Characterization of Cu/CeO2/γ-Al2O3 Thin Film Catalysts by Thermal Desorption Spectroscopy

Thermal desorption spectroscopy (TDS) under ultra high vacuum (UHV) condition has been used to investigate the desorption characteristics of Cu/CeO₂/γ-Al₂O₃ thin film catalysts coated onto the microchannel of a microreactor. TDS results demonstrate that surface desorption profiles and chemical properties (acid–base and redox properties) are remarkably influenced by the catalyst composition, i.e. the loading of copper and ceria. The enhanced basicity with the increase of ceria loading and the decrease of copper loading is evident from the shifted desorption maximum of CO₂ in TDS spectra. Three oxygen species, ranging from weakly bound oxygen desorbed at low temperature to the strongly held lattice oxygen desorbed at high temperature, are easily discernible and clearly identified by O₂ TDS spectra, depending on the catalyst compositions. The concomitant thermal desorption of O₂, CO₂, and H₂O at low temperature indicates the unique chemical properties of copper/ceria catalyst with appropriate copper and ceria contents. The observed low-temperature feature is ascribed to the role of porthole of copper/ceria interfacial area for several desorbed species. The weakly bound oxygen species is attributed to the enhanced abundance of copper/ceria interfacial anionic vacancies created by the intimate contact between copper and ceria entities and its impact on steam reforming of methanol (SRM) reaction is tentatively discussed in terms of reverse oxygen spillover.     

Characterization of C–S–H and C–A–S–H phases by electron microscopy imaging,diffraction, and energy dispersive X‐ray spectroscopy

Improving concrete sustainability by increasing durability requires a detailed knowledge about microstructural properties. Due to the nanoscale nature of hydrate phases that determine concrete properties, microstructural characterization remains a challenge. Analytical electron microscopy offers promising techniques to characterize cement hydrates. In this study, electron microscopy imaging, diffraction, and energy dispersive X‐ray spectroscopic information are combined in order to compare the structural properties of calcium silicate hydrate (C–S–H) and calcium aluminum silicate hydrate (C–A–S–H) phases. Results are shown for 28 days hydrated C–(A)–S–H of portland cement and cement containing ground granulated blast‐furnace slag (GGFBS). Electron diffraction patterns of single fibrous C–S–H and foil‐like C–A–S–H phases reveal a nanocrystalline structure. Also, it is shown by electron diffraction pattern that the crystal structures of C–S–H and C–A–S–H phases are similar. It is confirmed that the crystal structure of 14 Å tobermorite serves as good base for the structure of C–S–H. The electron diffraction patterns of fibrous C–S–H show streaks which indicate stacking faults, proofing that polymerization of silicate chains in C–S–H is limited. Here, we demonstrate for the first time that the dreierketten silicate chains contained in the C–S–H structure are oriented in parallel to the long axis of C–S–H fibers. This finding should be implemented in modeling of crystal growth of C–S–H.     

相互作用模型在城市规划中的运用

城市增长是未来几个世纪备受关注的问题。为了保证城市可持续发展，有必要对城市的发展进行监控，但预测城市的发展趋势需要一些空间信息的支持、卫星图像能够提供可靠的信息用来评定城市增长的不同状态，而预测未来的建设区段则更加重要。本文构建了相互作用模型（interaction models），或者更精确地说叫潜力模型（potential model），以确定城市空间的扩展方向。该模型被运用于法国斯特拉斯堡地区的分析，采用了两张遥感数据影像，一张用于模型处理，一张用于检验结果。另外，模型还运用GIS技术以提高准确度，同时还考虑到了交通网络。     

Too stressed out to participate? Examining the relation between stressors and survey response behavior.

Despite the use of survey-based organizational data in many studies of organizational behavior, survey response behavior and nonresponse are rarely studied phenomena. This study expands on previously proposed survey response and nonresponse frameworks by integrating the job stress literature. The authors investigated whether overload, role ambiguity, and role conflict experienced by individuals relate to survey response behavior. Using organizational citizenship behavior theory and social exchange theory as theoretical frameworks, the authors proposed that nonrespondents experience higher levels of stressors than respondents. Data collected in a longitudinal field study partially supported the hypotheses. As hypothesized, overload increased the likelihood of nonresponse. Contrary to hypotheses, role ambiguity decreased the likelihood of nonresponse. Role conflict was not significantly related to nonresponse. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Warm asphalt mixtures produced with addition of CCBit

There is a growing concern with the environmental damage caused by the various types of industrial activities. Because of that, research in paving has sought alternatives to reduce fuel consumption and emissions of greenhouse gases generated by those. The warm mixtures have received increasing attention because they are capable of decreasing the mixture and compaction temperatures of asphalt mixtures. The objective of this study was to evaluate the effect of the incorporation of CCBit from the mechanical characterization of asphalt mixtures. From the results, it was found that the incorporation of CCBit has the advantage of reducing mixing and compaction temperatures without harming their mechanical behavior.     

Antibiotic susceptibility testing of Bifidobacterium thermophilum and Bifidobacterium pseudolongum strains: broth microdilution vs. agar disc diffusion assay

There is urgent need for having available suitable methods and data regarding the susceptibility levels of antibiotic resistant and sensitive strains of bifidobacteria. Based on a defined standard operation procedure, agar disc diffusion and broth microdilution were compared in order to evaluate the antimicrobial susceptibility profiles of 82 B. pseudolongum and 80 B. thermophilum strains mainly originating from the meat production chain. The methods that were assessed showed interpretable agreement within this study. The disc diffusion zone diameters are highly reproducible making the method a useful alternative to broth microdilution for antimicrobial susceptibility screening of bifidobacteria.     

Plant Chemical Defense Induced by a Seed-Eating Pollinator Mutualist

Plant-seed parasite pollination mutualisms involve a specific pollinator whose larvae develop by consuming a fraction of the host plant seeds. These mutualisms are stable only if the plant can control seed destruction by the larvae. Here, we studied the chemical response of the European globeflower Trollius europaeus to infestation by an increasing number of Chiastocheta fly larvae. We used liquid chromatographic analysis to compare the content of phenolic compounds in unparasitized and parasitized fruits collected in two natural populations of the French Alps, and mass spectrometry and nuclear magnetic resonance to elucidate the structure of adonivernith, a C-glycosyl-flavone. This compound is present in many of the organs of T. europaeus, but not found in other Trollius species. Furthermore, it is overproduced in the carpel walls of parasitized fruits, and this induced response to infestation by fly larvae is density-dependent (increases with larval number), and site-dependent (more pronounced in the high-altitude site). Mechanical damage did not induce adonivernith production. This tissue-specific and density-dependent response of T. europaeus to infestation by Chiastocheta larvae might be an efficient regulation mechanism of seed-predator mutualist population growth if it decreases survival or growth of the larvae.     

Flexible power generation scenarios for biogas plants operated in Germany: impacts on economic viability and GHG emissions

Biogas plants enable power to be generated in a flexible way so that variable, renewable energy sources can be integrated into the energy system. In Germany, the Renewable Energy Sources Act promotes flexible power generation in biogas plants. Two existing biogas plants in flexible operation were analyzed with respect to economic viability and greenhouse gas (GHG) emissions to assess the feasibility of flexible operation. To do this, a biogas technology simulation model was developed to reproduce the technical design of both biogas plants and to link this design with twelve flexibilization scenarios. The evaluation of the economic viability is based on a discounting method of investment appraisal. For assessing the level of GHG emissions, the life cycle assessment method has been applied. The results show that the profitability of flexibilization is contingent upon premium payments promoting flexibility and direct sales resulting from a higher electrical efficiency of new or additionally installed combined heat and power units. Overall, with respect to profitability, the results of the flexible power generation scenarios are dependent upon the properties of the technical plant, such as its power generation and gas storage capacities. Relative GHG emissions from flexible biogas plants show significantly lower values than for referenced fossil gas–steam power stations. Among the various scenarios, the results reveal that the level of GHG emissions especially depends on the number of operating hours of the additional combined heat and power unit(s). The results of the analyzed biogas plants showed no direct correlation between GHG emissions and the economic benefits. Overall, a flexible power generation of biogas plants may improve the economic viability as well as result in lower GHG emissions in comparison with a conventional base load operation. © 2016 The Authors. International Journal of Energy Research published by John Wiley & Sons Ltd.     

Dietary fat in the prevention of cardiovascular disease — a review

In developed countries atherosclerotic cardiovascular disease is the reason for about 50% of all deaths. With growing prosperity coronary heart disease (CHD) is becoming the major cause of premature death. Most complications of atherosclerosis occur unexpectedly and more than 50% of the patients developing a myocardial infarction do not survive more than one year. Because of the severe morbidity and high mortality primary prevention is likely to be the only solution. Epidemiological studies show a strong, positive relationship between plasma cholesterol concentrations and the incidence of CHD. People who immigrate from low‐risk to high‐risk areas usually acquire similar plasma cholesterol levels as the native population and a similar CHD risk. This demonstrates that environmental rather than genetic factors lead to the differences in cardiovascular risk and supports the notion that nutrition and lifestyle play a major role. The association between dietary intake of fat and cholesterol and the extent of atherosclerosis and CHD has been recognized in previous studies. The amount of saturated fat in the diet correlates stronger with the incidence of CHD than with total fat intake. The consumption of unsaturated fatty acids, however, appears to be beneficial, since it is inversely correlated with the plasma cholesterol concentration and risk of myocardial infarction. Lately additional nutritional factors like trans fatty acids with a negative influence on risk as well as positive factors like linolenic acid have attracted much attention. In conclusion, as a challenge to public health, preventive medicine needs to focus on changes in dietary habits with priority, particularly fat modification. A nutrition low in total fat primarily avoiding saturated and trans fatty acids, but rich in fruit and vegetables should be recommended.     

Preparation and characterization of organic layers for UV protection of polycarbonate

In many applications, polycarbonate surfaces need to be coated as a protection against abrasion and decomposition caused by weathering. In particular, UV radiation during exposure to sunlight degrades polycarbonate, which causes delamination of the protective layer. To avoid coating delamination, the layer itself needs an absorption edge near 400 nm. One option is to use UV-absorbing organic molecules. The aim of the present study was to develop UV-protective layer stacks containing suitable organic molecules deposited in a vacuum process, with a focus on the stability of UV-absorbing organic layers during UV irradiation and their optical properties. The commercial UV absorber Tinuvin™ 360 and the organic compound N,N′-di(naphth-1-yl)-N,N′-diphenyl-benzidine were used. Thin layers of the organic materials were evaporated thermally. The optical properties and UV stability were investigated using UV-VIS and infrared spectroscopy.