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91.
This article presents a two-dimensional transient model for gas-solids flow and heat transfer through pipes using the coupled Computational Fluid Dynamics and Discrete Element Method approach. Numerical simulations have been conducted to examine the modification of fluid thermal structure due to the presence of particles in a pneumatic transport pipeline. Modeled results have demonstrated the key role of transversal motion of rebounding particles in the pipe cross section in altering fluid temperature. Further implementation of this modeling technique in air-drying processes is discussed and possible experimental methods for the measurement of in situ particle and fluid motion and temperature profile are cited. 相似文献
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A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP–DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc. 相似文献
94.
Basic data of four fractions, PM1, PM6, PM7and PM8, derived from Pingshuo bituminous coal were obtained by ultimate analyses, mean molecular weight measure, GC/MS, 13C-NM R, 1H-NM R and FTIR technigues. A method of calculating the average molecular parameters of the fractions is introduced. Based on the calculated parameters, the molecular structure models of the fractions of PM6, PM;and PM8are constructed. Significant structural information about the saturated hydrocarbon and aromatic hydrocarbon with heteroatom groups is given also. 相似文献
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本文利用简便的滴定过程模型,确立了微机模拟处理实验数据,方便、准确地求解络合滴定等当点的方法。设计了最佳实验条件模拟估计程序。该法测定Zn~(2+),Pb~(2+),Cu~(2+),Fe~(3+)结果的相对误差Δ<1%。pH=6-7时,测定Ca~(2+)的相对误差为-1.61%;σ<0.001mmol,(N=5)。 相似文献
98.
Permanent distortion is one of the main drawbacks of all the irreversible watermarking schemes. Attempts to recover the original signal after the signal passes the authentication process are being made, starting just a few years ago. Some common problems, such as salt-and-pepper artefacts owing to intensity wraparound and low embedding capacity, can now be resolved. However, some significant problems remain unsolved. First, the embedding capacity is signal-dependent, i.e., capacity varies significantly depending on the nature of the host signal. The direct impact of this is compromised security for signals with low capacity. Some signals may be even non-embeddable. Secondly, while seriously tackled in irreversible watermarking schemes, the well-known problem of block-wise dependence, which opens a security gap for the vector quantisation attack and transplantation attack, are not addressed by researchers of the reversible schemes. This work proposes a reversible watermarking scheme with near-constant signal-independent embedding capacity and immunity to the vector quantisation attack and transplantation attack. 相似文献
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