Microstructure Development of Oxycarbide Composites during Active-Filler-Controlled Polymer Pyrolysis

The microstructure development of a ceramic composite material fabricated by active-filler-controlled polymer pyrolysis (AFCOP) was investigated. During heating of a polysiloxane precursor mixed with titanium powder in argon atmosphere up to 1400°C, thermally induced decomposition of the polymer phase is combined with simultaneous carburization of the transition metal filler. Precipitation of nanocrystalline titanium carbide at the filler particle surface starts above 400°C, and larger, faceted carbide particles have growth above 800°C. A skeleton of turbostratic carbon is formed above 800°C in the polymer-derived silicon oxycarbide matrix from which b-silicon carbide and cristobalite crystallize above 1000°C. A pronounced reduction in linear shrinkage involved in polymer–ceramic conversion is observed. The shrinkage reduction ranges from more than 25% for the filler-free precursor to less than 10% in the presence of 30 vol% of the titanium filler. Thus, active-filler-controlled pyrolysis offers the possibility of controlling shrinkage and porosity formation during polymer–ceramic conversion in order to fabricate bulk components from organometallic polymer precursor systems.     

Executive Summary—Community Water Supply: The Handpump Option

An estimated 1,800 million people need improved water supplies in the fifteen years to the end of the century, if developing countries are to reach the target of full coverage. The first half of the International Drinking Water Supply and Sanitation Decade (1981–1990) has seen increases in the percentages of the rural population with access to safe water supplies, but only in Asia has the pace been quick enough to envisage a target of essentiahy full coverage by the end of the century (ten years later than the original Decade goals). In Africa, present progress rates would leave half of the rural population still without safe water in the year 2000, while in Latin America, it may be ten years into the next century before full coverage is achieved unless progress improves dramatically.

Accelerated progress is hampered by financial and technical resource constraints faced by many developing countries, and the problem is aggravated by the growing number of completed projects which are broken down and abandoned, or functioning much below capacity. Attempts to increase the pace of providing improved community water supplies have often been frustrated because the technology used has proved impossible to sustain in village conditions.

To make a lasting impact on the urgent needs, community water supply (CWS) strategies must be based on sustainable and replicable programs, and must take account of the pace at which resource constraints can be overcome. Human resource development programs take time to produce results, and institutional changes can only be accomplished gradually.     

Settlement as a driver for sewer rehabilitation

This paper assesses the influence of (differential) settlement on sewer system functioning. Based on historical data of the vertical position of sewer invert levels, tilt measurements and in-sewer inspection videos, settlement and settlement related influences are analyzed for a case study area in Amsterdam. The average settlement rate of this system was 4 mm/year. Given this settlement rate, it is shown that settlement significantly influences sewer system functioning within the lifetime of a sewer (system).     

Worker control: A reply to Ronan.

Argues that W. W. Ronan (1980) presents a one-sided picture of "work force control" by the "entrepreneur–capitalist–management group" and discredits the contributions of many psychologists to workers' well-being. Ronan's contentions that (1) psychological concepts are applied to programs that are motivated by management's desire to avoid unionization, (2) psychological experiments and interventions are unilaterally imposed on workers by management, and (3) economic benefits of psychological interventions should be shared equally with workers are discussed. It is concluded that psychologists have every reason to be proud of their colleagues' contributions to making companies more profitable while improving the work environment for employees. (1 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Scoring- und beidseitige Due-Diligence-Prozesse im Rahmen der Lieferantenauswahl beim Infrastrukturoutsourcing

Scoring and double-sided due diligence processes employed with vendor selection for IT infrastructure outsourcing Outsourcing opens the procurement of semi-finished products from business partners that are able to provide the respective processes in the required quality but at lower prices, e. g. because of bundling effects and specialization advantages. In particular, services that are not based on core-processes of an enterprise are well-suited for outsourcing. The evaluation of IT service outsourcing is difficult, because of its strategic position in enterprises. Against this background, this article describes a method to select a suitable vendor for IT infrastructure outsourcing employing scoring and double-sided due diligence processes. Our findings are based on experiences when selecting the vendor for outsourcing the European Information Technology Infrastructure (IT/I) area of the Deutsche Bank AG.     

Distinguishing video quality through differential matrices

Multicast multi-layered communications must implement efficient control algorithms to address undesirable network behaviors. This paper proposes two multi-metric algorithms for computing the rates of the video layers and improve the global video quality of a multicast session. In fact, we show that a single-metric approach may degrade some network parameters without obtaining any substantial improvements. Our first algorithm combines three metrics and a set of weights in such a way that one metric can be prioritized. This leads to an improved quality of multicast sessions, as we show through a number of experiments. In networks where the available resources are highly variable, however, the stability of the video quality is compromised if absolute values of the metrics are adopted. We then propose a second algorithm that uses the relative values of the metrics on a per-entry basis. Computation of the global quality of the multicast session is based on a differential matrix that stores the metrics for each receiver. This scheme takes into account the dynamics of the available resources and the heterogeneity of receivers. The great benefit of this approach is that the global video quality is always improved for every loop of the algorithm.     

A 2 MV Van de Graaff accelerator as a tool for planetary and impact physics research

Investigating the dynamical and physical properties of cosmic dust can reveal a great deal of information about both the dust and its many sources. Over recent years, several spacecraft (e.g., Cassini, Stardust, Galileo, and Ulysses) have successfully characterised interstellar, interplanetary, and circumplanetary dust using a variety of techniques, including in situ analyses and sample return. Charge, mass, and velocity measurements of the dust are performed either directly (induced charge signals) or indirectly (mass and velocity from impact ionisation signals or crater morphology) and constrain the dynamical parameters of the dust grains. Dust compositional information may be obtained via either time-of-flight mass spectrometry of the impact plasma or direct sample return. The accurate and reliable interpretation of collected spacecraft data requires a comprehensive programme of terrestrial instrument calibration. This process involves accelerating suitable solar system analogue dust particles to hypervelocity speeds in the laboratory, an activity performed at the Max Planck Institut fu?r Kernphysik in Heidelberg, Germany. Here, a 2 MV Van de Graaff accelerator electrostatically accelerates charged micron and submicron-sized dust particles to speeds up to 80 km s(-1). Recent advances in dust production and processing have allowed solar system analogue dust particles (silicates and other minerals) to be coated with a thin conductive shell, enabling them to be charged and accelerated. Refinements and upgrades to the beam line instrumentation and electronics now allow for the reliable selection of particles at velocities of 1-80 km s(-1) and with diameters of between 0.05 μm and 5 μm. This ability to select particles for subsequent impact studies based on their charges, masses, or velocities is provided by a particle selection unit (PSU). The PSU contains a field programmable gate array, capable of monitoring in real time the particles' speeds and charges, and is controlled remotely by a custom, platform independent, software package. The new control instrumentation and electronics, together with the wide range of accelerable particle types, allow the controlled investigation of hypervelocity impact phenomena across a hitherto unobtainable range of impact parameters.     

Quantitative detection of gold nanoparticles on individual, unstained cancer cells by scanning electron microscopy

Gold nanoparticles are rapidly emerging for use in biomedical applications. Characterization of the interaction and delivery of nanoparticles to cells through microscopy is important. Scanning electron microscopes have the intrinsic resolution to visualize gold nanoparticles on cells. A novel sample preparation protocol was developed to enable imaging of cells and gold nanoparticles with a conventional below lens scanning electron microscopes. The negative influence of 'charging' on the quality of scanning electron microscopes' images could be limited by deposition of biological cells on a conductive (gold) surface. The novel protocol enabled high-resolution scanning electron microscopes' imaging of small clusters and individual gold nanoparticles on uncoated cell surfaces. Gold nanoparticles could be counted on cancer cells with automated routines.     

Improved γ-alumina support based pseudo-boehmite shaped by micro-extrusion process for oxygen carrier support application

γ-Alumina extrudates for chemical-looping combustion in fluidized bed reactors were shaped by varying acetic acid concentrations between 0.07 and 3.76 M. Influence of pseudo-boehmite peptization on structural properties, microstructure, chemical phases and attrition resistance was determined. With addition of acetic acid, the d₉₀ of boehmite agglomerates after 1 h kneading decreased from 134 to 40 μm at pH 4. Due to this, the extrusion diameter was reduced from 1500 to 200 μm, as well as median pore radii (from 30.1 to 5.3 nm). Porosity was about 70%. Addition of more than 1.87 M acid lead to a slight increase in mesopore sizes caused by some pore blocking caused by the formation of aluminium acetate salts. A small micropore surface was determined with t-layer model from Harkins and Jura. Higher attrition resistance was observed for samples peptized with lower acid concentration because of the closer contact between particles after decomposition.