Improved high-rate performance and cycling stability of 1D LiFePO4 nanorods by a facile annealing process

To alleviate the main limitations of lithium ion diffusion rate and poor electronic conductivity for LiFePO4 cathode material, it is desirable to synthesize nano-size LiFePO4 material due to its enhanced electronic and lithium ion transport rates and thus an improved high-rate performance. However, our previous synthesized LiFePO4 nanorods only exhibited low high-rate and slightly unstable cycle performance. Possible reasons are the poor crystallization and Fe2+ oxidation of LiFePO4 nanorods prepared by hydrothermal method. In this paper, LiFePO4 nanorods were simply dealt with at 700 ℃ for 4 h under the protection of Ar and H2 mixture gas. The electrochemical properties of LiFePO4/Li cells were investigated by galvanostatic test and cyclic voltammetry(CV). The experimental results indicated that the annealed LiFePO4 nanorods delivered an excellent cycling stability and obviously improved capacity of 150 mA·h·g-1 at 1C, and even 122 mA·h·g-1 at 5C.     

Hot deformation behavior of low carbon steel during compression at elevated temperature

Hot compression tests of low carbon steel were carried out on Gleeble-3500 system in the temperature range from 750 to 900 ℃ and in the strain rate range from 0.001 to 1.0 s-1, and the associated microstructural evolution was studied by observations with a metallographic microscope. The results show that the stress-strain curves exhibit a peak stress at critical strain, after which the fl ow stresses decrease monotonically until reaching high strains, showing a dynamic fl ow softening. The peak stress level decreases with increasing deformation temperature and decreasing strain rate, which can be represented by the Zener-Hollomon parameter Z in the hyperbolic sine equation. The fl ow stress increases with increasing strain rate and decreasing deforming temperature. The fl ow stress can be described by constitutive equation in hyperbolic sine function and can also be described by a Zener–Hollomon parameter Z. With increasing deformation temperature and decreasing strain rate, the grain size as well as the volume fraction of the recrystallized grains increase. The safe region for hot working of the alloy has been determined according to the processing map and microstructure at the true strain of 0.5, which is the deformation temperature of 840-940 ℃ and the strain rate of 0.001-1.0 s-1.     

改良型腰果酚醛树脂废气治理的研究

改良型腰果酚醛树脂应用到铸件等浸渍、粘合、烘干等过程中会产生恶臭,排放前需要降解处理。研究采用低温等离子体技术结合吸收方法处理改良型腰果酚醛树脂废气,考察了处理工程中峰值电压、停留时间、吸收液pH值对废气去除率的影响。实验室小试改良型腰果酚醛树脂废气进口浓度85 ppm,停留时间1.2 s时,去除率可达92%;工业扩大示范工程去除率最高可达80%,排气口出气平均恶臭浓度1 239.5(无量纲),满足《恶臭污染物排放标准》(GB14554-93)中相关规定。     

一类修正的q-Baskakov算子的逼近性质

Baskakov型算子是研究函数逼近问题的一种很重要的工具。该文基于Gupta所提出的q-Baskakov算子,介绍了一类修正的q-Baskakov算子,给出了该类算子的一些基本性质,并且得到了该类算子的一致收敛定理,从而进一步推广了q-Baskakov算子的一些结论。     

超高频RFID标签命令头解析模块设计

该文针对超高频RFIDISO 18000-6C标准,分析了移位寄存器解析方案的冗余状态,提出了采用有限状态机优化超高频RFID标签命令头解析面积的方法。采用Verilog HDL,通过设置6组命令,进行了常用方案和新提出方案逻辑门数量的对比,从而反应出标签芯片电路面积的变化。实验结果表明,当指令数量在12 32条之间时,用有限状态机解析命令头的电路面积比用移位寄存器解析的面积小15%33%。     

网络协议电视频道快速切换研究

网络协议电视（Internet Protocol Television,IPTV）已经成为新一代网络（Next Generation Net-work,NGN）中最具潜力的应用,主要由于其具有随时随地都能发送电视节目的特性。随着IEEE 802.16d/e的规格制订,它具有高带宽及低延迟的能力,因此适合作为发送多媒体串流的服务。此外,它也提供讯号高涵盖率、行动性支持以及非视线功能。我们可以利用IEEE 802.16d/e提供发送IPTV串流的媒介,并提出一个简单但却有效的IPTV频道切换算法以维持频道切换的时间在一个可容许的范围内。提出的算法根据热门频道及个人化频道的预载,以减少因为网络传输所造成的延迟,达到快速切换频道的目的。最后,通过实验结果证实算法的效能。     

基于医学院校移动图书馆智能服务模式的研究

本文总结了当前医学院校移动图书馆服务开展的现状,分析了当前服务过程中存在的问题与需求,提出了目前我国医学院校移动图书馆服务的优化与发展方向。     

基于单片机控制的燃气灶自动开关设计

本文以AT89C51单片机为核心,与传统电子燃气灶结合,设计出可以自动点火的燃气灶。该燃气灶通过感受压力来控制燃气的通断和点火,并通过温度传感器检测燃气灶是否已经点燃了。     

以课程设计为中心的排水工程课教学改革初探

排水工程是给排水科学与工程专业的一门专业核心课程,剖析了以排水工程课程设计为核心的课程教学模式改革,阐述了培养学生实践应用能力和创新能力的一些具体教学方法。     

穿斗木结构房屋地震响应分析与构造技术研究

穿斗木结构是我国西南农村地区较常见的房屋结构类型.以一种典型穿斗木结构房屋为研究对象,采用ANSYS有限元软件建立结构整体模型,分析其静力反应、动力特性以及不同强度地震下的响应特性.研究结果表明:该类结构平动第二周期与扭转第一周期较为接近,有可能发生平扭耦联现象;不同强度地震下,加速度响应均在柱底最大,越往上越小,而位移响应均在柱顶最大,越往下越小;结构中的榫卯属于抗震有利部件,能够吸收和耗散地震能量,使结构顶部加速度响应较小,但由于节点的半刚性特点及纵向刚度较小,使结构整体性较差,造成顶部位移响应较大;基于有限元分析结论与实际施工特点,提出在中柱间设置剪刀撑,在梁下设置枋,加强檩条、柱、梁之间的连接,加强围护墙体与构件的连接等措施来提高穿斗木结构房屋的抗震性能.