Moisture Sensitive Smart Yarns and Textiles from Self‐Balanced Silk Fiber Muscles

Smart textiles that sense, interact, and adapt to environmental stimuli have provided exciting new opportunities for a variety of applications. However, current advances have largely remained at the research stage due to the high cost, complexity of manufacturing, and uncomfortableness of environment‐sensitive materials. In contrast, natural textile materials are more attractive for smart textiles due to their merits in terms of low cost and comfortability. Here, water fog and humidity‐driven torsional and tensile actuation of thermally set twisted, coiled, plied silk fibers, and weave textiles from these silk fibers are reported. When exposed to water fog, the torsional silk fiber provides a fully reversible torsional stroke of 547° mm^?1. Coiled‐and‐thermoset silk yarns provide a 70% contraction when the relative humidity is changed from 20% to 80%. Such an excellent actuation behavior originates from water absorption‐induced loss of hydrogen bonds within the silk proteins and the associated structural transformation, which are corroborated by atomistic and macroscopic characterization of silk and molecular dynamics simulations. With its large abundance, cost‐effectiveness, and comfortability for wearing, the silk muscles will open up additional possibilities in industrial applications, such as smart textiles and soft robotics.     

Engineering Fe–Fe3C@Fe–N–C Active Sites and Hybrid Structures from Dual Metal–Organic Frameworks for Oxygen Reduction Reaction in H2–O2 Fuel Cell and Li–O2 Battery

Dual metal–organic frameworks (MOFs, i.e., MIL‐100(Fe) and ZIF‐8) are thermally converted into Fe–Fe₃C‐embedded Fe–N‐codoped carbon as platinum group metal (PGM)‐free oxygen reduction reaction (ORR) electrocatalysts. Pyrolysis enables imidazolate in ZIF‐8 rearranged into highly N‐doped carbon, while Fe from MIL‐100(Fe) into N‐ligated atomic sites concurrently with a few Fe–Fe₃C nanoparticles. Upon precise control of MOF compositions, the optimal catalyst is highly active for the ORR in half‐cells (0.88 V in base and 0.79 V versus RHE in acid in half‐wave potential), a proton exchange membrane fuel cell (0.76 W cm^?2 in peak power density) and an aprotic Li–O₂ battery (8749 mAh g^?1 in discharge capacity), representing a state‐of‐the‐art PGM‐free ORR catalyst. In the material, amorphous carbon with partial graphitization ensures high active site exposure and fast charge transfer simultaneously. Macropores facilitate mass transport to the catalyst surface, followed by oxygen penetration in micropores to reach the infiltrated active sites. Further modeling simulations shed light on the true Fe–Fe₃C contribution to the catalyst performance, suggesting Fe₃C enhances oxygen affinity, while metallic Fe promotes *OH desorption as the rate‐determining step at the nearby Fe–N–C sites. These findings demonstrate MOFs as model system for rational design of electrocatalyst for energy‐based functional applications.     

Bipolar Tetraarylsilanes as Universal Hosts for Blue,Green, Orange,and White Electrophosphorescence with High Efficiency and Low Efficiency Roll‐Off

A series of tetraarylsilane compounds, namely p‐BISiTPA ( 1 ), m‐BISiTPA ( 2 ), p‐OXDSiTPA ( 3 ), m‐OXDSiTPA ( 4 ), are designed and synthesized by incorporating electron‐donating arylamine and electron‐accepting benzimidazole or oxadiazole into one molecule via a silicon‐bridge linkage mode. Their thermal, photophysical and electrochemical properties can be finely tuned through the different groups and linking topologies. The para‐disposition compounds 1 and 3 display higher glass transition temperatures, slightly lower HOMO levels and triplet energies than their meta‐disposition isomers 2 and 4 , respectively. The silicon‐interrupted conjugation of the electron‐donating and electron‐accepting segments gives these materials the following advantages: i) relative high triplet energies in the range of 2.69–2.73 eV; ii) HOMO/LUMO levels of the compounds mainly depend on the electron‐donating and electron‐accepting groups, respectively; iii) bipolar transporting feature as indicated by hole‐only and electron‐only devices. These advantages make these materials ideal universal hosts for multicolor phosphorescent OLEDs. 1 and 3 have been demonstrated as universal hosts for blue, green, orange and white electrophosphorescence, exhibiting high efficiencies and low efficiency roll‐off. For example, the devices hosted by 1 achieve maximum external quantum efficiencies of 16.1% for blue, 22.7% for green, 20.5% for orange, and 19.1% for white electrophosphorescence. Furthermore, the external quantum efficiencies are still as high as 14.2% for blue, 22.4% for green, 18.9% for orange, and 17.4% for white electrophosphorescence at a high luminance of 1000 cd m^?2. The two‐color, all‐phosphor white device hosted by 3 acquires a maximum current efficiency of 51.4 cd A^?1, and a maximum power efficiency of 51.9 lm W^?1. These values are among the highest for single emitting layer white PhOLEDs reported till now.     

FMCW车载毫米波雷达空时码信号处理方案

空时分组码是无线通信系统中的一种抗信道衰落和提高系统容量的编码方法,能够同时获得分集增益和编码增益。由此将MIMO通信和MIMO脉冲雷达中应用较多的空时分组码引入FMCW车载毫米波雷达信号处理中,通过对发射信号和接收信号的编码解耦,形成更大天线孔径的虚拟阵列,提高了系统角度分辨率。相比于基于时间分集的虚拟阵列算法,基于空时分组码的虚拟阵列算法能够在单天线功率受限的场景下,获得多根天线同时工作带来的功率增益。同时,针对空时分组码中目标运动带来的相位误差问题,根据FMCW车载毫米波雷达低复杂度的系统需求,设计了一种适用于相干目标的运动相位校准算法。仿真结果表明,基于空时分组码的FMCW车载毫米波雷达信号处理算法相比于已有算法能够获得更好的系统性能。     

基于云媒体的爱国主义教育平台建设

本文介绍了依托云媒体电视技术建设的淮海纪念塔爱国主义教育平台,该平台采用市、县区两级系统部署结构,在功能上系统划分为:内容制作与发布管理、流媒体、系统管理、统计分析、数据网关等,在终端上对微信和机顶盒进行系统集成。前端云平台迁移、接入网FTTD延伸、终端VR技术引入是今后发展演进方向。     

Research on adaptive dual task offloading decision algorithm for parking space recommendation service

In order to improve the efficiency of tasks processing and reduce the energy consumption of new energy vehicle (NEV), an adaptive dual task offloading decision-making scheme for Internet of vehicles is proposed based on information-assisted service of road side units (RSUs) and task offloading theory. Taking the roadside parking space recommendation service as the specific application Scenario, the task offloading model is built and a hierarchical self-organizing network model is constructed, which utilizes the computing power sharing among nodes, RSUs and mobile edge computing (MEC) servers. The task scheduling is performed through the adaptive task offloading decision algorithm, which helps to realize the available parking space recommendation service which is energy-saving and environmental-friendly. Compared with these traditional task offloading decisions, the proposed scheme takes less time and less energy in the whole process of tasks. Simulation results testified the effectiveness of the proposed scheme.     

Constructions and Properties of General (k,n) Block‐Based Progressive Visual Cryptography

Recently, Hou and others introduced a (2, n) block‐based progressive visual cryptographic scheme (BPVCS) in which image blocks can be gradually recovered step by step. In Hou and others’ (2, n)‐BPVCS, a secret image is subdivided into n non‐overlapping image blocks. When participants stack their shadow images, all the image blocks associated with these t participants will be recovered. However, Hou and others’ scheme is only a simple 2‐out‐of‐n case. In this paper, we discuss a general (k, n)‐BPVCS for any k and n. Our main contribution is to give two constructions (Construction 1 and Construction 2) of this general (k, n)‐BPVCS. Also, we theoretically prove that both constructions satisfy a threshold property and progressive recovery of the proposed (k, n)‐BPVCS. For , Construction 1 is reduced to Hou and others’ (2, n)‐BPVCS.]     

基于GPU的LCS算法加速机制研究与实现

协议特征识别技术中用到了一种重要的LCS算法,它是一种字符串比对算法,提取出字符串中的最长连续公共子串。然而,通过理论分析和实验表明：这个查找过程是一个时间复杂度较高的运算过程,如果输入的数据分组比较大,那么运行的时间将会非常长,为此不得不控制输入数据分组的大小和数量,这严重限制了所采用样本集的大小。提出了基于GPU对LCS运算实现加速的方法。在此基础上搭建和配置了CUDA平台,在此平台下研究并实现了LCS算法的并行性。通过对LCS算法在CUDA下并行性的研究,有效地加快了LCS算法的运行速度。实验结果表明,GPU下LCS算法的运行效率比CPU有了显著的提高。     

基于光谱吸收CH4传感器灵敏度的分析

基于气体红外吸收的基本原理,首先对部分常见气体的吸收谱进行了解,然后对甲烷（CH4）气体传感器原理进行分析。对于光纤气体传感器而言,气体检测灵敏度是一个重要的考虑因素。通过对光谱吸收理论的分析和数据模拟,得到在不考虑光路干扰因素,理想状态情况下,气室吸收长度L和气体浓度C对传感器灵敏度的影响。当L一定时,C增大,则会提高传感灵敏度。当C一定时,增加L,尤其当C较高时,则传感灵敏度较高。