Performance of the polymer- and oxide-supported triphase catalysts and effect of ultrasound on their stabilities

In this study, several trialkylamines were immobilized on chloromethylated polystyrene (CMPS), silica gel, and alumina to prepare triphase catalysts for catalyzing the etherification reaction of allyl bromide (the organic reactant) and sodium phenolate (the aqueous reactant). The reactor was agitated mechanically or with the aid of ultrasonic vibration. Performances of the prepared catalysts were compared, and the effect of imposing ultrasound was investigated based on the activity, selectivity, and stability of the catalyst. Experimental results show that tri-n-propylamine is the best active species when CMPS is used as the support, while tri-n-butylamine is the best when SiO₂ and Al₂O₃ are employed as the supports. The CMPS-supported catalyst is far better than the SiO₂- and Al₂O₃-supported catalysts in activity and selectivity but not in stability. Imposing the ultrasound can effectively increase the reaction rate. Mechanical agitation at a low speed with the imposition of ultrasonic vibration not only results in a conversion slightly higher than the case with a high mechanical agitation speed without ultrasonic vibration, but also gives a constant stability for the CMPS-supported catalyst.     

Effects of changes in strain path on the anisotropy of yield stresses of low-carbon steel and 70-30 brass sheets

Uniaxial tensile tests in various directions following uniaxial extension, equibiaxial stretching or plane strain rolling have been performed to study the effects of changes in strain path on the anisotropy of yield stresses of aluminium-killed low-carbon steel and 70-30 brass sheets. The anisotropy could be predicted from the specimen textures, if dislocation structure were equiaxed, as in the case of equibiaxial stretching. However, elongated dislocation cell structures, developed in the steel specimens prestrained in uniaxial tension or plane strain rolling, gave rise to the second-stage yield stresses higher than predicted from textures in the directions different from the maximum prestrain direction. Planar dislocation structures in the brass specimens prestrained in uniaxial tension or plane strain rolling gave the second-stage yield stresses lower than predicted from the textures in the directions different from the maximum prestrain direction. The phenomena are discussed based on textures and dislocation structures.     

Pharmacological specificities and modalities of prescriptions for corticoids for asthmatic adults

The efficacy of corticosteroids in asthma has been recognized over 40 years ago. Since that time, the advent of inhaled forms has further improved the therapeutic of these drugs which are now recognized as the fundamental treatment for asthma, and described in detail by national and international consensus. Based on a large body of literature, it can now be recommended to prescribe inhaled corticosteroids for symptomatic asthma patients. Long-term treatment is required and dosage not exceeding 1000 micrograms/d (beclometasone dipropionate equivalent) in adults are safe. Differences in the pharmacological characteristics of the various systematic and inhaled corticosteroids can be used to adapt treatment and administration route to each patient and achieve good patient compliance with optimal therapeutic efficacy.     

An isolated ZVS/ZCS flyback converter using the leakage inductanceof the coupled inductor

This paper describes a simple and effective way to modify an existing hard-switched flyback power converter into a circuit with zero-voltage switching (ZVS) and zero-current switching (ZCS). The key improvement is to turn the unattractive features of the coupled inductor leakage inductance and snubber capacitor into attractive ones. The coupled inductor leakage inductance and snubber are used to form a quasi-resonant circuit to facilitate ZVS/ZCS of all power devices. The operating principles of the power converter and experimental results are presented     

Anomalous variations of OFF-State leakage current in poly-Si TFTunder static stress

Studies the anomalous variations of the OFF-state leakage current (I_OFF) in n-channel poly-Si thin-film transistors (TFTs) under static stress. The dominant mechanisms for the anomalous I_OFF can be attributed to (1) I_OFF increases due to channel hot electrons trapping at the gate oxide/channel interface and silicon grain boundaries and (2) I_OFF decreases due to hot holes accumulated/trapped near the channel/bottom oxide interface near the source region. Under the stress of high drain bias, serious impact ionization effect will occur to generate hot electrons and hot holes near the drain region. Some of holes will be injected into the gate oxide due to the vertical field (~(V_Gstress V_Dstress)/T _OX) near the drain and the others will be migrated from drain to source along the channel due to lateral electric field (~V_Dstress/L_CH)     

A region-based selective optical flow back-projection for genuine motion vector estimation

Motion vector plays one significant feature in moving object segmentation. However, the motion vector in this application is required to represent the actual motion displacement, rather than regions of visually significant similarity. In this paper, region-based selective optical flow back-projection (RSOFB) which back-projects optical flows in a region to restore the region's motion vector from gradient-based optical flows, is proposed to obtain genuine motion displacement. The back-projection is performed based on minimizing the projection mean square errors of the motion vector on gradient directions. As optical flows of various magnitudes and directions provide various degrees of reliability in the genuine motion restoration, the optical flows to be used in the RSOFB are optimally selected based on their sensitivity to noises and their tendency in causing motion estimation errors. In this paper a deterministic solution is also derived for performing the minimization and obtaining the genuine motion magnitude and motion direction.     

Cardio-pulmonary function during acute unilateral occlusion of the pulmonary artery in broilers fed diets containing normal or high levels of arginine-HCl

Cardio-pulmonary function was measured in male broilers reared on diets formulated to contain 1.5% arginine (NORMAL group) or 2.5% arginine (ARGININE group). A snare placed around the right pulmonary artery permitted acute shunting of the entire cardiac output (CO) through the left pulmonary artery, resulting in sustained increases in blood flow (BF) through the left lung in both groups. The unilateral increase in BF was accompanied by sustained increases in pulmonary arterial pressure (PAP) and pulmonary vascular resistance (PVR) in the NORMAL group. However, following initial transient increases in PAP and PVR in the ARGININE group, subsequent pulmonary vasodilation gradually reduced PVR, and thus PAP, in spite of the ongoing elevation of BF through the left lung. The capacity of the pulmonary vasculature in the ARGININE group to accommodate an increased BF at a normal PAP accounts for the previously reported lower incidence of pulmonary hypertension syndrome (PHS, ascites) in cold-stressed broilers fed supplemental dietary arginine. Hypoxemia and respiratory acidosis ensued rapidly in both groups after tightening the pulmonary artery snare, in spite of a compensatory increase in the respiratory rate. The gradual return of PVR and PAP to presnare levels in the ARGININE group did not eliminate the concurrent ventilation-perfusion mismatch caused by the increased rate of BF through the left lung. Tightening the pulmonary artery snare caused mean systemic arterial pressure (MAP) to drop from control levels of approximately 98 mm Hg to sustained hypotensive levels of approximately 65 mm Hg in both groups. This systemic hypotension was caused by decreases in CO and total peripheral resistance (TPR). The reduction in CO were caused by reduction in stroke volume (SV) rather than heart rate (HR), suggesting that acutely tightening the pulmonary artery snare increased PVR sufficiently to impede left ventricular filling. Accordingly, the maximum increment in PAP attainable by the right ventricle during acute increases in PVR apparently was inadequate to propel the entire CO through the pulmonary vasculature, setting the stage for the congestive right-sided pooling of blood routinely associated with PHS in broilers.