Unprecedented Homoleptic Bis‐Tridentate Iridium(III) Phosphors: Facile,Scaled‐Up Production,and Superior Chemical Stability

Bis‐tridentate Ir(III) metal complexes are expected to show great potential in organic light‐emitting diode (OLED) applications due to the anticipated, superb chemical and photochemical stability. Unfortunately, their exploitation has long been hampered by lack of adequate methodology and with inferior synthetic yields. This hurdle can be overcome by design of the first homoleptic, bis‐tridentate Ir(III) complex [Ir(pzpyph)(pz^Hpyph)] ( 1 ), for which the abbreviation (pzpyph)H (or pz^Hpyph) stands for the parent 2‐pyrazolyl‐6‐phenyl pyridine chelate. After that, methylation and double methylation of 1 afford the charge‐neutral Ir(III) complex [Ir(pzpyph)(pz^Mepyph)] ( 2 ) and cationic complex [Ir(pz^Mepyph)₂][PF₆] ( 3 ), while deprotonation of 1 gives formation of anionic [Ir(pzpyph)₂][NBu₄] ( 4 ), all in high yields. These bis‐tridentate Ir(III) complexes 2 – 4 are highly emitted in solution and solid states, while the charge‐neutral 2 and corresponding t ‐butyl substituted derivative [Ir(pzpy^Buph)(pz^Mepy^Buph)] ( 5 ) exhibit superior photostability versus the tris‐bidentate references [Ir(ppy)₂(acac)] and [Ir(ppy)₃] in toluene under argon, making them ideal OLED emitters. For the track record, phosphor 5 gives very small efficiency roll‐off and excellent overall efficiencies of 20.7%, 66.8 cd A^?1, and 52.8 lm W^?1 at high brightness of 1000 cd m^?2. These results are expected to inspire further studies on the bis‐tridentate Ir(III) complexes, which are judged to be more stable than their tris‐bidentate counterparts from the entropic point of view.     

Performance analysis and power allocation for decode‐and‐forward cooperative communications over Rician fading channel

This paper derives the asymptotic symbol error rate (SER) and outage probability of decode‐and‐forward (DF) cooperative communications over Rician fading channels. How to optimally allocate the total power is also addressed when the performance metric in terms of SER or outage probability is taken into consideration. Analysis reveals the insights that Rician factor has a great impact on the system performance as compared with the channel variance, and the relay–destination channel quality is of importance. In addition, the source–relay channel condition is irrelevant to the optimal power allocation design. Simulation and numerical evaluation substantiate the tightness of the asymptotic expressions in the high‐SNR regions and demonstrate the accuracy of our theoretical analysis. Copyright © 2011 John Wiley & Sons, Ltd.     

A Novel Pt/In0.52Al0.48As Schottky Diode-Type Hydrogen Sensor

On the basis of a Pt/In_0.52Al_0.48As metal-semiconductor structure, a novel hydrogen sensor is fabricated and demonstrated. The studied Pt/In_0.52Al_0.48As Schottky diode-type hydrogen sensor exhibits significant sensing performance including high relative sensitivity ratio of about 2600% (under the 1% H₂/air gas and V_R=-0.5 V at 30 degC), large current variation of 310 muA (under the 1% H₂/air gas and V_R=-5 V at 200 degC), widespread reverse-voltage regime (0~-5 V), stable hydrogen-sensing current-voltage (I-V) curves, and fast transient response time of 1.5 s. The calculated Schottky barrier-height change and series-resistance variation, from the thermionic-emission model and Norde method, are 87.0 meV and 288 Omega, respectively (under the 1% H₂/air gas at 30 degC). The hydrogen concentrations and operating temperatures tested in this letter are in the range of 15 ppm-1% H₂/air and 30 degC-250 degC, respectively. Based on the excellent integration compatibility with InP-based electronic devices, the studied device provides the potentiality in high-performance sensor-array applications     

Computer-aided kidney segmentation on abdominal CT images.

In this paper, an effective model-based approach for computer-aided kidney segmentation of abdominal CT images with anatomic structure consideration is presented. This automatic segmentation system is expected to assist physicians in both clinical diagnosis and educational training. The proposed method is a coarse to fine segmentation approach divided into two stages. First, the candidate kidney region is extracted according to the statistical geometric location of kidney within the abdomen. This approach is applicable to images of different sizes by using the relative distance of the kidney region to the spine. The second stage identifies the kidney by a series of image processing operations. The main elements of the proposed system are: 1) the location of the spine is used as the landmark for coordinate references; 2) elliptic candidate kidney region extraction with progressive positioning on the consecutive CT images; 3) novel directional model for a more reliable kidney region seed point identification; and 4) adaptive region growing controlled by the properties of image homogeneity. In addition, in order to provide different views for the physicians, we have implemented a visualization tool that will automatically show the renal contour through the method of second-order neighborhood edge detection. We considered segmentation of kidney regions from CT scans that contain pathologies in clinical practice. The results of a series of tests on 358 images from 30 patients indicate an average correlation coefficient of up to 88% between automatic and manual segmentation.     

Adaptive blind receivers for MC‐CDMA communication systems

In this paper, we propose three adaptive blind algorithms for multiuser multicarrier code division multiple‐access systems in multipath fading channels. The proposed adaptive blind receivers are based on the property of the discreteness of the input data symbol and are updated in every symbol interval. We also use the concept that the variance of the output signal approaches to the variance of the desired signal to get the cost function. The three proposed receiver structures are the traditional finite impulse response (FIR) structure, the despreading (DES) filter structure and the generalized sidelobe canceller (GSC) structure. The advantage of the FIR filter is that the length of the filter weights does not have to be the same length as the spreading code. For the DES filter, the combination of the adaptive weight and the despreading code has the simplest structure than the other two proposed receiver structures. The constrained GSC filter is superior to the other two proposed receiver structures in the environments dominated by multiple‐access interference. By this constraint, the blind GSC filter can guarantee to converge to the desired solution. Simulation results are given to show the effectiveness and comparison of the proposed adaptive blind receivers. Copyright © 2012 John Wiley & Sons, Ltd.     

Design of Stepped-Impedance Combline Bandpass Filters With Symmetric Insertion-Loss Response and Wide Stopband Range

An enhanced stepped-impedance combline bandpass filter employs an array of stepped-impedance resonators with tapped-transformer coupling at input and output is presented in this study. This filter has enhanced performance, including symmetric insertion-loss response around the passband and wider stopband range. The structure is compact and suitable for multilayer realization because it is free of lumped capacitors and has fewer via-hole grounds. The circuit is investigated with the characteristic mode theory of coupled lines to prove the existence of multiple transmission zeros around the passband. Numerous diagrams are given for circuit design purposes. The second- and fourth-order bandpass filters at 2.45 GHz were designed, measured, and compared with the conventional combline structure to demonstrate their performance enhancement.     

Coherent frequency/phase modulation scheme

An L-phase-levelled coherent frequency/phase modulation (LCFPM) scheme is proposed and analysed for additive white Gaussian noise channels. The optimised LCFPM scheme with L>2 is found to have superior bandwidth efficiency to the conventional dual-frequency quadrature frequency/phase modulation scheme     

The effect of call admission policies on the system benefit of CDMA communication networks

Previous studies of call admission control (CAC) in mobile communication networks focused on call blocking and call dropping mechanisms. However, achieving global optimization of the system benefit is a complicated process. In this paper, we propose a benefit optimization model that accommodates as many users as possible, while simultaneously maintaining system-wide quality of service (QoS) in terms of admission control. To clarify the CAC concept, we construct a framework of CAC policies, derive associated interference models based on the framework, and then investigate the effects of the policies on the system benefit. In addition, to solve the complicated integer programming problem, we adopt the Lagrangean relaxation approach, and employ Lagrangean multipliers to perform sensitivity analysis of several parameters. The contribution of this study is twofold: the novel problem formulation and the improvement in the system benefit. The computational results demonstrate that the system accrues more benefit as new traffic is loaded and the number of users increases. Meanwhile, the sensitivity analysis shows that proper assignment of the strength of power-controlled signals is a key factor in the global optimization of the system benefit.     

CMOS Outphasing Class-D Amplifier With Chireix Combiner

This letter presents a CMOS outphasing class-D power amplifier (PA) with a Chireix combiner. Two voltage-mode class-D amplifiers used in the outphasing system were designed and implemented with a 0.18-mum CMOS process. By applying the Chireix combiner technique, drain efficiency of the outphasing PA for CDMA signals was improved from 38.6% to 48% while output power was increased from 14.5 to 15.4 dBm with an adjacent channel power ratio of -45 dBc.     

Energetics of Donor‐Doping,Metal Vacancies,and Oxygen‐Loss in A‐Site Rare‐Earth‐Doped BaTiO3

The energetics of La‐doping in BaTiO₃ are reported for both (electronic) donor‐doping with the creation of Ti³⁺ cations and ionic doping with the creation of Ti vacancies. The experiments (for samples prepared in air) and simulations demonstrate that ionic doping is the preferred mechanism for all concentrations of La‐doping. The apparent disagreement with electrical conduction of these ionic doped samples is explained by subsequent oxygen‐loss, which leads to the creation of Ti³⁺ cations. Simulations show that oxygen‐loss is much more favorable in the ionic‐doped system than undoped BaTiO₃ due to the unique local structure created around the defect site. These findings resolve the so‐called “donor‐doping” anomaly in BaTiO₃ and explain the source of semiconductivity in positive temperature coefficient of resistance (PTCR) BaTiO₃ thermistors.