定该配合物品体的化学结构式:[(H_2NCH_2CONHCH_2COO) Cu(OH) (C_(10)H_8N_2)Cu(OH) (H_2NCH_2CONHCH_2COO)]·9H_2O.晶体属于三斜晶系,P_空间群,晶胞参数a=1.1412nm,b=1.2298nm,C=1.4269nm,α=113.82°,β=101.91°,y=103.64°,V=1.6747nm~3,Z=2。衍射数据是在Nicolet XRD R3型四圆衍射仪上收集,结构参数经块矩阵最小二乘法精修后,最终一致性因子R值为0.068,RW值为0.057。     

Modification of silk with aminated polyepichlorohydrin to improve dyeability with reactive dyes

Reactive dyes have almost complete exhaustion and ideal fixation on aminated polyepichlorohydrin pretreated silk without addition of salt or alkali. The effects of varying pretreatments and dyeing conditions were studied. The dyeing behaviour of CI Reactive Red 15 on modified silk under pH 6 was investigated. Dyeings of modified silk showed good wash fastness, dry and wet rub fastnesses as well as light fastness. The quality of the dyed silks obtained after pretreatment was shown to be satisfactory and the dyeing effluent was less polluted.     

近闸布置斜向进流泵站进水流态及改善措施试验研究

靠近已建水闸新建的排涝泵站工程布置一般均偏置与河道主流一侧,受场地限制引渠长度及转弯半径往往无法满足规范要求,造成泵站进流不均,影响泵站正常运行。通过宁波市印洪碶泵站模型试验,分析"斜向进水"泵站进水建筑物进水流态及其改善措施。实验研究表明:其不良流态表现为新开河段凹岸侧回流和右侧翼墙后的绕流;独立进水池的隔墩约束导顺作用可有效改善泵站进水横向流速分布不均问题;采用减小引渠扩散角、采用直立岸墙断面代替直立+斜坡断面与前池平顺连接可有效消除前池入口左侧回流区。     

A general non-local denoising model using multi-kernel-induced measures

Noises are inevitably introduced in digital image acquisition processes, and thus image denoising is still a hot research problem. Different from local methods operating on local regions of images, the non-local methods utilize non-local information (even the whole image) to accomplish image denoising. Due to their superior performance, the non-local methods have recently drawn more and more attention in the image denoising community. However, these methods generally do not work well in handling complicated noises with different levels and types. Inspired by the fact in machine learning field that multi-kernel methods are more robust and effective in tackling complex problems than single-kernel ones, we establish a general non-local denoising model based on multi-kernel-induced measures (GNLMKIM for short), which provides us a platform to analyze some existing and design new filters. With the help of GNLMKIM, we reinterpret two well-known non-local filters in the united view and extend them to their novel multi-kernel counterparts. The comprehensive experiments indicate that these novel filters achieve encouraging denoising results in both visual effect and PSNR index.     

Adaptive recurrent neural network control of uncertain constrained nonholonomic mobile manipulators

In this article, motion/force control problem of a class of constrained mobile manipulators with unknown dynamics is considered. The system is subject to both holonomic and nonholonomic constraints. An adaptive recurrent neural network controller is proposed to deal with the unmodelled system dynamics. The proposed control strategy guarantees that the system motion asymptotically converges to the desired manifold while the constraint force remains bounded. In addition, an adaptive method is proposed to identify the contact surface. Simulation studies are carried out to verify the validation of the proposed approach.     

A perceptual evaluation of grating frequencies and velocities in the analysis of dynamic images

Dynamic images that possess beauty and are user-friendly can increase the use of digital technology. In addition to information conveyance, dynamic images also act as a communication bridge in the human–machine interface. Dynamic images are widely used in the application of digital media. Therefore, understanding the visual effects of dynamic images on viewers is a very important issue. From a visual communication design perspective, dynamic images influence not only image quality, but also the viewers’ perception and impression of the displayed image. In the contemporary age characterized by universal usage of dynamic images, designers should attain synchronized knowledge and understanding of relevant media technology so as to present preferred design quality in the management of digital design such as animation design, Web page design, multimedia design, and so on. The current study noted that psychological effects such as viewers’ visual attention, preferences, and understanding were more important than image quality. Therefore, this study adopted the viewpoint of “visual design” and conducted a perceptual evaluation of grating frequency and grating velocity. The pair-comparison method and scale method were adopted in the research methodology to simplify perceptual evaluations and enhance their validity. The purpose of this study was: (1) To propose recommendations for displaying dynamic images and improving image performance using perceptual evaluation methods. (2) To examine the influence of psychological factors on viewer’s comfort when they experience dynamic images. (3) To identify the best grating feature combinations that meet viewer’s psychological characteristics and propose recommendations for dynamic images design. The study concludes that it is useful to establish criteria for evaluating users’ perception and to, develop perceptual evaluations of dynamic images. It is recommended that designers find a balance between watching a moving imaging display “clearly” and watching it “comfortably” for successful reception by the viewer.     

降膜波动特性的研究

本文提出了一种测定膜厚的新方法－双电导探针法，测定了高湍流降膜的厚度沿降膜管管程的变化情况，探讨了径向平均膜厚及膜厚的概率密度分布沿管程的变化规律，证明降膜的波动特性同时受到液相雷诺数和管程的影响。并对平均膜厚和液相雷诺数作了经验关联，得出NT＝（δ^ )^2/3 [8.92(ReL/4)^5/2 6.0×10^-6(ReL/4)^9/2]^2/15。     

Association-Based Active Access Control models with balanced scalability and flexibility

In existing Active Access Control (AAC) models, the scalability and flexibility of security policy specification should be well balanced, especially: (1) authorizations to plenty of tasks should be simplified; (2) team workflows should be enabled; (3) fine-grained constraints should be enforced. To address this issue, a family of Association-Based Active Access Control (ABAAC) models is proposed. In the minimal model ABAAC₀, users are assigned to roles while permissions are assigned to task-role associations. In a workflow case, to execute such an association some users assigned to its component role will be allocated. The association's assigned permissions can be performed by them during the task is running in the case. In ABAAC₁, a generalized association is employed to extract common authorizations from multiple associations. In ABAAC₂, a fine-grained separation of duty (SoD) is enforced among associations. In the maximal model ABAAC₃, all these features are integrated, and similar constraints can be specified more concisely. Using a software workflow, case validation is performed. Comparison with a representative association based AAC model and the most scalable AAC model so far indicates that: (1) enough scalability is achieved; (2) without decomposition of a task, different permissions can be authorized to multiple roles in it; (3) separation of more fine-grained duties than roles and tasks can be enforced.     

Phase Assemblages of Pr α-sialon Derived from SHS-ed Powders and TEM Study on the Nucleation of Pr α-sialon

The Pr α-sialon powders prepared by self-propagating high-temperature synthesis (SHS), consisting of 55 wt% Pr α-sialon and 45 wt% of β-sialon (abbreviated as α' and β'), were hot-pressed at 1800°C for 1 h. The results showed that Pr α' phase would transfer to β' with the appearance of JEM phase (Pr(Si_{6− z} Al _z )(N_{10− z} O _z )) after sintering, thus resulting in the increase of β' phase to 86 wt%. The addition of Y₂O₃ into SHS-ed Pr α' powders as the starting materials restrains the transformation of α' to β' and prevents the formation of JEM phase as well. The nucleation mechanism of Pr α' grain during hot-pressing was investigated in terms of transmission electron microscope and energy-dispersive spectrometer analysis. Two nucleation modes of Pr α' grains were found, i.e., nucleating on the undissolved Pr α' grains and on the nuclei of (Pr, Y) α' grains precipitated from liquid phase.     

高效塔填料——共轭环的性能研究

本文总结了我国自行开发的高效散堆填料——共轭环的流体力学与传质性能,论述了共轭环的结构特点.用φ38塑料共轭环、鲍尔环、阶梯环做对比实验,其结果为:共轭环的每米压强降比阶梯环低40-45%、比鲍尔环低50—55%,共轭环的传质单元高度比阶梯环低15%、比鲍尔环低30%,即共轭环的流体力学和传质性能均比阶梯环、鲍尔环优良.