Effect of corrosive solutions on C-S-H microstructure in portland cement paste with fly ash

By means of ²⁹Si and ²⁷Al magic angle spinning nuclear magnetic resonance (MAS NMR) combined with deconvolution technique, X-ray diffraction (XRD), scanning electron microscopy (SEM) as well as energy dispersive X-ray system(EDX), the effect of 5 wt% corrosive solutions (viz. 5 wt% Na₂SO₄, MgSO₄, Na2SO4+NaCl and Na₂SO₄+NaCl+Na₂CO₃) on C-S-H microstructure in Portland cement containing 30 wt% fly ash was investigated.The results show that, in MgSO₄ solution, Mg²⁺ promotes the decalcification of C-S-H by SO ₄ ^2- ,increasing silicate tetrahedra polymerization and mean chain length (MCL) of C-S-H. However, the substituting degree of Al³⁺ for Si⁴⁺ (Al[4]/Si) in the paste does not change evidently. Effect of Na²SO⁴ solution on C-S-H is not significantly influenced by NaCl solution, while the MCL and Al[4]/Si of C-S-H in fly ashcement paste slightly change. However, the decalcification of C-S-H by SO ₄ ^2- and CO ₃ ^2- attack, as well as the activation of fly ash by SO ₄ ^2- attack will increase the MCL and Al[4]/Si, which are both higher than that under Na₂SO₄ corrosion, MgSO₄ or Na₂SO₄ +NaCl coordination corrosion.     

Effects of ultrasonic treatment on microstructure and mechanical properties of semisolid Sn-52Bi alloy

The effects of ultrasonic vibration temperature on the microstructure of semisolid Sn-52 Bi alloy and mechanical properties were investigated. The results show that the microstructure and mechanical properties are improved obviously after the ultrasonic treatment. Nearly round and uniformly distributed primary Sn phase particles were obtained under the cavitation and acoustic streaming caused by ultrasonic treatment. The best effects of ultrasonic treatment on microstructure and mechanical properties were obtained with the ultrasonic vibration for 120 s at 140 ℃. The elongation of semisolid Sn-52 Bi alloy treated by ultrasonic vibration for 120 s at 140 ℃ was 42% and increased by 156.09% compared to conventional liquid casting Sn-52 Bi alloy without ultrasonic vibration. It is a feasible and effective method to adopt the semisolid metal forming technology assisted with ultrasonic vibration to improve the ductility of Sn-Bi alloys.     

高速移动环境下无线信道模型的性能

针对移动网络在高铁通讯时存在接收信号不稳定问题,开展了多普勒效应及多径时延对正弦波叠加(Sum-of-Sinusoid,SOS)模型、XIAO模型(Jakes仿真器)和LIU Qian模型的影响研究.分析了3种模型的信噪比、相关性以及处理信号衰减的程度,结果表明,在多普勒效应及多径时延的环境下,SOS模型的算法复杂度最低,LIU Qian模型反之,而传递函数相关性最佳,XIAO模型对接入信号的衰落程度最小;在保证传输效率、信道容量足够的前提下,LIU Qian模型中接收信号的失真程度较小,更适宜作为高速移动环境下无线信道的研究模型.     

高心墙堆石坝蓄水变形和裂缝机理分析

我国高堆石坝建设正处于高潮期,其中高心墙堆石坝的坝高已达300 m级。结合实际监测资料的坝体变形分析对大坝变形机理的研究和工程设计具有重要的指导意义。结合某电站大坝的实际监测资料,分析初蓄水坝体各部位变形的变化趋势,并就此得出初蓄水对坝体变形的影响区域,分析了各部位变形的影响机理和坝体裂缝发生的机理及发生过程,并利用有限元方法进行了蓄水变形及裂缝的验证。     

基于车身侧视线条分析的汽车造型设计研究

为构建一种直观、快速分析交通工具造型设计的方法,对车身侧面线条进行提炼并归纳出3类关键曲线,即外轮廓线、分形线、内部分割线。结合奥迪A系4款车型,重点讨论外轮廓线与分形线的设计应用,通过外轮廓线定义车型、通过分形线表达设计定位、通过内部分割线完善车身细节。以一款车型设计为例,初步证明了该分析方法的合理性和可行性,结果表明:侧视线条分析是一种符合设计人员思维习惯的有效方法。     

Alignment control for a long span urban rail-transit cable-stayed bridge considering dynamic train loads

In this paper, bridge alignment control with considering dynamic train loads was experimentally and theoretically investigated. Analytical process of bridge dynamics and the self-adaptive Kalman filter bridge alignment control method with considering the dynamic train loads were briefly introduced. The static measurement, the dynamic test, the field alignment measurement as well as the finite element analysis (FEA) of the second longest rail transit cable-stayed bridge in the world were carried out. Based on the results, the train dynamic load effect on the bridge alignment was obtained quantitatively. Subsequently, alignment control of the rail transit bridge with considering this effect using a self-adaptive Kalman filter method was analyzed. The results show that: (a) the dynamic train loads have effects on alignment control of the bridge and therefore cannot be neglected; (b) the self-adaptive Kalman filter method is applicable and reliable for alignment control of bridges during construction. The analytical method and whole process contribute to develop a related specification and further engineering applications.     

Multi-species particle swarms optimization based on orthogonal learning and its application for optimal design of a butterfly-shaped patch antenna

A new multi-species particle swarm optimization with a two-level hierarchical topology and the orthogonal learning strategy(OMSPSO) is proposed, which enhances the global search ability of particles and increases their convergence rates. The numerical results on 10 benchmark functions demonstrated the effectiveness of our proposed algorithm. Then, the proposed algorithm is presented to design a butterfly-shaped microstrip patch antenna. Combined with the HFSS solver, a butterfly-shaped patch antenna with a bandwidth of about 40.1% is designed by using the proposed OMSPSO. The return loss of the butterfly-shaped antenna is greater than 10 d B between 4.15 and 6.36 GHz. The antenna can serve simultaneously for the high-speed wireless computer networks(5.15–5.35 GHz) and the RFID systems(5.8 GHz).     

莠去津磁性分子印迹材料制备与吸附应用研究

以莠去津(atrazine)为模板分子,甲基丙烯酸(methyl acrylic acid,MAA)为功能单体,Fe3O4磁性纳米微球为载体,制备了具有特异性识别莠去津的磁性分子印迹聚合物。通过Langmuir等温吸附模型得莠去津分子印迹聚合物(atrazine-magnetic molecularly imprinted polymer,AT-MMIPs)最大吸附量为84.34mg/g;结合吸附动力学模型和吸附位点Scatchard方程对莠去津磁性分子印迹聚合物进行了吸附机理分析。对水库水样中存在的痕量莠去津进行了模拟检测分析,结果表明莠去津磁性分子印迹聚合物用于检测水样中残存的痕量莠去津是可行的。     

混凝土弹塑性损伤本构模型参数及其工程应用

为提高弹塑性损伤本构模型的工程实用性,研究各参数取值对模型损伤发展、塑性发展及材料应力应变关系的影响.拟合参数取值与混凝土材料常用指标弹性模量、单轴抗压强度及单轴抗拉强度联系之间的函数关系,提出实用的参数取值确定方法.对规范规定的各强度混凝土材料进行数值模拟,结果表明:模型及参数确定方法能够较准确地模拟混凝土材料的各种非线性本构行为.采用用户材料子程序UMAT进行本构模型在ABAQUS中的二次开发,对上海某酒店项目进行数值模拟:在结构设计软件PKPM中完成建模,将模型转换为ABAQUS模型进行计算,并将计算结果与振动台试验结果进行比较.结果表明:各振形计算自振频率相差在5%以内,顶层位移时程除个别极值外总体匹配较好,楼层位移差在10%以内,最大层间位移除个别楼层相差达到30%以外,一般楼层相差10%左右,验证了所提出的参数确定方法及本构模型是合理有效的;通过分析结构各关键时刻损伤分布云图,表明弹塑性损伤本构模型能够实时反映结构的破坏过程,便于分析者直观地把握结构破坏形态.     

地震计标定及特性分析应用研究

地震计的参数是进行地震波形反演、地震震级确定的基本资料,其性能指标影响着地震数据产出的质量。地震计标定时,初始点位置的选取直接影响对仪器性能好坏的判断。本文以某水库地震监测台网中1个台站标定为例,通过检验和测定地震计标定过程中通频带平坦程度、三分向幅度响应一致性、频带范围、周期阻尼等参数,详细讨论了标定过程中起始点位置的选择原则及影响周期、阻尼计算结果的因素。